Inactive Overhang in Silicon Anodes Article Swipe
Aidin I. O’Brien
,
Stephen E. Trask
,
Devashish Salpekar
,
Seoung‐Bum Son
,
Alison R. Dunlop
,
Gabriel M. Veith
,
Wenquan Lu
,
Brian J. Ingram
,
Daniel P. Abraham
,
Andrew N. Jansen
,
Marco‐Tulio F. Rodrigues
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1149/1945-7111/ad5d22
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1149/1945-7111/ad5d22
Li-ion batteries contain excess anode area to improve manufacturability and prevent Li plating. These overhang areas in graphite electrodes are active but experience decreased Li + flux during cycling. Over time, the overhang and the anode portions directly opposite to the cathode can exchange Li + , driven by differences in local electrical potential across the electrode, which artificially inflates or decreases the measured cell capacity. Here, we show that lithiation of the overhang is less likely to happen in silicon anodes paired with layered oxide cathodes. The large voltage hysteresis of silicon creates a lower driving force for Li + exchange as lithium ions transit into the overhang, rendering this exchange highly inefficient. For crystalline Si particles, Li + storage at the overhang is prohibitive, because the low potential required for the initial lithiation can act as thermodynamic barrier for this exchange. We use micro-Raman spectroscopy to demonstrate that crystalline Si particles at the overhang are never lithiated even after cell storage at 45 °C for four months. Because the anode overhang can affect the forecasting of cell life, cells using silicon anodes may require different methodologies for life estimation compared to those used for traditional graphite-based Li-ion batteries.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1149/1945-7111/ad5d22
- https://iopscience.iop.org/article/10.1149/1945-7111/ad5d22/pdf
- OA Status
- hybrid
- Cited By
- 5
- References
- 38
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4400106668
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4400106668Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1149/1945-7111/ad5d22Digital Object Identifier
- Title
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Inactive Overhang in Silicon AnodesWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-06-28Full publication date if available
- Authors
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Aidin I. O’Brien, Stephen E. Trask, Devashish Salpekar, Seoung‐Bum Son, Alison R. Dunlop, Gabriel M. Veith, Wenquan Lu, Brian J. Ingram, Daniel P. Abraham, Andrew N. Jansen, Marco‐Tulio F. RodriguesList of authors in order
- Landing page
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https://doi.org/10.1149/1945-7111/ad5d22Publisher landing page
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https://iopscience.iop.org/article/10.1149/1945-7111/ad5d22/pdfDirect link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://iopscience.iop.org/article/10.1149/1945-7111/ad5d22/pdfDirect OA link when available
- Concepts
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Anode, Materials science, Silicon, Cathode, Electrode, Graphite, Crystalline silicon, Raman spectroscopy, Nanotechnology, Chemical engineering, Optoelectronics, Composite material, Chemistry, Optics, Physics, Physical chemistry, EngineeringTop concepts (fields/topics) attached by OpenAlex
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5Total citation count in OpenAlex
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2025: 3, 2024: 2Per-year citation counts (last 5 years)
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38Number of works referenced by this work
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-
10Other works algorithmically related by OpenAlex
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