Large orbital magnetic moment in VI3 Article Swipe

PDF

David Hovancik , Cínthia Piamonteze , Jiří Pospíšil , Karel Carva , V. Sechovský ·

YOU? · · 2022 · Open Access · · DOI: https://doi.org/10.48550/arxiv.2210.11278

The existence of the V3+ ion orbital moment is the open issue of the nature of magnetism in the van der Waals ferromagnet VI3. The huge magnetocrystalline anisotropy in conjunction with the significantly reduced ordered magnetic moment compared to the spin-only value provides strong but indirect evidence of a significant V orbital moment. We used the unique capability of X-ray magnetic circular dichroism to determine the orbital component of the total magnetic moment and provide for the first time a direct proof of an exceptionally sizable orbital moment of the V3+ ion in VI3. Our ligand field multiplet simulations of the XMCD spectra in synergy with the results of DFT calculations agree with the existence of two V sites with different orbital occupations and therefore different OM magnitudes in the ground state.

Related Topics

Condensed Matter Physics

Concepts

Magnetic circular dichroism Condensed matter physics Magnetic moment Electron magnetic dipole moment Nuclear magnetic moment Physics Magnetic anisotropy Magnetocrystalline anisotropy Magnetism Spin magnetic moment Neutron magnetic moment Multiplet Ligand field theory Atomic orbital Chemistry Magnetic dipole Ion Magnetic field Quantum mechanics Spectral line Electron Magnetization

Metadata

Type: preprint
Language: en
Landing Page: http://arxiv.org/abs/2210.11278
PDF: https://arxiv.org/pdf/2210.11278
OA Status: green
Related Works: 10
OpenAlex ID: https://openalex.org/W4307078208

All OpenAlex metadata

Raw OpenAlex JSON

OpenAlex ID: https://openalex.org/W4307078208

Canonical identifier for this work in OpenAlex
DOI: https://doi.org/10.48550/arxiv.2210.11278

Digital Object Identifier
Title: Large orbital magnetic moment in VI3

Work title
Type: preprint

OpenAlex work type
Language: en

Primary language
Publication year: 2022

Year of publication
Publication date: 2022-10-20

Full publication date if available
Authors: David Hovancik, Cínthia Piamonteze, Jiří Pospíšil, Karel Carva, V. Sechovský

List of authors in order
Landing page: https://arxiv.org/abs/2210.11278

Publisher landing page
PDF URL: https://arxiv.org/pdf/2210.11278

Direct link to full text PDF
Open access: Yes

Whether a free full text is available
OA status: green

Open access status per OpenAlex
OA URL: https://arxiv.org/pdf/2210.11278

Direct OA link when available
Concepts: Magnetic circular dichroism, Condensed matter physics, Magnetic moment, Electron magnetic dipole moment, Nuclear magnetic moment, Physics, Magnetic anisotropy, Magnetocrystalline anisotropy, Magnetism, Spin magnetic moment, Neutron magnetic moment, Multiplet, Ligand field theory, Atomic orbital, Chemistry, Magnetic dipole, Ion, Magnetic field, Quantum mechanics, Spectral line, Electron, Magnetization

