Isotropic Low Thermal Expansion over a Wide Temperature Range in Ti1–xZrxF3+x (0.1 ≤ x ≤ 0.5) Solid Solutions Article Swipe
Cheng Yang
,
Yugang Zhang
,
Jianming Bai
,
Peng Tong
,
Jianchao Lin
,
Haiyun Tong
,
Lei Zhang
,
Wen Wen
,
Xingmin Zhang
,
Yuping Sun
·
YOU?
·
· 2018
· Open Access
·
· DOI: https://doi.org/10.1021/acs.inorgchem.8b02593
YOU?
·
· 2018
· Open Access
·
· DOI: https://doi.org/10.1021/acs.inorgchem.8b02593
TiF3 exhibits a rhombohedral to ReO3-type cubic phase transformation at ∼340 K. Here we report that, by introducing ZrF4 into TiF3, the cubic phase is stabilized at least down to 123 K in the Ti1- xZr xF3+ x compounds. All compounds exhibit low thermal expansion (LTE) between 123 and 623 K, and a nearly zero thermal expansion (ZTE) was obtained in Ti0.7Zr0.3F3.3 (αL = 0.91 ppm/K). The analysis of pair distribution function reveals that the cation-centered octahedra are partially changed to pentagonal bipyramids in Ti1- xZr xF3+ x due to the excess fluorines relative to the case of TiF3. Therefore, the cooperative rotation of the polyhedra tends to be restricted, and the cubic phase is thus stabilized. The restrained polyhedral rotations compete against the lattice softening caused by the introduction of Zr4+, giving rise to the LTE. Our present strategy is applicable to other rhombohedral metal trifluorides for the design of new isotropic ZTE materials.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.inorgchem.8b02593
- OA Status
- green
- Cited By
- 11
- References
- 27
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2899500380
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Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2899500380Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.inorgchem.8b02593Digital Object Identifier
- Title
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Isotropic Low Thermal Expansion over a Wide Temperature Range in Ti1–xZrxF3+x (0.1 ≤ x ≤ 0.5) Solid SolutionsWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2018Year of publication
- Publication date
-
2018-10-31Full publication date if available
- Authors
-
Cheng Yang, Yugang Zhang, Jianming Bai, Peng Tong, Jianchao Lin, Haiyun Tong, Lei Zhang, Wen Wen, Xingmin Zhang, Yuping SunList of authors in order
- Landing page
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https://doi.org/10.1021/acs.inorgchem.8b02593Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
- OA URL
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https://www.osti.gov/biblio/1487256Direct OA link when available
- Concepts
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Chemistry, Thermal expansion, Isotropy, Atmospheric temperature range, Range (aeronautics), Thermal, Negative thermal expansion, Crystallography, X-ray crystallography, Mineralogy, Condensed matter physics, Thermodynamics, Composite material, Diffraction, Optics, Physics, Materials scienceTop concepts (fields/topics) attached by OpenAlex
- Cited by
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11Total citation count in OpenAlex
- Citations by year (recent)
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2023: 2, 2022: 3, 2021: 2, 2020: 3, 2019: 1Per-year citation counts (last 5 years)
- References (count)
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27Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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| cited_by_percentile_year.min | 90 |
| corresponding_author_ids | https://openalex.org/A5100399502, https://openalex.org/A5012194233 |
| countries_distinct_count | 2 |
| institutions_distinct_count | 10 |
| corresponding_institution_ids | https://openalex.org/I126520041, https://openalex.org/I19820366, https://openalex.org/I4210102600, https://openalex.org/I4210154057 |
| citation_normalized_percentile.value | 0.63681033 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |