Influence of the ZrO2 Crystalline Phases on the Nature of Active Sites in PdCu/ZrO2 Catalysts for the Methanol Steam Reforming Reaction—An In Situ Spectroscopic Study Article Swipe
Daniel Ruano
,
Beatriz M. Pabón
,
Cátia Azenha
,
Cécilia Mateos-Pedrero
,
Adélio Mendes
,
Virginia Pérez‐Dieste
,
Patricia Concepción
·
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.3390/catal10091005
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.3390/catal10091005
In this work, the electronic properties of the metal sites in cubic and monoclinic ZrO2 supported Pd and PdCu catalysts have been investigated using CO as probe molecule in in-situ IR studies, and the surface composition of the outermost layers has been studied by APXPS (Ambient Pressure X-ray Photoemission Spectroscopy). The reaction products were followed by mass spectrometry, making it possible to relate the chemical properties of the catalysts under reaction conditions with their selectivity. Combining these techniques, it has been shown that the structure of the support (monoclinic or cubic ZrO2) affects the metal dispersion, mobility, and reorganization of metal sites under methanol steam reforming (MSR) conditions, influencing the oxidation state of surface metal species, with important consequences in the catalytic activity. Correlating the mass spectra of the reaction products with these spectroscopic studies, it was possible to conclude that electropositive metal species play an imperative role for high CO2 and H2 selectivity in the MSR reaction (less CO formation).
Related Topics
Concepts
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.3390/catal10091005
- https://www.mdpi.com/2073-4344/10/9/1005/pdf
- OA Status
- gold
- Cited By
- 24
- References
- 34
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3082082054
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W3082082054Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.3390/catal10091005Digital Object Identifier
- Title
-
Influence of the ZrO2 Crystalline Phases on the Nature of Active Sites in PdCu/ZrO2 Catalysts for the Methanol Steam Reforming Reaction—An In Situ Spectroscopic StudyWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2020Year of publication
- Publication date
-
2020-09-02Full publication date if available
- Authors
-
Daniel Ruano, Beatriz M. Pabón, Cátia Azenha, Cécilia Mateos-Pedrero, Adélio Mendes, Virginia Pérez‐Dieste, Patricia ConcepciónList of authors in order
- Landing page
-
https://doi.org/10.3390/catal10091005Publisher landing page
- PDF URL
-
https://www.mdpi.com/2073-4344/10/9/1005/pdfDirect link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://www.mdpi.com/2073-4344/10/9/1005/pdfDirect OA link when available
- Concepts
-
Monoclinic crystal system, Steam reforming, Catalysis, Methanol, Metal, Selectivity, Inorganic chemistry, Materials science, Chemistry, Chemical engineering, Molecule, Organic chemistry, Hydrogen production, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
24Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 6, 2024: 9, 2023: 3, 2022: 3, 2021: 3Per-year citation counts (last 5 years)
- References (count)
-
34Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
Full payload
| id | https://openalex.org/W3082082054 |
|---|---|
| doi | https://doi.org/10.3390/catal10091005 |
| ids.doi | https://doi.org/10.3390/catal10091005 |
| ids.mag | 3082082054 |
| ids.openalex | https://openalex.org/W3082082054 |
| fwci | 0.77550504 |
| type | article |
| title | Influence of the ZrO2 Crystalline Phases on the Nature of Active Sites in PdCu/ZrO2 Catalysts for the Methanol Steam Reforming Reaction—An In Situ Spectroscopic Study |
| awards[0].id | https://openalex.org/G2106802096 |
| awards[0].funder_id | https://openalex.org/F4320322930 |
| awards[0].display_name | |
| awards[0].funder_award_id | RTI2018-099668-B-C21 |
| awards[0].funder_display_name | Ministerio de Ciencia e Innovación |
| awards[1].id | https://openalex.org/G7971188028 |
| awards[1].funder_id | https://openalex.org/F4320333065 |
| awards[1].display_name | |
| awards[1].funder_award_id | FP/2007-2013 |
| awards[1].funder_display_name | Seventh Framework Programme |
| biblio.issue | 9 |
| biblio.volume | 10 |
| biblio.last_page | 1005 |
| biblio.first_page | 1005 |
| topics[0].id | https://openalex.org/T10192 |
| topics[0].field.id | https://openalex.org/fields/25 |
| topics[0].field.display_name | Materials Science |
| topics[0].score | 0.9998000264167786 |
| topics[0].domain.id | https://openalex.org/domains/3 |
| topics[0].domain.display_name | Physical Sciences |
| topics[0].subfield.id | https://openalex.org/subfields/2505 |
| topics[0].subfield.display_name | Materials Chemistry |
| topics[0].display_name | Catalytic Processes in Materials Science |
| topics[1].id | https://openalex.org/T11784 |
