Interrogating the Role of Stack Pressure in Transport‐Reaction Interaction in the Solid‐State Battery Cathode Article Swipe
YOU?
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· 2024
· Open Access
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· DOI: https://doi.org/10.1002/aenm.202403360
As solid‐state batteries (SSBs) emerge as leading contenders for next‐generation energy storage, chemo‐mechanical challenges and instabilities at solid‐solid interfaces remain a critical bottleneck. Ensuring sufficient interfacial contact within composite cathode architectures often requires the application of high stack pressures, posing a significant hurdle in the development of viable, large‐scale SSBs. In this work, the impact of stack pressure is investigated on the performance of solid‐state composite cathodes comprised of single‐crystal LiNi 0.5 Mn 0.3 Co 0.2 O 2 (SC‐NMC532) active material particles and a Li 6 PS 5 Cl (LPSCl) solid electrolyte phase. By unraveling the complex interplay between stack pressure and microstructure‐dependent mechanisms, the profound influence on interfacial resistances, cathode utilization dynamics, current constriction effects, and lithiation heterogeneities are revealed. Through a comprehensive examination of coupled reaction kinetics and transport interactions at the electrode and particle length scales, the implications of stack pressure at different C‐rates and microstructural arrangements are elucidated, thereby delineating the limiting mechanisms that are prevalent at low stack pressures. This work underscores the critical role of optimizing the cathode microstructure to mitigate the chemo‐mechanical challenges associated with SSB operation at low stack pressures, offering valuable insights and design guidelines for the development of high‐performance SSBs.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/aenm.202403360
- OA Status
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- Cited By
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- OpenAlex ID
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Raw OpenAlex JSON
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https://openalex.org/W4403615241Canonical identifier for this work in OpenAlex
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https://doi.org/10.1002/aenm.202403360Digital Object Identifier
- Title
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Interrogating the Role of Stack Pressure in Transport‐Reaction Interaction in the Solid‐State Battery CathodeWork title
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articleOpenAlex work type
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enPrimary language
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2024Year of publication
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2024-10-20Full publication date if available
- Authors
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Kaustubh G. Naik, Manoj K. Jangid, Bairav S. Vishnugopi, Neil P. Dasgupta, Partha P. MukherjeeList of authors in order
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https://doi.org/10.1002/aenm.202403360Publisher landing page
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://doi.org/10.1002/aenm.202403360Direct OA link when available
- Concepts
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Materials science, Stack (abstract data type), Cathode, Battery (electricity), Solid-state, State (computer science), Chemical physics, Nanotechnology, Chemical engineering, Engineering physics, Thermodynamics, Electrical engineering, Computer science, Power (physics), Engineering, Programming language, Algorithm, PhysicsTop concepts (fields/topics) attached by OpenAlex
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15Total citation count in OpenAlex
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2025: 15Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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| primary_location.raw_source_name | Advanced Energy Materials |
| primary_location.landing_page_url | https://doi.org/10.1002/aenm.202403360 |
| publication_date | 2024-10-20 |
| publication_year | 2024 |
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