Low-cost, scalable integration of graphene with LiMn 2 O 4 for selective lithium extraction via hybrid capacitive deionization Article Swipe
YOU?
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· 2025
· Open Access
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· DOI: https://doi.org/10.21203/rs.3.rs-7053918/v1
Hybrid capacitive deionization (HCDI) is a promising strategy for selective lithium extraction from brines, yet scalable fabrication of high-performance electrodes remains challenging. Here, we report a ball milling strategy for the low-cost, scalable integration of graphene with LiMn2O4 (LMO) for selective lithium extraction via HCDI. The ball milling process exfoliates graphite into graphene and reduces the LMO particle size, enabling their in situ integration. The ball milled graphene/LMO composite (BGL) features a continuous conductive network with uniformly dispersed LMO nanoparticles, which simultaneously promotes charge transport, enhances active site accessibility, and suppresses Mn dissolution, thereby improving cycling stability. Accordingly, the BGL electrode achieves a Li+ adsorption capacity of 35.2 mg g− 1 and rate of 2.3 mg− 1 g− 1 min− 1, with 97.4% capacity retention over 50 cycles. It also enables high-purity Li+ recovery from simulated salt lake and actual low-grade brines. This ball milling approach allows scalable production of BGL, offering a practical route for industrial-grade HCDI electrode fabrication.
Related Topics
- Type
- preprint
- Language
- en
- Landing Page
- https://doi.org/10.21203/rs.3.rs-7053918/v1
- https://www.researchsquare.com/article/rs-7053918/latest.pdf
- OA Status
- gold
- References
- 43
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4412149439
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4412149439Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.21203/rs.3.rs-7053918/v1Digital Object Identifier
- Title
-
Low-cost, scalable integration of graphene with LiMn 2 O 4 for selective lithium extraction via hybrid capacitive deionizationWork title
- Type
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preprintOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-07-10Full publication date if available
- Authors
-
Hongmei Zhang, Wenjing Du, Panpan Zhang, Zhiyuan Guo, Lei Wang, Jing Wang, Zhiyong JiList of authors in order
- Landing page
-
https://doi.org/10.21203/rs.3.rs-7053918/v1Publisher landing page
- PDF URL
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https://www.researchsquare.com/article/rs-7053918/latest.pdfDirect link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://www.researchsquare.com/article/rs-7053918/latest.pdfDirect OA link when available
- Concepts
-
Capacitive deionization, Graphene, Lithium (medication), Extraction (chemistry), Scalability, Materials science, Capacitive sensing, Nanotechnology, Computer science, Chemistry, Chromatography, Electrochemistry, Electrode, Physical chemistry, Operating system, Medicine, Endocrinology, DatabaseTop concepts (fields/topics) attached by OpenAlex
- Cited by
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0Total citation count in OpenAlex
- References (count)
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43Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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| publication_date | 2025-07-10 |
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| referenced_works | https://openalex.org/W4402891131, https://openalex.org/W3009349083, https://openalex.org/W4410523266, https://openalex.org/W4365514975, https://openalex.org/W4406564249, https://openalex.org/W4403650352, https://openalex.org/W4410760840, https://openalex.org/W4403955115, https://openalex.org/W4392345827, https://openalex.org/W4402572887, https://openalex.org/W4387420969, https://openalex.org/W4405268637, https://openalex.org/W4395663451, https://openalex.org/W4390778432, https://openalex.org/W4401560390, https://openalex.org/W4289525944, https://openalex.org/W2947575279, https://openalex.org/W4395659465, https://openalex.org/W4281297065, https://openalex.org/W2777911438, https://openalex.org/W4393197261, https://openalex.org/W2061475115, https://openalex.org/W4391014461, https://openalex.org/W3202294205, https://openalex.org/W2922488136, https://openalex.org/W4292444069, https://openalex.org/W1972727161, https://openalex.org/W4386701158, https://openalex.org/W4399969409, https://openalex.org/W4210335549, https://openalex.org/W2903980758, https://openalex.org/W4407872350, https://openalex.org/W4404779308, https://openalex.org/W4406593942, https://openalex.org/W4280511181, https://openalex.org/W4387674776, https://openalex.org/W4403130101, https://openalex.org/W4206568848, https://openalex.org/W4206104010, https://openalex.org/W4287577457, https://openalex.org/W3164789647, https://openalex.org/W4399564393, https://openalex.org/W2751659304 |
| referenced_works_count | 43 |
| abstract_inverted_index.a | 6, 26, 72, 103, 153 |
| abstract_inverted_index.50 | 127 |
| abstract_inverted_index.It | 129 |
| abstract_inverted_index.Mn | 92 |
| abstract_inverted_index.in | 62 |
| abstract_inverted_index.is | 5 |
| abstract_inverted_index.mg | 109 |
| abstract_inverted_index.of | 18, 35, 107, 114, 150 |
| abstract_inverted_index.we | 24 |
| abstract_inverted_index.2.3 | 115 |
| abstract_inverted_index.BGL | 100 |
| abstract_inverted_index.LMO | 57, 79 |
| abstract_inverted_index.The | 46, 65 |
| abstract_inverted_index.and | 54, 90, 112, 139 |
| abstract_inverted_index.for | 9, 30, 40, 156 |
| abstract_inverted_index.the | 31, 56, 99 |
| abstract_inverted_index.via | 44 |
| abstract_inverted_index.yet | 15 |
| abstract_inverted_index.35.2 | 108 |
| abstract_inverted_index.BGL, | 151 |
| abstract_inverted_index.HCDI | 158 |
| abstract_inverted_index.This | 143 |
| abstract_inverted_index.also | 130 |
| abstract_inverted_index.ball | 27, 47, 66, 144 |
| abstract_inverted_index.from | 13, 135 |
| abstract_inverted_index.into | 52 |
| abstract_inverted_index.lake | 138 |
| abstract_inverted_index.over | 126 |
| abstract_inverted_index.rate | 113 |
| abstract_inverted_index.salt | 137 |
| abstract_inverted_index.site | 88 |
| abstract_inverted_index.situ | 63 |
| abstract_inverted_index.with | 37, 76, 122 |
| abstract_inverted_index.(BGL) | 70 |
| abstract_inverted_index.(LMO) | 39 |
| abstract_inverted_index.97.4% | 123 |
| abstract_inverted_index.HCDI. | 45 |
| abstract_inverted_index.Here, | 23 |
| abstract_inverted_index.route | 155 |
| abstract_inverted_index.size, | 59 |
| abstract_inverted_index.their | 61 |
| abstract_inverted_index.which | 81 |
| abstract_inverted_index.(HCDI) | 4 |
| abstract_inverted_index.Hybrid | 1 |
| abstract_inverted_index.active | 87 |
| abstract_inverted_index.actual | 140 |
| abstract_inverted_index.allows | 147 |
| abstract_inverted_index.charge | 84 |
| abstract_inverted_index.milled | 67 |
| abstract_inverted_index.report | 25 |
| abstract_inverted_index.1</sup> | 111, 117, 119 |
| abstract_inverted_index.brines, | 14 |
| abstract_inverted_index.brines. | 142 |
| abstract_inverted_index.cycles. | 128 |
| abstract_inverted_index.cycling | 96 |
| abstract_inverted_index.enables | 131 |
| abstract_inverted_index.lithium | 11, 42 |
| abstract_inverted_index.milling | 28, 48, 145 |
| abstract_inverted_index.network | 75 |
| abstract_inverted_index.process | 49 |
| abstract_inverted_index.reduces | 55 |
| abstract_inverted_index.remains | 21 |
| abstract_inverted_index.thereby | 94 |
| abstract_inverted_index.1</sup>, | 121 |
| abstract_inverted_index.achieves | 102 |
| abstract_inverted_index.approach | 146 |
| abstract_inverted_index.capacity | 106, 124 |
| abstract_inverted_index.enabling | 60 |
| abstract_inverted_index.enhances | 86 |
| abstract_inverted_index.features | 71 |
| abstract_inverted_index.graphene | 36, 53 |
| abstract_inverted_index.graphite | 51 |
| abstract_inverted_index.offering | 152 |
| abstract_inverted_index.particle | 58 |
| abstract_inverted_index.promotes | 83 |
| abstract_inverted_index.recovery | 134 |
| abstract_inverted_index.scalable | 16, 33, 148 |
| abstract_inverted_index.strategy | 8, 29 |
| abstract_inverted_index.composite | 69 |
| abstract_inverted_index.dispersed | 78 |
| abstract_inverted_index.electrode | 101, 159 |
| abstract_inverted_index.g<sup>− | 110, 118 |
| abstract_inverted_index.improving | 95 |
| abstract_inverted_index.low-cost, | 32 |
| abstract_inverted_index.low-grade | 141 |
| abstract_inverted_index.practical | 154 |
| abstract_inverted_index.promising | 7 |
| abstract_inverted_index.retention | 125 |
| abstract_inverted_index.selective | 10, 41 |
| abstract_inverted_index.simulated | 136 |
| abstract_inverted_index.uniformly | 77 |
| abstract_inverted_index.adsorption | 105 |
| abstract_inverted_index.capacitive | 2 |
| abstract_inverted_index.conductive | 74 |
| abstract_inverted_index.continuous | 73 |
| abstract_inverted_index.electrodes | 20 |
| abstract_inverted_index.exfoliates | 50 |
| abstract_inverted_index.extraction | 12, 43 |
| abstract_inverted_index.mg<sup>− | 116 |
| abstract_inverted_index.production | 149 |
| abstract_inverted_index.stability. | 97 |
| abstract_inverted_index.suppresses | 91 |
| abstract_inverted_index.transport, | 85 |
| abstract_inverted_index.fabrication | 17 |
| abstract_inverted_index.high-purity | 132 |
| abstract_inverted_index.integration | 34 |
| abstract_inverted_index.min<sup>− | 120 |
| abstract_inverted_index.Accordingly, | 98 |
| abstract_inverted_index.challenging. | 22 |
| abstract_inverted_index.deionization | 3 |
| abstract_inverted_index.dissolution, | 93 |
| abstract_inverted_index.fabrication. | 160 |
| abstract_inverted_index.graphene/LMO | 68 |
| abstract_inverted_index.integration. | 64 |
| abstract_inverted_index.Li<sup>+</sup> | 104, 133 |
| abstract_inverted_index.accessibility, | 89 |
| abstract_inverted_index.nanoparticles, | 80 |
| abstract_inverted_index.simultaneously | 82 |
| abstract_inverted_index.high-performance | 19 |
| abstract_inverted_index.industrial-grade | 157 |
| abstract_inverted_index.<title>Abstract</title> | 0 |
| abstract_inverted_index.LiMn<sub>2</sub>O<sub>4</sub> | 38 |
| cited_by_percentile_year | |
| countries_distinct_count | 1 |
| institutions_distinct_count | 7 |
| citation_normalized_percentile.value | 0.28971051 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |