Insight into functionalized-macrocycles-guided supramolecular photocatalysis Article Swipe

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Minzan Zuo , K. Velmurugan , Kaiya Wang , Xueqi Tian , Xiao‐Yu Hu ·

YOU? · · 2021 · Open Access · · DOI: https://doi.org/10.3762/bjoc.17.15

Due to the unique characteristics of macrocycles (e.g., the ease of modification, hydrophobic cavities, and specific guest recognition), they can provide a suitable environment to realize photocatalysis via noncovalent interactions with different substrates. In this minireview, we emphasized the photochemical transformation and catalytic reactivity of different guests based on the binding with various macrocyclic hosts as well as on the role of macrocyclic-hosts-assisted hybrid materials in energy transfer. To keep the clarity of this review, the macrocycles are categorized into the most commonly used supramolecular hosts, including crown ethers, cyclodextrins, cucurbiturils, calixarenes, and pillararenes. This minireview not only summarizes the role that macrocycles play in photocatalytic reactions but also clarifies the photocatalytic mechanisms. Finally, the future research efforts and new pathways to apply macrocycles and supramolecular hybrid materials in photocatalysis are also discussed.

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Cucurbituril Supramolecular chemistry Photocatalysis Chemistry Supramolecular catalysis Nanotechnology Calixarene Non-covalent interactions Combinatorial chemistry Reactivity (psychology) Catalysis Organic chemistry Molecule Materials science Hydrogen bond Pathology Alternative medicine Medicine

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Type: review
Language: en
Landing Page: https://doi.org/10.3762/bjoc.17.15
PDF: https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-17-15.pdf
OA Status: diamond
Cited By: 26
References: 60
Related Works: 10
OpenAlex ID: https://openalex.org/W3123049688

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OpenAlex ID: https://openalex.org/W3123049688

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DOI: https://doi.org/10.3762/bjoc.17.15

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Title: Insight into functionalized-macrocycles-guided supramolecular photocatalysis

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Type: review

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Language: en

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Publication year: 2021

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Publication date: 2021-01-18

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Authors: Minzan Zuo, K. Velmurugan, Kaiya Wang, Xueqi Tian, Xiao‐Yu Hu

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Landing page: https://doi.org/10.3762/bjoc.17.15

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PDF URL: https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-17-15.pdf

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Concepts: Cucurbituril, Supramolecular chemistry, Photocatalysis, Chemistry, Supramolecular catalysis, Nanotechnology, Calixarene, Non-covalent interactions, Combinatorial chemistry, Reactivity (psychology), Catalysis, Organic chemistry, Molecule, Materials science, Hydrogen bond, Pathology, Alternative medicine, Medicine

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Cited by: 26

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Citations by year (recent): 2025: 5, 2024: 2, 2023: 5, 2022: 9, 2021: 5

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Related works (count): 10

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