Top concepts (fields/topics) attached by OpenAlex
Cited by: 0

Total citation count in OpenAlex
Related works (count): 10

Other works algorithmically related by OpenAlex

Full payload

id	https://openalex.org/W4307078208
doi	https://doi.org/10.48550/arxiv.2210.11278
ids.doi	https://doi.org/10.48550/arxiv.2210.11278
ids.openalex	https://openalex.org/W4307078208
fwci	0.0
type	preprint
title	Large orbital magnetic moment in VI3
biblio.issue
biblio.volume
biblio.last_page
biblio.first_page
topics[0].id	https://openalex.org/T10002
topics[0].field.id	https://openalex.org/fields/31
topics[0].field.display_name	Physics and Astronomy
topics[0].score	0.998199999332428
topics[0].domain.id	https://openalex.org/domains/3
topics[0].domain.display_name	Physical Sciences
topics[0].subfield.id	https://openalex.org/subfields/3107
topics[0].subfield.display_name	Atomic and Molecular Physics, and Optics
topics[0].display_name	Advanced Chemical Physics Studies
topics[1].id	https://openalex.org/T11682
topics[1].field.id	https://openalex.org/fields/31
topics[1].field.display_name	Physics and Astronomy
topics[1].score	0.9954000115394592
topics[1].domain.id	https://openalex.org/domains/3
topics[1].domain.display_name	Physical Sciences
topics[1].subfield.id	https://openalex.org/subfields/3104
topics[1].subfield.display_name	Condensed Matter Physics
topics[1].display_name	Advanced Condensed Matter Physics
topics[2].id	https://openalex.org/T10612
topics[2].field.id	https://openalex.org/fields/25
topics[2].field.display_name	Materials Science
topics[2].score	0.9908999800682068
topics[2].domain.id	https://openalex.org/domains/3
topics[2].domain.display_name	Physical Sciences
topics[2].subfield.id	https://openalex.org/subfields/2504
topics[2].subfield.display_name	Electronic, Optical and Magnetic Materials
topics[2].display_name	Magnetism in coordination complexes
is_xpac	False
apc_list
apc_paid
concepts[0].id	https://openalex.org/C68563686
concepts[0].level	3
concepts[0].score	0.6494255661964417
concepts[0].wikidata	https://www.wikidata.org/wiki/Q6731531
concepts[0].display_name	Magnetic circular dichroism
concepts[1].id	https://openalex.org/C26873012
concepts[1].level	1
concepts[1].score	0.647415816783905
concepts[1].wikidata	https://www.wikidata.org/wiki/Q214781
concepts[1].display_name	Condensed matter physics
concepts[2].id	https://openalex.org/C54553102
concepts[2].level	2
concepts[2].score	0.634523868560791
concepts[2].wikidata	https://www.wikidata.org/wiki/Q242657
concepts[2].display_name	Magnetic moment
concepts[3].id	https://openalex.org/C188533889
concepts[3].level	4
concepts[3].score	0.5517256259918213
concepts[3].wikidata	https://www.wikidata.org/wiki/Q13534105
concepts[3].display_name	Electron magnetic dipole moment
concepts[4].id	https://openalex.org/C186923303
concepts[4].level	5
concepts[4].score	0.5434988737106323
concepts[4].wikidata	https://www.wikidata.org/wiki/Q3269677
concepts[4].display_name	Nuclear magnetic moment
concepts[5].id	https://openalex.org/C121332964
concepts[5].level	0
concepts[5].score	0.5379930138587952
concepts[5].wikidata	https://www.wikidata.org/wiki/Q413
concepts[5].display_name	Physics
concepts[6].id	https://openalex.org/C32938098
concepts[6].level	4
concepts[6].score	0.523435115814209
concepts[6].wikidata	https://www.wikidata.org/wiki/Q918398
concepts[6].display_name	Magnetic anisotropy
concepts[7].id	https://openalex.org/C56803174
concepts[7].level	5
concepts[7].score	0.49827027320861816
concepts[7].wikidata	https://www.wikidata.org/wiki/Q6731660
concepts[7].display_name	Magnetocrystalline anisotropy
concepts[8].id	https://openalex.org/C197162081
concepts[8].level	2
concepts[8].score	0.49784231185913086
concepts[8].wikidata	https://www.wikidata.org/wiki/Q3294789
concepts[8].display_name	Magnetism
concepts[9].id	https://openalex.org/C103829212
concepts[9].level	4
concepts[9].score	0.48852646350860596
concepts[9].wikidata	https://www.wikidata.org/wiki/Q3319738
concepts[9].display_name	Spin magnetic moment
concepts[10].id	https://openalex.org/C95802253
concepts[10].level	5
concepts[10].score	0.4748958647251129
concepts[10].wikidata	https://www.wikidata.org/wiki/Q3109934
concepts[10].display_name	Neutron magnetic moment
concepts[11].id	https://openalex.org/C133871045
concepts[11].level	3
concepts[11].score	0.4553464353084564
concepts[11].wikidata	https://www.wikidata.org/wiki/Q4598301
concepts[11].display_name	Multiplet
concepts[12].id	https://openalex.org/C57805442
concepts[12].level	3
concepts[12].score	0.4190460443496704
concepts[12].wikidata	https://www.wikidata.org/wiki/Q898951
concepts[12].display_name	Ligand field theory
concepts[13].id	https://openalex.org/C189394030
concepts[13].level	3
concepts[13].score	0.4136689007282257
concepts[13].wikidata	https://www.wikidata.org/wiki/Q53860
concepts[13].display_name	Atomic orbital
concepts[14].id	https://openalex.org/C185592680
concepts[14].level	0
concepts[14].score	0.40916985273361206
concepts[14].wikidata	https://www.wikidata.org/wiki/Q2329
concepts[14].display_name	Chemistry
concepts[15].id	https://openalex.org/C169852918
concepts[15].level	3
concepts[15].score	0.3564215302467346
concepts[15].wikidata	https://www.wikidata.org/wiki/Q390314
concepts[15].display_name	Magnetic dipole
concepts[16].id	https://openalex.org/C145148216
concepts[16].level	2
concepts[16].score	0.3171434700489044
concepts[16].wikidata	https://www.wikidata.org/wiki/Q36496
concepts[16].display_name	Ion
concepts[17].id	https://openalex.org/C115260700
concepts[17].level	2
concepts[17].score	0.23102769255638123
concepts[17].wikidata	https://www.wikidata.org/wiki/Q11408
concepts[17].display_name	Magnetic field
concepts[18].id	https://openalex.org/C62520636
concepts[18].level	1
concepts[18].score	0.20581793785095215
concepts[18].wikidata	https://www.wikidata.org/wiki/Q944
concepts[18].display_name	Quantum mechanics
concepts[19].id	https://openalex.org/C4839761
concepts[19].level	2
concepts[19].score	0.1997404396533966
concepts[19].wikidata	https://www.wikidata.org/wiki/Q212111
concepts[19].display_name	Spectral line
concepts[20].id	https://openalex.org/C147120987
concepts[20].level	2
concepts[20].score	0.13385432958602905
concepts[20].wikidata	https://www.wikidata.org/wiki/Q2225
concepts[20].display_name	Electron
concepts[21].id	https://openalex.org/C32546565
concepts[21].level	3
concepts[21].score	0.11198493838310242
concepts[21].wikidata	https://www.wikidata.org/wiki/Q856711
concepts[21].display_name	Magnetization
keywords[0].id	https://openalex.org/keywords/magnetic-circular-dichroism
keywords[0].score	0.6494255661964417
keywords[0].display_name	Magnetic circular dichroism
keywords[1].id	https://openalex.org/keywords/condensed-matter-physics
keywords[1].score	0.647415816783905
keywords[1].display_name	Condensed matter physics
keywords[2].id	https://openalex.org/keywords/magnetic-moment
keywords[2].score	0.634523868560791
keywords[2].display_name	Magnetic moment
keywords[3].id	https://openalex.org/keywords/electron-magnetic-dipole-moment
keywords[3].score	0.5517256259918213
keywords[3].display_name	Electron magnetic dipole moment
keywords[4].id	https://openalex.org/keywords/nuclear-magnetic-moment
keywords[4].score	0.5434988737106323
keywords[4].display_name	Nuclear magnetic moment
keywords[5].id	https://openalex.org/keywords/physics
keywords[5].score	0.5379930138587952
keywords[5].display_name	Physics
keywords[6].id	https://openalex.org/keywords/magnetic-anisotropy
keywords[6].score	0.523435115814209
keywords[6].display_name	Magnetic anisotropy
keywords[7].id	https://openalex.org/keywords/magnetocrystalline-anisotropy
keywords[7].score	0.49827027320861816
keywords[7].display_name	Magnetocrystalline anisotropy
keywords[8].id	https://openalex.org/keywords/magnetism
keywords[8].score	0.49784231185913086
keywords[8].display_name	Magnetism
keywords[9].id	https://openalex.org/keywords/spin-magnetic-moment
keywords[9].score	0.48852646350860596
keywords[9].display_name	Spin magnetic moment
keywords[10].id	https://openalex.org/keywords/neutron-magnetic-moment
keywords[10].score	0.4748958647251129
keywords[10].display_name	Neutron magnetic moment
keywords[11].id	https://openalex.org/keywords/multiplet
keywords[11].score	0.4553464353084564
keywords[11].display_name	Multiplet
keywords[12].id	https://openalex.org/keywords/ligand-field-theory
keywords[12].score	0.4190460443496704
keywords[12].display_name	Ligand field theory
keywords[13].id	https://openalex.org/keywords/atomic-orbital
keywords[13].score	0.4136689007282257
keywords[13].display_name	Atomic orbital
keywords[14].id	https://openalex.org/keywords/chemistry
keywords[14].score	0.40916985273361206
keywords[14].display_name	Chemistry
keywords[15].id	https://openalex.org/keywords/magnetic-dipole
keywords[15].score	0.3564215302467346
keywords[15].display_name	Magnetic dipole
keywords[16].id	https://openalex.org/keywords/ion
keywords[16].score	0.3171434700489044
keywords[16].display_name	Ion
keywords[17].id	https://openalex.org/keywords/magnetic-field
keywords[17].score	0.23102769255638123
keywords[17].display_name	Magnetic field
keywords[18].id	https://openalex.org/keywords/quantum-mechanics
keywords[18].score	0.20581793785095215
keywords[18].display_name	Quantum mechanics
keywords[19].id	https://openalex.org/keywords/spectral-line
keywords[19].score	0.1997404396533966
keywords[19].display_name	Spectral line
keywords[20].id	https://openalex.org/keywords/electron
keywords[20].score	0.13385432958602905
keywords[20].display_name	Electron
keywords[21].id	https://openalex.org/keywords/magnetization
keywords[21].score	0.11198493838310242
keywords[21].display_name	Magnetization
language	en
locations[0].id	pmh:oai:arXiv.org:2210.11278
locations[0].is_oa	True
locations[0].source.id	https://openalex.org/S4306400194
locations[0].source.issn
locations[0].source.type	repository
locations[0].source.is_oa	True
locations[0].source.issn_l
locations[0].source.is_core	False
locations[0].source.is_in_doaj	False
locations[0].source.display_name	arXiv (Cornell University)
locations[0].source.host_organization	https://openalex.org/I205783295
locations[0].source.host_organization_name	Cornell University
locations[0].source.host_organization_lineage	https://openalex.org/I205783295
locations[0].license
locations[0].pdf_url	https://arxiv.org/pdf/2210.11278
locations[0].version	submittedVersion
locations[0].raw_type	text
locations[0].license_id
locations[0].is_accepted	False
locations[0].is_published	False
locations[0].raw_source_name
locations[0].landing_page_url	http://arxiv.org/abs/2210.11278
locations[1].id	doi:10.48550/arxiv.2210.11278
locations[1].is_oa	True
locations[1].source.id	https://openalex.org/S4306400194
locations[1].source.issn
locations[1].source.type	repository
locations[1].source.is_oa	True
locations[1].source.issn_l
locations[1].source.is_core	False
locations[1].source.is_in_doaj	False
locations[1].source.display_name	arXiv (Cornell University)
locations[1].source.host_organization	https://openalex.org/I205783295
locations[1].source.host_organization_name	Cornell University
locations[1].source.host_organization_lineage	https://openalex.org/I205783295
locations[1].license	public-domain
locations[1].pdf_url
locations[1].version
locations[1].raw_type	article-journal
locations[1].license_id	https://openalex.org/licenses/public-domain
locations[1].is_accepted	False
locations[1].is_published
locations[1].raw_source_name
locations[1].landing_page_url	https://doi.org/10.48550/arxiv.2210.11278
indexed_in	arxiv, datacite
authorships[0].author.id	https://openalex.org/A5014994316
authorships[0].author.orcid
authorships[0].author.display_name	David Hovancik
authorships[0].author_position	first
authorships[0].raw_author_name	Hovancik, David
authorships[0].is_corresponding	False
authorships[1].author.id	https://openalex.org/A5024098889
authorships[1].author.orcid	https://orcid.org/0000-0002-8416-9668
authorships[1].author.display_name	Cínthia Piamonteze
authorships[1].author_position	middle
authorships[1].raw_author_name	Piamonteze, Cinthia
authorships[1].is_corresponding	False
authorships[2].author.id	https://openalex.org/A5048388607
authorships[2].author.orcid	https://orcid.org/0000-0001-6642-5317
authorships[2].author.display_name	Jiří Pospíšil
authorships[2].author_position	middle
authorships[2].raw_author_name	Pospisil, Jiri
authorships[2].is_corresponding	False
authorships[3].author.id	https://openalex.org/A5033027491
authorships[3].author.orcid	https://orcid.org/0000-0002-2275-1986
authorships[3].author.display_name	Karel Carva
authorships[3].author_position	middle
authorships[3].raw_author_name	Carva, Karel
authorships[3].is_corresponding	False
authorships[4].author.id	https://openalex.org/A5002340076
authorships[4].author.orcid	https://orcid.org/0000-0003-1298-2120
authorships[4].author.display_name	V. Sechovský
authorships[4].author_position	last
authorships[4].raw_author_name	Sechovsky, Vladimir
authorships[4].is_corresponding	False
has_content.pdf	False
has_content.grobid_xml	False
is_paratext	False
open_access.is_oa	True
open_access.oa_url	https://arxiv.org/pdf/2210.11278
open_access.oa_status	green
open_access.any_repository_has_fulltext	False
created_date	2025-10-10T00:00:00
display_name	Large orbital magnetic moment in VI3
has_fulltext	False
is_retracted	False
updated_date	2025-11-06T06:51:31.235846
primary_topic.id	https://openalex.org/T10002
primary_topic.field.id	https://openalex.org/fields/31
primary_topic.field.display_name	Physics and Astronomy
primary_topic.score	0.998199999332428
primary_topic.domain.id	https://openalex.org/domains/3
primary_topic.domain.display_name	Physical Sciences
primary_topic.subfield.id	https://openalex.org/subfields/3107
primary_topic.subfield.display_name	Atomic and Molecular Physics, and Optics
primary_topic.display_name	Advanced Chemical Physics Studies
related_works	https://openalex.org/W1964559522, https://openalex.org/W2131622498, https://openalex.org/W1993810906, https://openalex.org/W2489133680, https://openalex.org/W2013513743, https://openalex.org/W2564434114, https://openalex.org/W3206481270, https://openalex.org/W123311390, https://openalex.org/W2049970597, https://openalex.org/W1967258600
cited_by_count	0
locations_count	2
best_oa_location.id	pmh:oai:arXiv.org:2210.11278
best_oa_location.is_oa	True
best_oa_location.source.id	https://openalex.org/S4306400194
best_oa_location.source.issn
best_oa_location.source.type	repository
best_oa_location.source.is_oa	True
best_oa_location.source.issn_l
best_oa_location.source.is_core	False
best_oa_location.source.is_in_doaj	False
best_oa_location.source.display_name	arXiv (Cornell University)
best_oa_location.source.host_organization	https://openalex.org/I205783295
best_oa_location.source.host_organization_name	Cornell University
best_oa_location.source.host_organization_lineage	https://openalex.org/I205783295
best_oa_location.license
best_oa_location.pdf_url	https://arxiv.org/pdf/2210.11278
best_oa_location.version	submittedVersion
best_oa_location.raw_type	text
best_oa_location.license_id
best_oa_location.is_accepted	False
best_oa_location.is_published	False
best_oa_location.raw_source_name
best_oa_location.landing_page_url	http://arxiv.org/abs/2210.11278
primary_location.id	pmh:oai:arXiv.org:2210.11278
primary_location.is_oa	True
primary_location.source.id	https://openalex.org/S4306400194
primary_location.source.issn
primary_location.source.type	repository
primary_location.source.is_oa	True
primary_location.source.issn_l
primary_location.source.is_core	False
primary_location.source.is_in_doaj	False
primary_location.source.display_name	arXiv (Cornell University)
primary_location.source.host_organization	https://openalex.org/I205783295
primary_location.source.host_organization_name	Cornell University
primary_location.source.host_organization_lineage	https://openalex.org/I205783295
primary_location.license
primary_location.pdf_url	https://arxiv.org/pdf/2210.11278
primary_location.version	submittedVersion
primary_location.raw_type	text
primary_location.license_id
primary_location.is_accepted	False
primary_location.is_published	False
primary_location.raw_source_name
primary_location.landing_page_url	http://arxiv.org/abs/2210.11278
publication_date	2022-10-20
publication_year	2022
referenced_works_count	0
abstract_inverted_index.V	50, 117
abstract_inverted_index.a	48, 79
abstract_inverted_index.OM	126
abstract_inverted_index.We	53
abstract_inverted_index.an	83
abstract_inverted_index.in	17, 28, 92, 103, 128
abstract_inverted_index.is	8
abstract_inverted_index.of	2, 12, 15, 47, 58, 68, 82, 88, 99, 108, 115
abstract_inverted_index.to	38, 63
abstract_inverted_index.DFT	109
abstract_inverted_index.Our	94
abstract_inverted_index.The	0, 24
abstract_inverted_index.V3+	4, 90
abstract_inverted_index.and	73, 123
abstract_inverted_index.but	44
abstract_inverted_index.der	20
abstract_inverted_index.for	75
abstract_inverted_index.ion	5, 91
abstract_inverted_index.the	3, 9, 13, 18, 31, 39, 55, 65, 69, 76, 89, 100, 106, 113, 129
abstract_inverted_index.two	116
abstract_inverted_index.van	19
abstract_inverted_index.VI3.	23, 93
abstract_inverted_index.XMCD	101
abstract_inverted_index.huge	25
abstract_inverted_index.open	10
abstract_inverted_index.time	78
abstract_inverted_index.used	54
abstract_inverted_index.with	30, 105, 112, 119
abstract_inverted_index.Waals	21
abstract_inverted_index.X-ray	59
abstract_inverted_index.agree	111
abstract_inverted_index.field	96
abstract_inverted_index.first	77
abstract_inverted_index.issue	11
abstract_inverted_index.proof	81
abstract_inverted_index.sites	118
abstract_inverted_index.total	70
abstract_inverted_index.value	41
abstract_inverted_index.direct	80
abstract_inverted_index.ground	130
abstract_inverted_index.ligand	95
abstract_inverted_index.moment	7, 36, 72, 87
abstract_inverted_index.nature	14
abstract_inverted_index.state.	131
abstract_inverted_index.strong	43
abstract_inverted_index.unique	56
abstract_inverted_index.moment.	52
abstract_inverted_index.orbital	6, 51, 66, 86, 121
abstract_inverted_index.ordered	34
abstract_inverted_index.provide	74
abstract_inverted_index.reduced	33
abstract_inverted_index.results	107
abstract_inverted_index.sizable	85
abstract_inverted_index.spectra	102
abstract_inverted_index.synergy	104
abstract_inverted_index.circular	61
abstract_inverted_index.compared	37
abstract_inverted_index.evidence	46
abstract_inverted_index.indirect	45
abstract_inverted_index.magnetic	35, 60, 71
abstract_inverted_index.provides	42
abstract_inverted_index.component	67
abstract_inverted_index.determine	64
abstract_inverted_index.dichroism	62
abstract_inverted_index.different	120, 125
abstract_inverted_index.existence	1, 114
abstract_inverted_index.magnetism	16
abstract_inverted_index.multiplet	97
abstract_inverted_index.spin-only	40
abstract_inverted_index.therefore	124
abstract_inverted_index.anisotropy	27
abstract_inverted_index.capability	57
abstract_inverted_index.magnitudes	127
abstract_inverted_index.conjunction	29
abstract_inverted_index.ferromagnet	22
abstract_inverted_index.occupations	122
abstract_inverted_index.significant	49
abstract_inverted_index.simulations	98
abstract_inverted_index.calculations	110
abstract_inverted_index.exceptionally	84
abstract_inverted_index.significantly	32
abstract_inverted_index.magnetocrystalline	26
cited_by_percentile_year
countries_distinct_count	0
institutions_distinct_count	5
citation_normalized_percentile.value	0.14033894
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	False