Large Thermo-Optic Blue Shift in a Silicon Micro-ring Resonator using Fe/Co Bistable Molecule Article Swipe

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Sujit Kamilya , Aneesh Dash , Viphretuo Mere , Ashutosh Mohanty , Shankar Kumar Selvaraja , Akshay Naik , Abhishake Mondal ·

YOU? · · 2025 · Open Access · · DOI: https://doi.org/10.26434/chemrxiv-2025-8l031

Phase change materials (PCMs) with distinct optical properties at different phases are promising candidates for programmable photonics, optical communication and photonic computing. In this work, we have studied thermo-optic effect in a PCM-based integrated photonic device comprising a film of bistable [Fe2Co2] molecular square complex of Prussian Blue Analogues deposited on an on-chip silicon slot waveguide micro-ring resonator. Herein, we are reporting a large thermo-optic blue-shift of 200 pm/K corresponding to a thermo-optic coefficient of −0.4 RIU/K at room temperature, which is an order of magnitude larger than conventional photonic materials. The thermo-optic coefficient can be thermally tuned to zero at the phase-transition temperature of the bistable molecule

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Bistability Resonator Optical bistability Materials science Silicon Blueshift Molecule Ring (chemistry) Optoelectronics Optics Chemistry Physics Nonlinear optics Laser Photoluminescence Organic chemistry

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Type: preprint
Language: en
Landing Page: https://doi.org/10.26434/chemrxiv-2025-8l031
PDF: https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/67bdd06681d2151a02fffd2f/original/large-thermo-optic-blue-shift-in-a-silicon-micro-ring-resonator-using-fe-co-bistable-molecule.pdf
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DOI: https://doi.org/10.26434/chemrxiv-2025-8l031

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Title: Large Thermo-Optic Blue Shift in a Silicon Micro-ring Resonator using Fe/Co Bistable Molecule

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Language: en

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Publication year: 2025

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Publication date: 2025-02-26

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Authors: Sujit Kamilya, Aneesh Dash, Viphretuo Mere, Ashutosh Mohanty, Shankar Kumar Selvaraja, Akshay Naik, Abhishake Mondal

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Landing page: https://doi.org/10.26434/chemrxiv-2025-8l031

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Concepts: Bistability, Resonator, Optical bistability, Materials science, Silicon, Blueshift, Molecule, Ring (chemistry), Optoelectronics, Optics, Chemistry, Physics, Nonlinear optics, Laser, Photoluminescence, Organic chemistry

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abstract_inverted_index.larger	86
abstract_inverted_index.phases	10
abstract_inverted_index.square	43
abstract_inverted_index.−0.4	75
abstract_inverted_index.Herein,	58
abstract_inverted_index.complex	44
abstract_inverted_index.on-chip	52
abstract_inverted_index.optical	6, 17
abstract_inverted_index.silicon	53
abstract_inverted_index.studied	27
abstract_inverted_index.Prussian	46
abstract_inverted_index.[Fe2Co2]	41
abstract_inverted_index.bistable	40, 106
abstract_inverted_index.distinct	5
abstract_inverted_index.molecule	107
abstract_inverted_index.photonic	20, 34, 89
abstract_inverted_index.Analogues	48
abstract_inverted_index.PCM-based	32
abstract_inverted_index.deposited	49
abstract_inverted_index.different	9
abstract_inverted_index.magnitude	85
abstract_inverted_index.materials	2
abstract_inverted_index.molecular	42
abstract_inverted_index.promising	12
abstract_inverted_index.reporting	61
abstract_inverted_index.thermally	96
abstract_inverted_index.waveguide	55
abstract_inverted_index.blue-shift	65
abstract_inverted_index.candidates	13
abstract_inverted_index.comprising	36
abstract_inverted_index.computing.	21
abstract_inverted_index.integrated	33
abstract_inverted_index.materials.	90
abstract_inverted_index.micro-ring	56
abstract_inverted_index.photonics,	16
abstract_inverted_index.properties	7
abstract_inverted_index.resonator.	57
abstract_inverted_index.coefficient	73, 93
abstract_inverted_index.temperature	103
abstract_inverted_index.conventional	88
abstract_inverted_index.programmable	15
abstract_inverted_index.temperature,	79
abstract_inverted_index.thermo-optic	28, 64, 72, 92
abstract_inverted_index.communication	18
abstract_inverted_index.corresponding	69
abstract_inverted_index.phase-transition	102
cited_by_percentile_year
countries_distinct_count	1
institutions_distinct_count	7
citation_normalized_percentile.value	0.05675642
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	False