| topics[1].field.id | https://openalex.org/fields/21 |
| topics[1].field.display_name | Energy |
| topics[1].score | 0.9990000128746033 |
| topics[1].domain.id | https://openalex.org/domains/3 |
| topics[1].domain.display_name | Physical Sciences |
| topics[1].subfield.id | https://openalex.org/subfields/2105 |
| topics[1].subfield.display_name | Renewable Energy, Sustainability and the Environment |
| topics[1].display_name | CO2 Reduction Techniques and Catalysts |
| topics[2].id | https://openalex.org/T11825 |
| topics[2].field.id | https://openalex.org/fields/15 |
| topics[2].field.display_name | Chemical Engineering |
| topics[2].score | 0.9990000128746033 |
| topics[2].domain.id | https://openalex.org/domains/3 |
| topics[2].domain.display_name | Physical Sciences |
| topics[2].subfield.id | https://openalex.org/subfields/1503 |
| topics[2].subfield.display_name | Catalysis |
| topics[2].display_name | Catalysis and Oxidation Reactions |
| funders[0].id | https://openalex.org/F4320322930 |
| funders[0].ror | https://ror.org/034900433 |
| funders[0].display_name | Ministerio de Ciencia e Innovación |
| funders[1].id | https://openalex.org/F4320333065 |
| funders[1].ror | |
| funders[1].display_name | Seventh Framework Programme |
| is_xpac | False |
| apc_list.value | 2200 |
| apc_list.currency | CHF |
| apc_list.value_usd | 2382 |
| apc_paid.value | 2200 |
| apc_paid.currency | CHF |
| apc_paid.value_usd | 2382 |
| concepts[0].id | https://openalex.org/C61276311 |
| concepts[0].level | 3 |
| concepts[0].score | 0.8302472829818726 |
| concepts[0].wikidata | https://www.wikidata.org/wiki/Q624543 |
| concepts[0].display_name | Monoclinic crystal system |
| concepts[1].id | https://openalex.org/C43535742 |
| concepts[1].level | 4 |
| concepts[1].score | 0.8150389194488525 |
| concepts[1].wikidata | https://www.wikidata.org/wiki/Q556466 |
| concepts[1].display_name | Steam reforming |
| concepts[2].id | https://openalex.org/C161790260 |
| concepts[2].level | 2 |
| concepts[2].score | 0.8077017664909363 |
| concepts[2].wikidata | https://www.wikidata.org/wiki/Q82264 |
| concepts[2].display_name | Catalysis |
| concepts[3].id | https://openalex.org/C2779607525 |
| concepts[3].level | 2 |
| concepts[3].score | 0.5953055620193481 |
| concepts[3].wikidata | https://www.wikidata.org/wiki/Q14982 |
| concepts[3].display_name | Methanol |
| concepts[4].id | https://openalex.org/C544153396 |
| concepts[4].level | 2 |
| concepts[4].score | 0.5895453691482544 |
| concepts[4].wikidata | https://www.wikidata.org/wiki/Q11426 |
| concepts[4].display_name | Metal |
| concepts[5].id | https://openalex.org/C118792377 |
| concepts[5].level | 3 |
| concepts[5].score | 0.5515800714492798 |
| concepts[5].wikidata | https://www.wikidata.org/wiki/Q108584245 |
| concepts[5].display_name | Selectivity |
| concepts[6].id | https://openalex.org/C179104552 |
| concepts[6].level | 1 |
| concepts[6].score | 0.4398408532142639 |
| concepts[6].wikidata | https://www.wikidata.org/wiki/Q11165 |
| concepts[6].display_name | Inorganic chemistry |
| concepts[7].id | https://openalex.org/C192562407 |
| concepts[7].level | 0 |
| concepts[7].score | 0.4288483262062073 |
| concepts[7].wikidata | https://www.wikidata.org/wiki/Q228736 |
| concepts[7].display_name | Materials science |
| concepts[8].id | https://openalex.org/C185592680 |
| concepts[8].level | 0 |
| concepts[8].score | 0.4126686155796051 |
| concepts[8].wikidata | https://www.wikidata.org/wiki/Q2329 |
| concepts[8].display_name | Chemistry |
| concepts[9].id | https://openalex.org/C42360764 |
| concepts[9].level | 1 |
| concepts[9].score | 0.4027318060398102 |
| concepts[9].wikidata | https://www.wikidata.org/wiki/Q83588 |
| concepts[9].display_name | Chemical engineering |
| concepts[10].id | https://openalex.org/C32909587 |
| concepts[10].level | 2 |
| concepts[10].score | 0.29491591453552246 |
| concepts[10].wikidata | https://www.wikidata.org/wiki/Q11369 |
| concepts[10].display_name | Molecule |
| concepts[11].id | https://openalex.org/C178790620 |
| concepts[11].level | 1 |
| concepts[11].score | 0.16077789664268494 |
| concepts[11].wikidata | https://www.wikidata.org/wiki/Q11351 |
| concepts[11].display_name | Organic chemistry |
| concepts[12].id | https://openalex.org/C202189072 |
| concepts[12].level | 3 |
| concepts[12].score | 0.1100594699382782 |
| concepts[12].wikidata | https://www.wikidata.org/wiki/Q1929999 |
| concepts[12].display_name | Hydrogen production |
| concepts[13].id | https://openalex.org/C127413603 |
| concepts[13].level | 0 |
| concepts[13].score | 0.0 |
| concepts[13].wikidata | https://www.wikidata.org/wiki/Q11023 |
| concepts[13].display_name | Engineering |
| keywords[0].id | https://openalex.org/keywords/monoclinic-crystal-system |
| keywords[0].score | 0.8302472829818726 |
| keywords[0].display_name | Monoclinic crystal system |
| keywords[1].id | https://openalex.org/keywords/steam-reforming |
| keywords[1].score | 0.8150389194488525 |
| keywords[1].display_name | Steam reforming |
| keywords[2].id | https://openalex.org/keywords/catalysis |
| keywords[2].score | 0.8077017664909363 |
| keywords[2].display_name | Catalysis |
| keywords[3].id | https://openalex.org/keywords/methanol |
| keywords[3].score | 0.5953055620193481 |
| keywords[3].display_name | Methanol |
| keywords[4].id | https://openalex.org/keywords/metal |
| keywords[4].score | 0.5895453691482544 |
| keywords[4].display_name | Metal |
| keywords[5].id | https://openalex.org/keywords/selectivity |
| keywords[5].score | 0.5515800714492798 |
| keywords[5].display_name | Selectivity |
| keywords[6].id | https://openalex.org/keywords/inorganic-chemistry |
| keywords[6].score | 0.4398408532142639 |
| keywords[6].display_name | Inorganic chemistry |
| keywords[7].id | https://openalex.org/keywords/materials-science |
| keywords[7].score | 0.4288483262062073 |
| keywords[7].display_name | Materials science |
| keywords[8].id | https://openalex.org/keywords/chemistry |
| keywords[8].score | 0.4126686155796051 |
| keywords[8].display_name | Chemistry |
| keywords[9].id | https://openalex.org/keywords/chemical-engineering |
| keywords[9].score | 0.4027318060398102 |
| keywords[9].display_name | Chemical engineering |
| keywords[10].id | https://openalex.org/keywords/molecule |
| keywords[10].score | 0.29491591453552246 |
| keywords[10].display_name | Molecule |
| keywords[11].id | https://openalex.org/keywords/organic-chemistry |
| keywords[11].score | 0.16077789664268494 |
| keywords[11].display_name | Organic chemistry |
| keywords[12].id | https://openalex.org/keywords/hydrogen-production |
| keywords[12].score | 0.1100594699382782 |
| keywords[12].display_name | Hydrogen production |
| language | en |
| locations[0].id | doi:10.3390/catal10091005 |
| locations[0].is_oa | True |
| locations[0].source.id | https://openalex.org/S2738539744 |
| locations[0].source.issn | 2073-4344 |
| locations[0].source.type | journal |
| locations[0].source.is_oa | True |
| locations[0].source.issn_l | 2073-4344 |
| locations[0].source.is_core | True |
| locations[0].source.is_in_doaj | False |
| locations[0].source.display_name | Catalysts |
| locations[0].source.host_organization | https://openalex.org/P4310310987 |
| locations[0].source.host_organization_name | Multidisciplinary Digital Publishing Institute |
| locations[0].source.host_organization_lineage | https://openalex.org/P4310310987 |
| locations[0].source.host_organization_lineage_names | Multidisciplinary Digital Publishing Institute |
| locations[0].license | cc-by |
| locations[0].pdf_url | https://www.mdpi.com/2073-4344/10/9/1005/pdf |
| locations[0].version | publishedVersion |
| locations[0].raw_type | journal-article |
| locations[0].license_id | https://openalex.org/licenses/cc-by |
| locations[0].is_accepted | True |
| locations[0].is_published | True |
| locations[0].raw_source_name | Catalysts |
| locations[0].landing_page_url | https://doi.org/10.3390/catal10091005 |
| locations[1].id | pmh:oai:doaj.org/article:72dd9dfabb764d8ca990106e12dd4224 |
| locations[1].is_oa | True |
| locations[1].source.id | https://openalex.org/S4306401280 |
| locations[1].source.issn | |
| locations[1].source.type | repository |
| locations[1].source.is_oa | False |
| locations[1].source.issn_l | |
| locations[1].source.is_core | False |
| locations[1].source.is_in_doaj | False |
| locations[1].source.display_name | DOAJ (DOAJ: Directory of Open Access Journals) |
| locations[1].source.host_organization | |
| locations[1].source.host_organization_name | |
| locations[1].license | cc-by-sa |
| locations[1].pdf_url | |
| locations[1].version | submittedVersion |
| locations[1].raw_type | article |
| locations[1].license_id | https://openalex.org/licenses/cc-by-sa |
| locations[1].is_accepted | False |
| locations[1].is_published | False |
| locations[1].raw_source_name | Catalysts, Vol 10, Iss 1005, p 1005 (2020) |
| locations[1].landing_page_url | https://doaj.org/article/72dd9dfabb764d8ca990106e12dd4224 |
| locations[2].id | pmh:oai:mdpi.com:/2073-4344/10/9/1005/ |
| locations[2].is_oa | True |
| locations[2].source.id | https://openalex.org/S4306400947 |
| locations[2].source.issn | |
| locations[2].source.type | repository |
| locations[2].source.is_oa | True |
| locations[2].source.issn_l | |
| locations[2].source.is_core | False |
| locations[2].source.is_in_doaj | False |
| locations[2].source.display_name | MDPI (MDPI AG) |
| locations[2].source.host_organization | https://openalex.org/I4210097602 |
| locations[2].source.host_organization_name | Multidisciplinary Digital Publishing Institute (Switzerland) |
| locations[2].source.host_organization_lineage | https://openalex.org/I4210097602 |
| locations[2].license | cc-by |
| locations[2].pdf_url | |
| locations[2].version | submittedVersion |
| locations[2].raw_type | Text |
| locations[2].license_id | https://openalex.org/licenses/cc-by |
| locations[2].is_accepted | False |
| locations[2].is_published | False |
| locations[2].raw_source_name | Catalysts; Volume 10; Issue 9; Pages: 1005 |
| locations[2].landing_page_url | https://dx.doi.org/10.3390/catal10091005 |
| locations[3].id | pmh:oai:repositorio-aberto.up.pt:10216/138598 |
| locations[3].is_oa | True |
| locations[3].source.id | https://openalex.org/S4306401934 |
| locations[3].source.issn | |
| locations[3].source.type | repository |
| locations[3].source.is_oa | False |
| locations[3].source.issn_l | |
| locations[3].source.is_core | False |
| locations[3].source.is_in_doaj | False |
| locations[3].source.display_name | Open Repository of the University of Porto (University of Porto) |
| locations[3].source.host_organization | https://openalex.org/I182534213 |
| locations[3].source.host_organization_name | Universidade do Porto |
| locations[3].source.host_organization_lineage | https://openalex.org/I182534213 |
| locations[3].license | other-oa |
| locations[3].pdf_url | |
| locations[3].version | submittedVersion |
| locations[3].raw_type | journal article |
| locations[3].license_id | https://openalex.org/licenses/other-oa |
| locations[3].is_accepted | False |
| locations[3].is_published | False |
| locations[3].raw_source_name | |
| locations[3].landing_page_url | https://hdl.handle.net/10216/138598 |
| indexed_in | crossref, doaj |
| authorships[0].author.id | https://openalex.org/A5085203815 |
| authorships[0].author.orcid | https://orcid.org/0000-0002-0145-5133 |
| authorships[0].author.display_name | Daniel Ruano |
| authorships[0].countries | ES |
| authorships[0].affiliations[0].institution_ids | https://openalex.org/I2801631255 |
| authorships[0].affiliations[0].raw_affiliation_string | ALBA Synchrotron Light Source, Carrer Llum 2-26, 08290 Cerdanyola Del Valles, Spain |
| authorships[0].affiliations[1].institution_ids | https://openalex.org/I134820265, https://openalex.org/I4210135619, https://openalex.org/I60053951 |
| authorships[0].affiliations[1].raw_affiliation_string | Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avenida de los Naranjos s/n, 46022 Valencia, Spain |
| authorships[0].institutions[0].id | https://openalex.org/I2801631255 |
| authorships[0].institutions[0].ror | https://ror.org/02j9n6e35 |
| authorships[0].institutions[0].type | company |
| authorships[0].institutions[0].lineage | https://openalex.org/I2801631255 |
| authorships[0].institutions[0].country_code | ES |
| authorships[0].institutions[0].display_name | ALBA Synchrotron (Spain) |
| authorships[0].institutions[1].id | https://openalex.org/I134820265 |
| authorships[0].institutions[1].ror | https://ror.org/02gfc7t72 |
| authorships[0].institutions[1].type | government |
| authorships[0].institutions[1].lineage | https://openalex.org/I134820265 |
| authorships[0].institutions[1].country_code | ES |
| authorships[0].institutions[1].display_name | Consejo Superior de Investigaciones Científicas |
| authorships[0].institutions[2].id | https://openalex.org/I4210135619 |
| authorships[0].institutions[2].ror | https://ror.org/038792a28 |
| authorships[0].institutions[2].type | facility |
| authorships[0].institutions[2].lineage | https://openalex.org/I134820265, https://openalex.org/I4210135619, https://openalex.org/I60053951 |
| authorships[0].institutions[2].country_code | ES |
| authorships[0].institutions[2].display_name | Instituto de Tecnología Química |
| authorships[0].institutions[3].id | https://openalex.org/I60053951 |
| authorships[0].institutions[3].ror | https://ror.org/01460j859 |
| authorships[0].institutions[3].type | education |
| authorships[0].institutions[3].lineage | https://openalex.org/I60053951 |
| authorships[0].institutions[3].country_code | ES |
| authorships[0].institutions[3].display_name | Universitat Politècnica de València |
| authorships[0].author_position | first |
| authorships[0].raw_author_name | Daniel Ruano |
| authorships[0].is_corresponding | False |
| authorships[0].raw_affiliation_strings | ALBA Synchrotron Light Source, Carrer Llum 2-26, 08290 Cerdanyola Del Valles, Spain, Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avenida de los Naranjos s/n, 46022 Valencia, Spain |
| authorships[1].author.id | https://openalex.org/A5046411890 |
| authorships[1].author.orcid | https://orcid.org/0000-0003-4732-4777 |
| authorships[1].author.display_name | Beatriz M. Pabón |
| authorships[1].countries | ES |
| authorships[1].affiliations[0].institution_ids | https://openalex.org/I134820265, https://openalex.org/I4210135619, https://openalex.org/I60053951 |
| authorships[1].affiliations[0].raw_affiliation_string | Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avenida de los Naranjos s/n, 46022 Valencia, Spain |
| authorships[1].institutions[0].id | https://openalex.org/I134820265 |
| authorships[1].institutions[0].ror | https://ror.org/02gfc7t72 |
| authorships[1].institutions[0].type | government |
| authorships[1].institutions[0].lineage | https://openalex.org/I134820265 |
| authorships[1].institutions[0].country_code | ES |
| authorships[1].institutions[0].display_name | Consejo Superior de Investigaciones Científicas |
| authorships[1].institutions[1].id | https://openalex.org/I4210135619 |
| authorships[1].institutions[1].ror | https://ror.org/038792a28 |
| authorships[1].institutions[1].type | facility |
| authorships[1].institutions[1].lineage | https://openalex.org/I134820265, https://openalex.org/I4210135619, https://openalex.org/I60053951 |
| authorships[1].institutions[1].country_code | ES |
| authorships[1].institutions[1].display_name | Instituto de Tecnología Química |
| authorships[1].institutions[2].id | https://openalex.org/I60053951 |
| authorships[1].institutions[2].ror | https://ror.org/01460j859 |
| authorships[1].institutions[2].type | education |
| authorships[1].institutions[2].lineage | https://openalex.org/I60053951 |
| authorships[1].institutions[2].country_code | ES |
| authorships[1].institutions[2].display_name | Universitat Politècnica de València |
| authorships[1].author_position | middle |
| authorships[1].raw_author_name | Beatriz M. Pabón |
| authorships[1].is_corresponding | False |
| authorships[1].raw_affiliation_strings | Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avenida de los Naranjos s/n, 46022 Valencia, Spain |
| authorships[2].author.id | https://openalex.org/A5076190425 |
| authorships[2].author.orcid | https://orcid.org/0000-0002-7411-0304 |
| authorships[2].author.display_name | Cátia Azenha |
| authorships[2].countries | PT |
| authorships[2].affiliations[0].institution_ids | https://openalex.org/I182534213 |
| authorships[2].affiliations[0].raw_affiliation_string | LEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal |
| authorships[2].institutions[0].id | https://openalex.org/I182534213 |
| authorships[2].institutions[0].ror | https://ror.org/043pwc612 |
| authorships[2].institutions[0].type | education |
| authorships[2].institutions[0].lineage | https://openalex.org/I182534213 |
| authorships[2].institutions[0].country_code | PT |
| authorships[2].institutions[0].display_name | Universidade do Porto |
| authorships[2].author_position | middle |
| authorships[2].raw_author_name | Càtia Azenha |
| authorships[2].is_corresponding | False |
| authorships[2].raw_affiliation_strings | LEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal |
| authorships[3].author.id | https://openalex.org/A5060597509 |
| authorships[3].author.orcid | https://orcid.org/0000-0002-8836-089X |
| authorships[3].author.display_name | Cécilia Mateos-Pedrero |
| authorships[3].countries | PT |
| authorships[3].affiliations[0].institution_ids | https://openalex.org/I182534213 |
| authorships[3].affiliations[0].raw_affiliation_string | LEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal |
| authorships[3].institutions[0].id | https://openalex.org/I182534213 |
| authorships[3].institutions[0].ror | https://ror.org/043pwc612 |
| authorships[3].institutions[0].type | education |
| authorships[3].institutions[0].lineage | https://openalex.org/I182534213 |
| authorships[3].institutions[0].country_code | PT |
| authorships[3].institutions[0].display_name | Universidade do Porto |
| authorships[3].author_position | middle |
| authorships[3].raw_author_name | Cecilia Mateos-Pedrero |
| authorships[3].is_corresponding | False |
| authorships[3].raw_affiliation_strings | LEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal |
| authorships[4].author.id | https://openalex.org/A5067759365 |
| authorships[4].author.orcid | https://orcid.org/0000-0003-2472-3265 |
| authorships[4].author.display_name | Adélio Mendes |
| authorships[4].countries | PT |
| authorships[4].affiliations[0].institution_ids | https://openalex.org/I182534213 |
| authorships[4].affiliations[0].raw_affiliation_string | LEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal |
| authorships[4].institutions[0].id | https://openalex.org/I182534213 |
| authorships[4].institutions[0].ror | https://ror.org/043pwc612 |
| authorships[4].institutions[0].type | education |
| authorships[4].institutions[0].lineage | https://openalex.org/I182534213 |
| authorships[4].institutions[0].country_code | PT |
| authorships[4].institutions[0].display_name | Universidade do Porto |
| authorships[4].author_position | middle |
| authorships[4].raw_author_name | Adélio Mendes |
| authorships[4].is_corresponding | False |
| authorships[4].raw_affiliation_strings | LEPABE—Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal |
| authorships[5].author.id | https://openalex.org/A5030683006 |
| authorships[5].author.orcid | |
| authorships[5].author.display_name | Virginia Pérez‐Dieste |
| authorships[5].countries | ES |
| authorships[5].affiliations[0].institution_ids | https://openalex.org/I2801631255 |
| authorships[5].affiliations[0].raw_affiliation_string | ALBA Synchrotron Light Source, Carrer Llum 2-26, 08290 Cerdanyola Del Valles, Spain |
| authorships[5].institutions[0].id | https://openalex.org/I2801631255 |
| authorships[5].institutions[0].ror | https://ror.org/02j9n6e35 |
| authorships[5].institutions[0].type | company |
| authorships[5].institutions[0].lineage | https://openalex.org/I2801631255 |
| authorships[5].institutions[0].country_code | ES |
| authorships[5].institutions[0].display_name | ALBA Synchrotron (Spain) |
| authorships[5].author_position | middle |
| authorships[5].raw_author_name | Virginia Pérez-Dieste |
| authorships[5].is_corresponding | True |
| authorships[5].raw_affiliation_strings | ALBA Synchrotron Light Source, Carrer Llum 2-26, 08290 Cerdanyola Del Valles, Spain |
| authorships[6].author.id | https://openalex.org/A5073126664 |
| authorships[6].author.orcid | https://orcid.org/0000-0003-2058-3103 |
| authorships[6].author.display_name | Patricia Concepción |
| authorships[6].countries | ES |
| authorships[6].affiliations[0].institution_ids | https://openalex.org/I134820265, https://openalex.org/I4210135619, https://openalex.org/I60053951 |
| authorships[6].affiliations[0].raw_affiliation_string | Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avenida de los Naranjos s/n, 46022 Valencia, Spain |
| authorships[6].institutions[0].id | https://openalex.org/I134820265 |
| authorships[6].institutions[0].ror | https://ror.org/02gfc7t72 |
| authorships[6].institutions[0].type | government |
| authorships[6].institutions[0].lineage | https://openalex.org/I134820265 |
| authorships[6].institutions[0].country_code | ES |
| authorships[6].institutions[0].display_name | Consejo Superior de Investigaciones Científicas |
| authorships[6].institutions[1].id | https://openalex.org/I4210135619 |
| authorships[6].institutions[1].ror | https://ror.org/038792a28 |
| authorships[6].institutions[1].type | facility |
| authorships[6].institutions[1].lineage | https://openalex.org/I134820265, https://openalex.org/I4210135619, https://openalex.org/I60053951 |
| authorships[6].institutions[1].country_code | ES |
| authorships[6].institutions[1].display_name | Instituto de Tecnología Química |
| authorships[6].institutions[2].id | https://openalex.org/I60053951 |
| authorships[6].institutions[2].ror | https://ror.org/01460j859 |
| authorships[6].institutions[2].type | education |
| authorships[6].institutions[2].lineage | https://openalex.org/I60053951 |
| authorships[6].institutions[2].country_code | ES |
| authorships[6].institutions[2].display_name | Universitat Politècnica de València |
| authorships[6].author_position | last |
| authorships[6].raw_author_name | Patricia Concepción |
| authorships[6].is_corresponding | True |
| authorships[6].raw_affiliation_strings | Instituto de Tecnología Química, Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC), Avenida de los Naranjos s/n, 46022 Valencia, Spain |
| has_content.pdf | True |
| has_content.grobid_xml | True |
| is_paratext | False |
| open_access.is_oa | True |
| open_access.oa_url | https://www.mdpi.com/2073-4344/10/9/1005/pdf |
| open_access.oa_status | gold |
| open_access.any_repository_has_fulltext | False |
| created_date | 2020-09-08T00:00:00 |
| display_name | Influence of the ZrO2 Crystalline Phases on the Nature of Active Sites in PdCu/ZrO2 Catalysts for the Methanol Steam Reforming Reaction—An In Situ Spectroscopic Study |
| has_fulltext | True |
| is_retracted | False |
| updated_date | 2025-11-06T03:46:38.306776 |
| primary_topic.id | https://openalex.org/T10192 |
| primary_topic.field.id | https://openalex.org/fields/25 |
| primary_topic.field.display_name | Materials Science |
| primary_topic.score | 0.9998000264167786 |
| primary_topic.domain.id | https://openalex.org/domains/3 |
| primary_topic.domain.display_name | Physical Sciences |
| primary_topic.subfield.id | https://openalex.org/subfields/2505 |
| primary_topic.subfield.display_name | Materials Chemistry |
| primary_topic.display_name | Catalytic Processes in Materials Science |
| related_works | https://openalex.org/W2320118746, https://openalex.org/W2086299624, https://openalex.org/W1964159414, https://openalex.org/W1981634121, https://openalex.org/W1964369749, https://openalex.org/W4241180448, https://openalex.org/W3037628611, https://openalex.org/W343708777, https://openalex.org/W2606459909, https://openalex.org/W2365726912 |
| cited_by_count | 24 |
| counts_by_year[0].year | 2025 |
| counts_by_year[0].cited_by_count | 6 |
| counts_by_year[1].year | 2024 |
| counts_by_year[1].cited_by_count | 9 |
| counts_by_year[2].year | 2023 |
| counts_by_year[2].cited_by_count | 3 |
| counts_by_year[3].year | 2022 |
| counts_by_year[3].cited_by_count | 3 |
| counts_by_year[4].year | 2021 |
| counts_by_year[4].cited_by_count | 3 |
| locations_count | 4 |
| best_oa_location.id | doi:10.3390/catal10091005 |
| best_oa_location.is_oa | True |
| best_oa_location.source.id | https://openalex.org/S2738539744 |
| best_oa_location.source.issn | 2073-4344 |
| best_oa_location.source.type | journal |
| best_oa_location.source.is_oa | True |
| best_oa_location.source.issn_l | 2073-4344 |
| best_oa_location.source.is_core | True |
| best_oa_location.source.is_in_doaj | False |
| best_oa_location.source.display_name | Catalysts |
| best_oa_location.source.host_organization | https://openalex.org/P4310310987 |
| best_oa_location.source.host_organization_name | Multidisciplinary Digital Publishing Institute |
| best_oa_location.source.host_organization_lineage | https://openalex.org/P4310310987 |
| best_oa_location.source.host_organization_lineage_names | Multidisciplinary Digital Publishing Institute |
| best_oa_location.license | cc-by |
| best_oa_location.pdf_url | https://www.mdpi.com/2073-4344/10/9/1005/pdf |
| best_oa_location.version | publishedVersion |
| best_oa_location.raw_type | journal-article |
| best_oa_location.license_id | https://openalex.org/licenses/cc-by |
| best_oa_location.is_accepted | True |
| best_oa_location.is_published | True |
| best_oa_location.raw_source_name | Catalysts |
| best_oa_location.landing_page_url | https://doi.org/10.3390/catal10091005 |
| primary_location.id | doi:10.3390/catal10091005 |
| primary_location.is_oa | True |
| primary_location.source.id | https://openalex.org/S2738539744 |
| primary_location.source.issn | 2073-4344 |
| primary_location.source.type | journal |
| primary_location.source.is_oa | True |
| primary_location.source.issn_l | 2073-4344 |
| primary_location.source.is_core | True |
| primary_location.source.is_in_doaj | False |
| primary_location.source.display_name | Catalysts |
| primary_location.source.host_organization | https://openalex.org/P4310310987 |
| primary_location.source.host_organization_name | Multidisciplinary Digital Publishing Institute |
| primary_location.source.host_organization_lineage | https://openalex.org/P4310310987 |
| primary_location.source.host_organization_lineage_names | Multidisciplinary Digital Publishing Institute |
| primary_location.license | cc-by |
| primary_location.pdf_url | https://www.mdpi.com/2073-4344/10/9/1005/pdf |
| primary_location.version | publishedVersion |
| primary_location.raw_type | journal-article |
| primary_location.license_id | https://openalex.org/licenses/cc-by |
| primary_location.is_accepted | True |
| primary_location.is_published | True |
| primary_location.raw_source_name | Catalysts |
| primary_location.landing_page_url | https://doi.org/10.3390/catal10091005 |
| publication_date | 2020-09-02 |
| publication_year | 2020 |
| referenced_works | https://openalex.org/W2896198484, https://openalex.org/W1979665920, https://openalex.org/W3010325843, https://openalex.org/W2915803412, https://openalex.org/W2002877575, https://openalex.org/W2040083220, https://openalex.org/W1997073739, https://openalex.org/W2128468022, https://openalex.org/W2035237983, https://openalex.org/W2794522566, https://openalex.org/W1996687700, https://openalex.org/W2536484611, https://openalex.org/W2283009411, https://openalex.org/W1968971399, https://openalex.org/W2914100710, https://openalex.org/W2524828455, https://openalex.org/W2930530371, https://openalex.org/W2293267107, https://openalex.org/W2792314387, https://openalex.org/W2898923076, https://openalex.org/W2612369154, https://openalex.org/W1985287794, https://openalex.org/W2951894306, https://openalex.org/W2006014999, https://openalex.org/W6735663894, https://openalex.org/W1983089035, https://openalex.org/W2154947348, https://openalex.org/W2083949185, https://openalex.org/W2040791136, https://openalex.org/W2040663003, https://openalex.org/W2031558071, https://openalex.org/W1994138637, https://openalex.org/W1996245510, https://openalex.org/W2601939159 |
| referenced_works_count | 34 |
| abstract_inverted_index.CO | 24, 159 |
| abstract_inverted_index.H2 | 152 |
| abstract_inverted_index.IR | 30 |
| abstract_inverted_index.In | 0 |
| abstract_inverted_index.Pd | 16 |
| abstract_inverted_index.an | 145 |
| abstract_inverted_index.as | 25 |
| abstract_inverted_index.by | 43, 55 |
| abstract_inverted_index.in | 10, 28, 119, 154 |
| abstract_inverted_index.it | 59, 78, 135 |
| abstract_inverted_index.of | 6, 36, 66, 85, 99, 112, 127 |
| abstract_inverted_index.or | 89 |
| abstract_inverted_index.to | 61, 138 |
| abstract_inverted_index.CO2 | 150 |
| abstract_inverted_index.MSR | 156 |
| abstract_inverted_index.The | 50 |
| abstract_inverted_index.and | 12, 17, 32, 97, 151 |
| abstract_inverted_index.for | 148 |
| abstract_inverted_index.has | 40, 79 |
| abstract_inverted_index.the | 3, 7, 33, 37, 63, 67, 83, 86, 93, 109, 120, 124, 128, 155 |
| abstract_inverted_index.was | 136 |
| abstract_inverted_index.PdCu | 18 |
| abstract_inverted_index.ZrO2 | 14 |
| abstract_inverted_index.been | 21, 41, 80 |
| abstract_inverted_index.have | 20 |
| abstract_inverted_index.high | 149 |
| abstract_inverted_index.mass | 56, 125 |
| abstract_inverted_index.play | 144 |
| abstract_inverted_index.role | 147 |
| abstract_inverted_index.that | 82, 140 |
| abstract_inverted_index.this | 1 |
| abstract_inverted_index.were | 53 |
| abstract_inverted_index.with | 72, 116, 131 |
| abstract_inverted_index.(MSR) | 106 |
| abstract_inverted_index.(less | 158 |
| abstract_inverted_index.APXPS | 44 |
| abstract_inverted_index.X-ray | 47 |
| abstract_inverted_index.ZrO2) | 91 |
| abstract_inverted_index.cubic | 11, 90 |
| abstract_inverted_index.metal | 8, 94, 100, 114, 142 |
| abstract_inverted_index.probe | 26 |
| abstract_inverted_index.shown | 81 |
| abstract_inverted_index.sites | 9, 101 |
| abstract_inverted_index.state | 111 |
| abstract_inverted_index.steam | 104 |
| abstract_inverted_index.their | 73 |
| abstract_inverted_index.these | 76, 132 |
| abstract_inverted_index.under | 69, 102 |
| abstract_inverted_index.using | 23 |
| abstract_inverted_index.work, | 2 |
| abstract_inverted_index.layers | 39 |
| abstract_inverted_index.making | 58 |
| abstract_inverted_index.relate | 62 |
| abstract_inverted_index.affects | 92 |
| abstract_inverted_index.in-situ | 29 |
| abstract_inverted_index.species | 143 |
| abstract_inverted_index.spectra | 126 |
| abstract_inverted_index.studied | 42 |
| abstract_inverted_index.support | 87 |
| abstract_inverted_index.surface | 34, 113 |
| abstract_inverted_index.(Ambient | 45 |
| abstract_inverted_index.Pressure | 46 |
| abstract_inverted_index.chemical | 64 |
| abstract_inverted_index.conclude | 139 |
| abstract_inverted_index.followed | 54 |
| abstract_inverted_index.methanol | 103 |
| abstract_inverted_index.molecule | 27 |
| abstract_inverted_index.possible | 60, 137 |
| abstract_inverted_index.products | 52, 130 |
| abstract_inverted_index.reaction | 51, 70, 129, 157 |
| abstract_inverted_index.species, | 115 |
| abstract_inverted_index.studies, | 31, 134 |
| abstract_inverted_index.Combining | 75 |
| abstract_inverted_index.activity. | 122 |
| abstract_inverted_index.catalysts | 19, 68 |
| abstract_inverted_index.catalytic | 121 |
| abstract_inverted_index.important | 117 |
| abstract_inverted_index.mobility, | 96 |
| abstract_inverted_index.outermost | 38 |
| abstract_inverted_index.oxidation | 110 |
| abstract_inverted_index.reforming | 105 |
| abstract_inverted_index.structure | 84 |
| abstract_inverted_index.supported | 15 |
| abstract_inverted_index.conditions | 71 |
| abstract_inverted_index.electronic | 4 |
| abstract_inverted_index.imperative | 146 |
| abstract_inverted_index.monoclinic | 13 |
| abstract_inverted_index.properties | 5, 65 |
| abstract_inverted_index.(monoclinic | 88 |
| abstract_inverted_index.Correlating | 123 |
| abstract_inverted_index.composition | 35 |
| abstract_inverted_index.conditions, | 107 |
| abstract_inverted_index.dispersion, | 95 |
| abstract_inverted_index.formation). | 160 |
| abstract_inverted_index.influencing | 108 |
| abstract_inverted_index.selectivity | 153 |
| abstract_inverted_index.techniques, | 77 |
| abstract_inverted_index.consequences | 118 |
| abstract_inverted_index.investigated | 22 |
| abstract_inverted_index.selectivity. | 74 |
| abstract_inverted_index.Photoemission | 48 |
| abstract_inverted_index.spectrometry, | 57 |
| abstract_inverted_index.spectroscopic | 133 |
| abstract_inverted_index.Spectroscopy). | 49 |
| abstract_inverted_index.reorganization | 98 |
| abstract_inverted_index.electropositive | 141 |
| cited_by_percentile_year.max | 99 |
| cited_by_percentile_year.min | 95 |
| corresponding_author_ids | https://openalex.org/A5030683006, https://openalex.org/A5073126664 |
| countries_distinct_count | 2 |
| institutions_distinct_count | 7 |
| corresponding_institution_ids | https://openalex.org/I134820265, https://openalex.org/I2801631255, https://openalex.org/I4210135619, https://openalex.org/I60053951 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/14 |
| sustainable_development_goals[0].score | 0.550000011920929 |
| sustainable_development_goals[0].display_name | Life below water |
| citation_normalized_percentile.value | 0.66468512 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |