Implementation of a Core–Shell Design Approach for Constructing MOFs for CO₂ Capture Article Swipe

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Yiwen He , Paul Boone , Austin Lieber , Zi Tong , Prasenjit Das , Katherine Hornbostel , Christopher E. Wilmer , Nathaniel L. Rosi ·

YOU? · · 2023 · Open Access · · DOI: https://doi.org/10.1021/acsami.3c03457

Adsorption-based capture of CO₂ from flue gas and from air requires materials that have a high affinity for CO₂ and can resist water molecules that competitively bind to adsorption sites. Here, we present a core-shell metal-organic framework (MOF) design strategy where the core MOF is designed to selectively adsorb CO₂, and the shell MOF is designed to block H₂O diffusion into the core. To implement and test this strategy, we used the zirconium (Zr)-based UiO MOF platform because of its relative structural rigidity and chemical stability. Previously reported computational screening results were used to select optimal core and shell MOF compositions from a basis set of possible building blocks, and the target core-shell MOFs were prepared. Their compositions and structures were characterized using scanning electron microscopy, transmission electron microscopy, and powder X-ray diffraction. Multigas (CO₂, N₂, and H₂O) sorption data were collected both for the core-shell MOFs and for the core and shell MOFs individually. These data were compared to determine whether the core-shell MOF architecture improved the CO₂ capture performance under humid conditions. The combination of experimental and computational results demonstrated that adding a shell layer with high CO₂/H₂O diffusion selectivity can significantly reduce the effect of water on CO₂ uptake.

Related Topics

Materials Science

Metal–Organic Framework

Adsorption

Transmission Electron Microscopy

Nanotechnology

Chemical Engineering

Zirconium

Scanning Electron Microscope

Scanning Transmission Electron Microscopy

Concepts

Materials science Metal-organic framework Adsorption Sorption Transmission electron microscopy Shell (structure) Nanotechnology Chemical engineering Zirconium Scanning electron microscope Scanning transmission electron microscopy Chemistry Composite material Organic chemistry Metallurgy Engineering

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Type: article
Language: en
Landing Page: https://doi.org/10.1021/acsami.3c03457
PDF: https://pubs.acs.org/doi/pdf/10.1021/acsami.3c03457
OA Status: hybrid
Cited By: 25
References: 45
Related Works: 10
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DOI: https://doi.org/10.1021/acsami.3c03457

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Title: Implementation of a Core–Shell Design Approach for Constructing MOFs for CO₂ Capture

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Type: article

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Language: en

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Publication year: 2023

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Publication date: 2023-05-04

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Authors: Yiwen He, Paul Boone, Austin Lieber, Zi Tong, Prasenjit Das, Katherine Hornbostel, Christopher E. Wilmer, Nathaniel L. Rosi

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Landing page: https://doi.org/10.1021/acsami.3c03457

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Concepts: Materials science, Metal-organic framework, Adsorption, Sorption, Transmission electron microscopy, Shell (structure), Nanotechnology, Chemical engineering, Zirconium, Scanning electron microscope, Scanning transmission electron microscopy, Chemistry, Composite material, Organic chemistry, Metallurgy, Engineering

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Cited by: 25

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Implementation of a Core–Shell Design Approach for Constructing MOFs for CO2 Capture Article Swipe

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Implementation of a Core–Shell Design Approach for Constructing MOFs for CO₂ Capture Article Swipe