Increasing the Magnetic Transition Dipole Moment of Chiral Perovskite Through Eu3+ Doping Article Swipe
Zhichao Zeng
,
Haolin Lu
,
Zhengwei Yang
,
Haolin Wu
,
Chuang Zhang
,
Guankui Long
,
Yaping Du
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/apxr.202400064
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/apxr.202400064
Chiral hybrid organic‐inorganic perovskites (HOIPs) are widely investigated due to their superior chiroptical and chiral spintronic properties. Research on the enhancement of chiroptical performance is highly important for the real application of chiral HOIPs. This work employed a rare earth doping strategy to increase the magnetic transition dipole moment of chiral 2D HOIPs R ‐/ S ‐NPB (NPB = 1‐(1‐naphthyl) ethylammonium lead bromide). Doping with Eu 3+ does not change the original layered NPB microstructure, and R ‐/ S ‐NPB‐Eu exhibited the magnetic dipole‐allowed transition luminescence of Eu 3+ at 594 nm ( 5 D 0 → 7 F 1 ). Circular polarized luminescence (CPL) spectra combined with theoretical calculations and transient photoluminescence measurements indicated that the introduction of Eu 3+ can enhance the magnetic transition dipole moment of R ‐/ S ‐NPB, thus resulting in an unprecedented g lum of 0.05. To the best of our knowledge, this is the highest value for chiral perovskite films. This work combines the unique and superior optoelectronic properties of rare‐earth ions with chiral perovskite and develops an efficient strategy to increase its anisotropy factor, which can accelerate the development of chiral optoelectronics and spintronics towards real application.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/apxr.202400064
- OA Status
- diamond
- Cited By
- 4
- References
- 41
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4402651188
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4402651188Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/apxr.202400064Digital Object Identifier
- Title
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Increasing the Magnetic Transition Dipole Moment of Chiral Perovskite Through Eu3+ DopingWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-09-19Full publication date if available
- Authors
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Zhichao Zeng, Haolin Lu, Zhengwei Yang, Haolin Wu, Chuang Zhang, Guankui Long, Yaping DuList of authors in order
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https://doi.org/10.1002/apxr.202400064Publisher landing page
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YesWhether a free full text is available
- OA status
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diamondOpen access status per OpenAlex
- OA URL
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https://doi.org/10.1002/apxr.202400064Direct OA link when available
- Concepts
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Doping, Perovskite (structure), Condensed matter physics, Dipole, Moment (physics), Magnetic moment, Materials science, Magnetic dipole, Nuclear magnetic resonance, Physics, Chemistry, Crystallography, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
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4Total citation count in OpenAlex
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2025: 4Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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