Light-Induced Conjugation of Inorganic Phosphate and Sulfate with Aminocyclobutenediones under Aqueous Conditions Article Swipe
Koki Ogawa
,
R Kobayashi
,
Nobuhiro Okada
,
Kenji Mishiro
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.26434/chemrxiv-2024-xf1x0-v2
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.26434/chemrxiv-2024-xf1x0-v2
Phosphate and sulfate groups play an important role in controlling the physical properties of biomolecules and artificial materials. However, despite their significance, the incorporation of phosphate or sulfate groups into aqueous organic compounds using non-enzymatic methods has been unprecedented. In this study, we have successfully conjugated inorganic phosphate and sulfate with aminocyclobutenedione derivatives via photochemical reactions under aqueous conditions. A plausible mechanism for the conjugation reactions was proposed on the basis of DFT calculations. These reactions will promote life science research based on organophosphates and organosulfates which have been difficult to access up to now.
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Metadata
- Type
- preprint
- Language
- en
- Landing Page
- https://doi.org/10.26434/chemrxiv-2024-xf1x0-v2
- https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/674ee6b17be152b1d0c979c4/original/light-induced-conjugation-of-inorganic-phosphate-and-sulfate-with-aminocyclobutenediones-under-aqueous-conditions.pdf
- OA Status
- gold
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4405018615
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4405018615Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.26434/chemrxiv-2024-xf1x0-v2Digital Object Identifier
- Title
-
Light-Induced Conjugation of Inorganic Phosphate and Sulfate with Aminocyclobutenediones under Aqueous ConditionsWork title
- Type
-
preprintOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-12-04Full publication date if available
- Authors
-
Koki Ogawa, R Kobayashi, Nobuhiro Okada, Kenji MishiroList of authors in order
- Landing page
-
https://doi.org/10.26434/chemrxiv-2024-xf1x0-v2Publisher landing page
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https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/674ee6b17be152b1d0c979c4/original/light-induced-conjugation-of-inorganic-phosphate-and-sulfate-with-aminocyclobutenediones-under-aqueous-conditions.pdfDirect link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
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https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/674ee6b17be152b1d0c979c4/original/light-induced-conjugation-of-inorganic-phosphate-and-sulfate-with-aminocyclobutenediones-under-aqueous-conditions.pdfDirect OA link when available
- Concepts
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Aqueous solution, Sulfate, Chemistry, Phosphate, Biomolecule, Conjugated system, Inorganic chemistry, Combinatorial chemistry, Organic chemistry, Polymer, BiochemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
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0Total citation count in OpenAlex
- Related works (count)
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10Other works algorithmically related by OpenAlex
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