Investigation of Electronic Structures of Triplet States Using Step-Scan Time-Resolved Fourier-Transform Near-Infrared Spectroscopy Article Swipe

PDF

Chia‐Chun Wu , Yu-Xiang Tsai , Li‐Kang Chu , I‐Chia Chen ·

YOU? · · 2024 · Open Access · · DOI: https://doi.org/10.1021/acs.jpclett.3c03521

Triplet transitions of light-emitting materials, including rose bengal, tris(2-phenylpyridine)iridium(III) [Ir(ppy)₃], tris(1-phenylisoquinoline)iridium(III) [Ir(piq)₃], and bis[2-(4,6-difluorophenyl)pyridinato-C2,N](picolinato)iridium(III) (FIrpic), were studied using step-scan time-resolved Fourier-transform near-infrared spectroscopy. The samples were excited to their singlet excited states by a 355 nm laser and then underwent efficient conversions/crossings to their triplet manifolds. For rose bengal, a transient absorption band appeared at 9400 cm^-1, attributed to the T₃ ← T₁ transition based on the corresponding time evolution and the theoretical calculations. For Ir(ppy)₃, Ir(piq)₃, and FIrpic, the most intense bands were observed at 7700, 7500, and 7500 cm^-1 and assigned to T₇ ← T₁, T₆ ← T₁, and T₆ ← T₁ transitions, respectively. For Ir(ppy)₃, the most intense band involved transitions between different triplet metal-to-ligand charge transfer (³MLCT) states, while for Ir(piq)₃ and FIrpic, they involved a metal center to ³MLCT transition. These T₁ states were assigned to ³MLCT.

Related Topics

Fourier-Transform Infrared Spectroscopy

Infrared Spectroscopy

Optics

Nuclear Magnetic Resonance

Physics

Quantum Mechanics

Concepts

Fourier transform infrared spectroscopy Fourier transform spectroscopy Fourier transform Infrared Spectroscopy Materials science Infrared spectroscopy Optics Nuclear magnetic resonance Physics Quantum mechanics

Metadata

Type: article
Language: en
Landing Page: https://doi.org/10.1021/acs.jpclett.3c03521
PDF: https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.3c03521
OA Status: hybrid
Cited By: 2
References: 39
Related Works: 10
OpenAlex ID: https://openalex.org/W4391035700

All OpenAlex metadata

Raw OpenAlex JSON

OpenAlex ID: https://openalex.org/W4391035700

Canonical identifier for this work in OpenAlex
DOI: https://doi.org/10.1021/acs.jpclett.3c03521

Digital Object Identifier
Title: Investigation of Electronic Structures of Triplet States Using Step-Scan Time-Resolved Fourier-Transform Near-Infrared Spectroscopy

Work title
Type: article

OpenAlex work type
Language: en

Primary language
Publication year: 2024

Year of publication
Publication date: 2024-01-19

Full publication date if available
Authors: Chia‐Chun Wu, Yu-Xiang Tsai, Li‐Kang Chu, I‐Chia Chen

List of authors in order
Landing page: https://doi.org/10.1021/acs.jpclett.3c03521

Publisher landing page
PDF URL: https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.3c03521

Direct link to full text PDF
Open access: Yes

Whether a free full text is available
OA status: hybrid

Open access status per OpenAlex
OA URL: https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.3c03521

Direct OA link when available
Concepts: Fourier transform infrared spectroscopy, Fourier transform spectroscopy, Fourier transform, Infrared, Spectroscopy, Materials science, Infrared spectroscopy, Optics, Nuclear magnetic resonance, Physics, Quantum mechanics

Top concepts (fields/topics) attached by OpenAlex
Cited by: 2

Total citation count in OpenAlex
Citations by year (recent): 2024: 2

Per-year citation counts (last 5 years)
References (count): 39

Number of works referenced by this work
Related works (count): 10

Other works algorithmically related by OpenAlex

Full payload

id	https://openalex.org/W4391035700
doi	https://doi.org/10.1021/acs.jpclett.3c03521
ids.doi	https://doi.org/10.1021/acs.jpclett.3c03521
ids.pmid	https://pubmed.ncbi.nlm.nih.gov/38241171
ids.openalex	https://openalex.org/W4391035700
fwci	0.33868835
type	article
title	Investigation of Electronic Structures of Triplet States Using Step-Scan Time-Resolved Fourier-Transform Near-Infrared Spectroscopy
awards[0].id	https://openalex.org/G780300848
awards[0].funder_id	https://openalex.org/F4320321540
awards[0].display_name
awards[0].funder_award_id	109-2628-M-007-004-MY3
awards[0].funder_display_name	Ministry of Science and Technology of the People's Republic of China
awards[1].id	https://openalex.org/G7882127125
awards[1].funder_id	https://openalex.org/F4320321540
awards[1].display_name
awards[1].funder_award_id	111-2113-M-007-028
awards[1].funder_display_name	Ministry of Science and Technology of the People's Republic of China
biblio.issue	4
biblio.volume	15
biblio.last_page	918
biblio.first_page	912
topics[0].id	https://openalex.org/T11240
topics[0].field.id	https://openalex.org/fields/25
topics[0].field.display_name	Materials Science
topics[0].score	0.9998999834060669
topics[0].domain.id	https://openalex.org/domains/3
topics[0].domain.display_name	Physical Sciences
topics[0].subfield.id	https://openalex.org/subfields/2505
topics[0].subfield.display_name	Materials Chemistry
topics[0].display_name	Luminescence and Fluorescent Materials
topics[1].id	https://openalex.org/T10611
topics[1].field.id	https://openalex.org/fields/22
topics[1].field.display_name	Engineering
topics[1].score	0.9984999895095825
topics[1].domain.id	https://openalex.org/domains/3
topics[1].domain.display_name	Physical Sciences
topics[1].subfield.id	https://openalex.org/subfields/2208
topics[1].subfield.display_name	Electrical and Electronic Engineering
topics[1].display_name	Organic Light-Emitting Diodes Research
topics[2].id	https://openalex.org/T10247
topics[2].field.id	https://openalex.org/fields/22
topics[2].field.display_name	Engineering
topics[2].score	0.9952999949455261
topics[2].domain.id	https://openalex.org/domains/3
topics[2].domain.display_name	Physical Sciences
topics[2].subfield.id	https://openalex.org/subfields/2208
topics[2].subfield.display_name	Electrical and Electronic Engineering
topics[2].display_name	Perovskite Materials and Applications
funders[0].id	https://openalex.org/F4320321540
funders[0].ror	https://ror.org/027s68j25
funders[0].display_name	Ministry of Science and Technology of the People's Republic of China
is_xpac	False
apc_list
apc_paid
concepts[0].id	https://openalex.org/C160892712
concepts[0].level	2
concepts[0].score	0.7064942717552185
concepts[0].wikidata	https://www.wikidata.org/wiki/Q901559
concepts[0].display_name	Fourier transform infrared spectroscopy
concepts[1].id	https://openalex.org/C41610221
concepts[1].level	3
concepts[1].score	0.6904377937316895
concepts[1].wikidata	https://www.wikidata.org/wiki/Q2047974
concepts[1].display_name	Fourier transform spectroscopy
concepts[2].id	https://openalex.org/C102519508
concepts[2].level	2
concepts[2].score	0.6570296883583069
concepts[2].wikidata	https://www.wikidata.org/wiki/Q6520159
concepts[2].display_name	Fourier transform
concepts[3].id	https://openalex.org/C158355884
concepts[3].level	2
concepts[3].score	0.6050930023193359
concepts[3].wikidata	https://www.wikidata.org/wiki/Q11388
concepts[3].display_name	Infrared
concepts[4].id	https://openalex.org/C32891209
concepts[4].level	2
concepts[4].score	0.5733805298805237
concepts[4].wikidata	https://www.wikidata.org/wiki/Q483666
concepts[4].display_name	Spectroscopy
concepts[5].id	https://openalex.org/C192562407
concepts[5].level	0
concepts[5].score	0.4760670065879822
concepts[5].wikidata	https://www.wikidata.org/wiki/Q228736
concepts[5].display_name	Materials science
concepts[6].id	https://openalex.org/C153642686
concepts[6].level	2
concepts[6].score	0.4192236661911011
concepts[6].wikidata	https://www.wikidata.org/wiki/Q70906
concepts[6].display_name	Infrared spectroscopy
concepts[7].id	https://openalex.org/C120665830
concepts[7].level	1
concepts[7].score	0.3509436845779419
concepts[7].wikidata	https://www.wikidata.org/wiki/Q14620
concepts[7].display_name	Optics
concepts[8].id	https://openalex.org/C46141821
concepts[8].level	1
concepts[8].score	0.32918763160705566
concepts[8].wikidata	https://www.wikidata.org/wiki/Q209402
concepts[8].display_name	Nuclear magnetic resonance
concepts[9].id	https://openalex.org/C121332964
concepts[9].level	0
concepts[9].score	0.26888442039489746
concepts[9].wikidata	https://www.wikidata.org/wiki/Q413
concepts[9].display_name	Physics
concepts[10].id	https://openalex.org/C62520636
concepts[10].level	1
concepts[10].score	0.0
concepts[10].wikidata	https://www.wikidata.org/wiki/Q944
concepts[10].display_name	Quantum mechanics
keywords[0].id	https://openalex.org/keywords/fourier-transform-infrared-spectroscopy
keywords[0].score	0.7064942717552185
keywords[0].display_name	Fourier transform infrared spectroscopy
keywords[1].id	https://openalex.org/keywords/fourier-transform-spectroscopy
keywords[1].score	0.6904377937316895
keywords[1].display_name	Fourier transform spectroscopy
keywords[2].id	https://openalex.org/keywords/fourier-transform
keywords[2].score	0.6570296883583069
keywords[2].display_name	Fourier transform
keywords[3].id	https://openalex.org/keywords/infrared
keywords[3].score	0.6050930023193359
keywords[3].display_name	Infrared
keywords[4].id	https://openalex.org/keywords/spectroscopy
keywords[4].score	0.5733805298805237
keywords[4].display_name	Spectroscopy
keywords[5].id	https://openalex.org/keywords/materials-science
keywords[5].score	0.4760670065879822
keywords[5].display_name	Materials science
keywords[6].id	https://openalex.org/keywords/infrared-spectroscopy
keywords[6].score	0.4192236661911011
keywords[6].display_name	Infrared spectroscopy
keywords[7].id	https://openalex.org/keywords/optics
keywords[7].score	0.3509436845779419
keywords[7].display_name	Optics
keywords[8].id	https://openalex.org/keywords/nuclear-magnetic-resonance
keywords[8].score	0.32918763160705566
keywords[8].display_name	Nuclear magnetic resonance
keywords[9].id	https://openalex.org/keywords/physics
keywords[9].score	0.26888442039489746
keywords[9].display_name	Physics
language	en
locations[0].id	doi:10.1021/acs.jpclett.3c03521
locations[0].is_oa	True
locations[0].source.id	https://openalex.org/S123480357
locations[0].source.issn	1948-7185
locations[0].source.type	journal
locations[0].source.is_oa	False
locations[0].source.issn_l	1948-7185
locations[0].source.is_core	True
locations[0].source.is_in_doaj	False
locations[0].source.display_name	The Journal of Physical Chemistry Letters
locations[0].source.host_organization	https://openalex.org/P4310320006
locations[0].source.host_organization_name	American Chemical Society
locations[0].source.host_organization_lineage	https://openalex.org/P4310320006
locations[0].source.host_organization_lineage_names	American Chemical Society
locations[0].license	cc-by
locations[0].pdf_url	https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.3c03521
locations[0].version	publishedVersion
locations[0].raw_type	journal-article
locations[0].license_id	https://openalex.org/licenses/cc-by
locations[0].is_accepted	True
locations[0].is_published	True
locations[0].raw_source_name	The Journal of Physical Chemistry Letters
locations[0].landing_page_url	https://doi.org/10.1021/acs.jpclett.3c03521
locations[1].id	pmid:38241171
locations[1].is_oa	False
locations[1].source.id	https://openalex.org/S4306525036
locations[1].source.issn
locations[1].source.type	repository
locations[1].source.is_oa	False
locations[1].source.issn_l
locations[1].source.is_core	False
locations[1].source.is_in_doaj	False
locations[1].source.display_name	PubMed
locations[1].source.host_organization	https://openalex.org/I1299303238
locations[1].source.host_organization_name	National Institutes of Health
locations[1].source.host_organization_lineage	https://openalex.org/I1299303238
locations[1].license
locations[1].pdf_url
locations[1].version	publishedVersion
locations[1].raw_type
locations[1].license_id
locations[1].is_accepted	True
locations[1].is_published	True
locations[1].raw_source_name	The journal of physical chemistry letters
locations[1].landing_page_url	https://pubmed.ncbi.nlm.nih.gov/38241171
locations[2].id	pmh:oai:pubmedcentral.nih.gov:10839901
locations[2].is_oa	True
locations[2].source.id	https://openalex.org/S2764455111
locations[2].source.issn
locations[2].source.type	repository
locations[2].source.is_oa	False
locations[2].source.issn_l
locations[2].source.is_core	False
locations[2].source.is_in_doaj	False
locations[2].source.display_name	PubMed Central
locations[2].source.host_organization	https://openalex.org/I1299303238
locations[2].source.host_organization_name	National Institutes of Health
locations[2].source.host_organization_lineage	https://openalex.org/I1299303238
locations[2].license	cc-by
locations[2].pdf_url	https://pmc.ncbi.nlm.nih.gov/articles/PMC10839901/pdf/jz3c03521.pdf
locations[2].version	submittedVersion
locations[2].raw_type	Text
locations[2].license_id	https://openalex.org/licenses/cc-by
locations[2].is_accepted	False
locations[2].is_published	False
locations[2].raw_source_name	J Phys Chem Lett
locations[2].landing_page_url	https://www.ncbi.nlm.nih.gov/pmc/articles/10839901
indexed_in	crossref, pubmed
authorships[0].author.id	https://openalex.org/A5101704467
authorships[0].author.orcid	https://orcid.org/0000-0003-2563-8679
authorships[0].author.display_name	Chia‐Chun Wu
authorships[0].countries	TW
authorships[0].affiliations[0].institution_ids	https://openalex.org/I25846049
authorships[0].affiliations[0].raw_affiliation_string	Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300044, Republic of China
authorships[0].institutions[0].id	https://openalex.org/I25846049
authorships[0].institutions[0].ror	https://ror.org/00zdnkx70
authorships[0].institutions[0].type	education
authorships[0].institutions[0].lineage	https://openalex.org/I25846049
authorships[0].institutions[0].country_code	TW
authorships[0].institutions[0].display_name	National Tsing Hua University
authorships[0].author_position	first
authorships[0].raw_author_name	Chia Chun Wu
authorships[0].is_corresponding	False
authorships[0].raw_affiliation_strings	Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300044, Republic of China
authorships[1].author.id	https://openalex.org/A5108895027
authorships[1].author.orcid
authorships[1].author.display_name	Yu-Xiang Tsai
authorships[1].countries	TW
authorships[1].affiliations[0].institution_ids	https://openalex.org/I25846049
authorships[1].affiliations[0].raw_affiliation_string	Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300044, Republic of China
authorships[1].institutions[0].id	https://openalex.org/I25846049
authorships[1].institutions[0].ror	https://ror.org/00zdnkx70
authorships[1].institutions[0].type	education
authorships[1].institutions[0].lineage	https://openalex.org/I25846049
authorships[1].institutions[0].country_code	TW
authorships[1].institutions[0].display_name	National Tsing Hua University
authorships[1].author_position	middle
authorships[1].raw_author_name	Yu-Xiang Tsai
authorships[1].is_corresponding	False
authorships[1].raw_affiliation_strings	Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300044, Republic of China
authorships[2].author.id	https://openalex.org/A5017321913
authorships[2].author.orcid	https://orcid.org/0000-0001-6080-9598
authorships[2].author.display_name	Li‐Kang Chu
authorships[2].countries	TW
authorships[2].affiliations[0].institution_ids	https://openalex.org/I25846049
authorships[2].affiliations[0].raw_affiliation_string	Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300044, Republic of China
authorships[2].institutions[0].id	https://openalex.org/I25846049
authorships[2].institutions[0].ror	https://ror.org/00zdnkx70
authorships[2].institutions[0].type	education
authorships[2].institutions[0].lineage	https://openalex.org/I25846049
authorships[2].institutions[0].country_code	TW
authorships[2].institutions[0].display_name	National Tsing Hua University
authorships[2].author_position	middle
authorships[2].raw_author_name	Li-Kang Chu
authorships[2].is_corresponding	True
authorships[2].raw_affiliation_strings	Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300044, Republic of China
authorships[3].author.id	https://openalex.org/A5013264546
authorships[3].author.orcid	https://orcid.org/0000-0002-5821-6416
authorships[3].author.display_name	I‐Chia Chen
authorships[3].countries	TW
authorships[3].affiliations[0].institution_ids	https://openalex.org/I25846049
authorships[3].affiliations[0].raw_affiliation_string	Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300044, Republic of China
authorships[3].institutions[0].id	https://openalex.org/I25846049
authorships[3].institutions[0].ror	https://ror.org/00zdnkx70
authorships[3].institutions[0].type	education
authorships[3].institutions[0].lineage	https://openalex.org/I25846049
authorships[3].institutions[0].country_code	TW
authorships[3].institutions[0].display_name	National Tsing Hua University
authorships[3].author_position	last
authorships[3].raw_author_name	I-Chia Chen
authorships[3].is_corresponding	True
authorships[3].raw_affiliation_strings	Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300044, Republic of China
has_content.pdf	True
has_content.grobid_xml	False
is_paratext	False
open_access.is_oa	True
open_access.oa_url	https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.3c03521
open_access.oa_status	hybrid
open_access.any_repository_has_fulltext	False
created_date	2025-10-10T00:00:00
display_name	Investigation of Electronic Structures of Triplet States Using Step-Scan Time-Resolved Fourier-Transform Near-Infrared Spectroscopy
has_fulltext	False
is_retracted	False
updated_date	2025-11-06T03:46:38.306776
primary_topic.id	https://openalex.org/T11240
primary_topic.field.id	https://openalex.org/fields/25
primary_topic.field.display_name	Materials Science
primary_topic.score	0.9998999834060669
primary_topic.domain.id	https://openalex.org/domains/3
primary_topic.domain.display_name	Physical Sciences
primary_topic.subfield.id	https://openalex.org/subfields/2505
primary_topic.subfield.display_name	Materials Chemistry
primary_topic.display_name	Luminescence and Fluorescent Materials
related_works	https://openalex.org/W2135375667, https://openalex.org/W4323652357, https://openalex.org/W4236933654, https://openalex.org/W2008512696, https://openalex.org/W2916853706, https://openalex.org/W2018674345, https://openalex.org/W2469340274, https://openalex.org/W117824151, https://openalex.org/W1982027788, https://openalex.org/W2490963019
cited_by_count	2
counts_by_year[0].year	2024
counts_by_year[0].cited_by_count	2
locations_count	3
best_oa_location.id	doi:10.1021/acs.jpclett.3c03521
best_oa_location.is_oa	True
best_oa_location.source.id	https://openalex.org/S123480357
best_oa_location.source.issn	1948-7185
best_oa_location.source.type	journal
best_oa_location.source.is_oa	False
best_oa_location.source.issn_l	1948-7185
best_oa_location.source.is_core	True
best_oa_location.source.is_in_doaj	False
best_oa_location.source.display_name	The Journal of Physical Chemistry Letters
best_oa_location.source.host_organization	https://openalex.org/P4310320006
best_oa_location.source.host_organization_name	American Chemical Society
best_oa_location.source.host_organization_lineage	https://openalex.org/P4310320006
best_oa_location.source.host_organization_lineage_names	American Chemical Society
best_oa_location.license	cc-by
best_oa_location.pdf_url	https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.3c03521
best_oa_location.version	publishedVersion
best_oa_location.raw_type	journal-article
best_oa_location.license_id	https://openalex.org/licenses/cc-by
best_oa_location.is_accepted	True
best_oa_location.is_published	True
best_oa_location.raw_source_name	The Journal of Physical Chemistry Letters
best_oa_location.landing_page_url	https://doi.org/10.1021/acs.jpclett.3c03521
primary_location.id	doi:10.1021/acs.jpclett.3c03521
primary_location.is_oa	True
primary_location.source.id	https://openalex.org/S123480357
primary_location.source.issn	1948-7185
primary_location.source.type	journal
primary_location.source.is_oa	False
primary_location.source.issn_l	1948-7185
primary_location.source.is_core	True
primary_location.source.is_in_doaj	False
primary_location.source.display_name	The Journal of Physical Chemistry Letters
primary_location.source.host_organization	https://openalex.org/P4310320006
primary_location.source.host_organization_name	American Chemical Society
primary_location.source.host_organization_lineage	https://openalex.org/P4310320006
primary_location.source.host_organization_lineage_names	American Chemical Society
primary_location.license	cc-by
primary_location.pdf_url	https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.3c03521
primary_location.version	publishedVersion
primary_location.raw_type	journal-article
primary_location.license_id	https://openalex.org/licenses/cc-by
primary_location.is_accepted	True
primary_location.is_published	True
primary_location.raw_source_name	The Journal of Physical Chemistry Letters
primary_location.landing_page_url	https://doi.org/10.1021/acs.jpclett.3c03521
publication_date	2024-01-19
publication_year	2024
referenced_works	https://openalex.org/W2078445791, https://openalex.org/W2024819813, https://openalex.org/W2126811792, https://openalex.org/W2144197904, https://openalex.org/W2781914409, https://openalex.org/W2413618376, https://openalex.org/W2314938964, https://openalex.org/W2792839694, https://openalex.org/W2019037012, https://openalex.org/W2786633572, https://openalex.org/W2918182973, https://openalex.org/W2327467382, https://openalex.org/W3213225228, https://openalex.org/W4380551357, https://openalex.org/W4367048012, https://openalex.org/W3166313966, https://openalex.org/W2319458912, https://openalex.org/W2164782128, https://openalex.org/W4310699965, https://openalex.org/W4213340548, https://openalex.org/W4283268802, https://openalex.org/W4211020071, https://openalex.org/W4206354735, https://openalex.org/W2619959352, https://openalex.org/W4386095620, https://openalex.org/W2027035378, https://openalex.org/W2335049268, https://openalex.org/W2089301877, https://openalex.org/W2037733439, https://openalex.org/W2808077398, https://openalex.org/W2770151295, https://openalex.org/W2046792324, https://openalex.org/W2328714650, https://openalex.org/W2135076719, https://openalex.org/W2020995304, https://openalex.org/W4212781900, https://openalex.org/W2064781341, https://openalex.org/W4293117075, https://openalex.org/W2039559098
referenced_works_count	39
abstract_inverted_index.a	33, 49, 129
abstract_inverted_index.at	54, 85
abstract_inverted_index.by	32
abstract_inverted_index.nm	35
abstract_inverted_index.of	2
abstract_inverted_index.on	65
abstract_inverted_index.to	27, 42, 58, 93, 132, 140
abstract_inverted_index.355	34
abstract_inverted_index.For	46, 74, 106
abstract_inverted_index.The	23
abstract_inverted_index.and	12, 37, 70, 77, 88, 91, 100, 125
abstract_inverted_index.for	123
abstract_inverted_index.the	59, 66, 71, 79, 108
abstract_inverted_index.←	61, 95, 98, 102
abstract_inverted_index.7500	89
abstract_inverted_index.9400	55
abstract_inverted_index.band	52, 111
abstract_inverted_index.most	80, 109
abstract_inverted_index.rose	6, 47
abstract_inverted_index.then	38
abstract_inverted_index.they	127
abstract_inverted_index.time	68
abstract_inverted_index.were	15, 25, 83, 138
abstract_inverted_index.7500,	87
abstract_inverted_index.7700,	86
abstract_inverted_index.These	135
abstract_inverted_index.bands	82
abstract_inverted_index.based	64
abstract_inverted_index.laser	36
abstract_inverted_index.metal	130
abstract_inverted_index.their	28, 43
abstract_inverted_index.using	17
abstract_inverted_index.while	122
abstract_inverted_index.center	131
abstract_inverted_index.charge	118
abstract_inverted_index.states	31, 137
abstract_inverted_index.FIrpic,	78, 126
abstract_inverted_index.Triplet	0
abstract_inverted_index.bengal,	7, 48
abstract_inverted_index.between	114
abstract_inverted_index.excited	26, 30
abstract_inverted_index.intense	81, 110
abstract_inverted_index.samples	24
abstract_inverted_index.singlet	29
abstract_inverted_index.states,	121
abstract_inverted_index.studied	16
abstract_inverted_index.triplet	44, 116
abstract_inverted_index.appeared	53
abstract_inverted_index.assigned	92, 139
abstract_inverted_index.involved	112, 128
abstract_inverted_index.observed	84
abstract_inverted_index.transfer	119
abstract_inverted_index.(FIrpic),	14
abstract_inverted_index.different	115
abstract_inverted_index.efficient	40
abstract_inverted_index.evolution	69
abstract_inverted_index.including	5
abstract_inverted_index.step-scan	18
abstract_inverted_index.transient	50
abstract_inverted_index.underwent	39
abstract_inverted_index.absorption	51
abstract_inverted_index.attributed	57
abstract_inverted_index.manifolds.	45
abstract_inverted_index.materials,	4
abstract_inverted_index.transition	63
abstract_inverted_index.theoretical	72
abstract_inverted_index.transition.	134
abstract_inverted_index.transitions	1, 113
abstract_inverted_index.transitions,	104
abstract_inverted_index.T<sub>1</sub>	62, 103, 136
abstract_inverted_index.T<sub>3</sub>	60
abstract_inverted_index.T<sub>6</sub>	97, 101
abstract_inverted_index.T<sub>7</sub>	94
abstract_inverted_index.calculations.	73
abstract_inverted_index.corresponding	67
abstract_inverted_index.near-infrared	21
abstract_inverted_index.respectively.	105
abstract_inverted_index.spectroscopy.	22
abstract_inverted_index.time-resolved	19
abstract_inverted_index.T<sub>1</sub>,	96, 99
abstract_inverted_index.light-emitting	3
abstract_inverted_index.cm<sup>-1</sup>	90
abstract_inverted_index.metal-to-ligand	117
abstract_inverted_index.<sup>3</sup>MLCT	133
abstract_inverted_index.cm<sup>-1</sup>,	56
abstract_inverted_index.<sup>3</sup>MLCT.	141
abstract_inverted_index.Fourier-transform	20
abstract_inverted_index.(<sup>3</sup>MLCT)	120
abstract_inverted_index.Ir(piq)<sub>3</sub>	124
abstract_inverted_index.Ir(piq)<sub>3</sub>,	76
abstract_inverted_index.Ir(ppy)<sub>3</sub>,	75, 107
abstract_inverted_index.conversions/crossings	41
abstract_inverted_index.[Ir(piq)<sub>3</sub>],	11
abstract_inverted_index.[Ir(ppy)<sub>3</sub>],	9
abstract_inverted_index.tris(2-phenylpyridine)iridium(III)	8
abstract_inverted_index.tris(1-phenylisoquinoline)iridium(III)	10
abstract_inverted_index.bis[2-(4,6-difluorophenyl)pyridinato-C2,N](picolinato)iridium(III)	13
cited_by_percentile_year.max	96
cited_by_percentile_year.min	94
corresponding_author_ids	https://openalex.org/A5017321913, https://openalex.org/A5013264546
countries_distinct_count	1
institutions_distinct_count	4
corresponding_institution_ids	https://openalex.org/I25846049
citation_normalized_percentile.value	0.51769997
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	False