Macronutrient Solubility in Response to the pH of Soilless Container Substrates Article Swipe
YOU?
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· 2025
· Open Access
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· DOI: https://doi.org/10.1007/s42729-025-02331-0
This study investigated the complex interactions between pH and nutrient availability in soilless substrates, focusing on how different nutrient solution formulations, substrate components, and liming materials influence macronutrient solubility. The objective was to develop a more sophisticated representation of pH-nutrient solubility relationships compared with charts currently used by horticulture professionals. Macronutrient concentration was measured in response to substrate-pH using Ca(OH) 2 and Mg(OH) 2 in four peat-based substrates (70% peat mixed with 30% perlite, pine bark, coconut coir, or vermiculite by volume). A range of lime rates and fertilizer formulations were applied, and resulting pH and macronutrient concentration in a water extract solution was analyzed. Nitrate-N and ammonium-N concentrations decreased at higher pH levels. Phosphorus concentration decreased, especially when limed with Ca(OH) 2 . Potassium availability was affected by substrate type and cation exchange capacity. Calcium solubility increased with Ca(OH)₂ but decreased with Mg(OH)₂ at elevated pH levels, whereas magnesium solubility showed a reverse pattern. Sulfate-sulfur concentration remained stable across treatments. Chemical equilibrium simulations with Visual MINTEQ highlighted the formation of insoluble Ca-P compounds with Ca(OH) 2 as the lime source, and low solubility Mg-P compounds with Mg(OH) 2 as lime, hindering available P. This study illustrates several key trends in pH effects on macronutrient solubility and plant availability that have practical implications for horticulture fertilizer management and emphasize the real-world complexity beyond widely-used pH solubility charts. The review of published plant studies highlights that tissue nutrient concentrations do not always correlate with nutrient solubility. This discrepancy is influenced by factors such as root-secreted compounds and pH modifications caused by nutrient uptake by plant roots.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1007/s42729-025-02331-0
- https://link.springer.com/content/pdf/10.1007/s42729-025-02331-0.pdf
- OA Status
- hybrid
- Cited By
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- OpenAlex ID
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Raw OpenAlex JSON
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https://openalex.org/W4408189208Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1007/s42729-025-02331-0Digital Object Identifier
- Title
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Macronutrient Solubility in Response to the pH of Soilless Container SubstratesWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-03-06Full publication date if available
- Authors
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Jinsheng Huang, Paul R. Fisher, William R. Argo, Ka Yeon Jeong, James E. AltlandList of authors in order
- Landing page
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https://doi.org/10.1007/s42729-025-02331-0Publisher landing page
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https://link.springer.com/content/pdf/10.1007/s42729-025-02331-0.pdfDirect link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://link.springer.com/content/pdf/10.1007/s42729-025-02331-0.pdfDirect OA link when available
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Container (type theory), Solubility, Hydroponics, Chemistry, Food science, Horticulture, Materials science, Organic chemistry, Biology, Composite materialTop concepts (fields/topics) attached by OpenAlex
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6Total citation count in OpenAlex
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2025: 6Per-year citation counts (last 5 years)
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84Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.peat | 70 |
| abstract_inverted_index.pine | 75 |
| abstract_inverted_index.such | 252 |
| abstract_inverted_index.that | 210, 235 |
| abstract_inverted_index.type | 131 |
| abstract_inverted_index.used | 47 |
| abstract_inverted_index.were | 91 |
| abstract_inverted_index.when | 119 |
| abstract_inverted_index.with | 44, 72, 121, 139, 143, 165, 175, 187, 243 |
| abstract_inverted_index.bark, | 76 |
| abstract_inverted_index.coir, | 78 |
| abstract_inverted_index.lime, | 191 |
| abstract_inverted_index.limed | 120 |
| abstract_inverted_index.mixed | 71 |
| abstract_inverted_index.plant | 208, 232, 264 |
| abstract_inverted_index.range | 84 |
| abstract_inverted_index.rates | 87 |
| abstract_inverted_index.study | 2, 196 |
| abstract_inverted_index.using | 59 |
| abstract_inverted_index.water | 101 |
| abstract_inverted_index.Ca(OH) | 60, 122, 176 |
| abstract_inverted_index.MINTEQ | 167 |
| abstract_inverted_index.Mg(OH) | 63, 188 |
| abstract_inverted_index.Visual | 166 |
| abstract_inverted_index.across | 160 |
| abstract_inverted_index.always | 241 |
| abstract_inverted_index.beyond | 223 |
| abstract_inverted_index.cation | 133 |
| abstract_inverted_index.caused | 259 |
| abstract_inverted_index.charts | 45 |
| abstract_inverted_index.higher | 112 |
| abstract_inverted_index.liming | 25 |
| abstract_inverted_index.review | 229 |
| abstract_inverted_index.roots. | 265 |
| abstract_inverted_index.showed | 152 |
| abstract_inverted_index.stable | 159 |
| abstract_inverted_index.tissue | 236 |
| abstract_inverted_index.trends | 200 |
| abstract_inverted_index.uptake | 262 |
| abstract_inverted_index.Calcium | 136 |
| abstract_inverted_index.between | 7 |
| abstract_inverted_index.charts. | 227 |
| abstract_inverted_index.coconut | 77 |
| abstract_inverted_index.complex | 5 |
| abstract_inverted_index.develop | 34 |
| abstract_inverted_index.effects | 203 |
| abstract_inverted_index.extract | 102 |
| abstract_inverted_index.factors | 251 |
| abstract_inverted_index.levels, | 148 |
| abstract_inverted_index.levels. | 114 |
| abstract_inverted_index.reverse | 154 |
| abstract_inverted_index.several | 198 |
| abstract_inverted_index.source, | 181 |
| abstract_inverted_index.studies | 233 |
| abstract_inverted_index.whereas | 149 |
| abstract_inverted_index.Abstract | 0 |
| abstract_inverted_index.Chemical | 162 |
| abstract_inverted_index.affected | 128 |
| abstract_inverted_index.applied, | 92 |
| abstract_inverted_index.compared | 43 |
| abstract_inverted_index.elevated | 146 |
| abstract_inverted_index.exchange | 134 |
| abstract_inverted_index.focusing | 15 |
| abstract_inverted_index.measured | 54 |
| abstract_inverted_index.nutrient | 10, 19, 237, 244, 261 |
| abstract_inverted_index.pattern. | 155 |
| abstract_inverted_index.perlite, | 74 |
| abstract_inverted_index.remained | 158 |
| abstract_inverted_index.response | 56 |
| abstract_inverted_index.soilless | 13 |
| abstract_inverted_index.solution | 20, 103 |
| abstract_inverted_index.volume). | 82 |
| abstract_inverted_index.Ca(OH)₂ | 140 |
| abstract_inverted_index.Mg(OH)₂ | 144 |
| abstract_inverted_index.Nitrate-N | 106 |
| abstract_inverted_index.Potassium | 125 |
| abstract_inverted_index.analyzed. | 105 |
| abstract_inverted_index.available | 193 |
| abstract_inverted_index.capacity. | 135 |
| abstract_inverted_index.compounds | 174, 186, 255 |
| abstract_inverted_index.correlate | 242 |
| abstract_inverted_index.currently | 46 |
| abstract_inverted_index.decreased | 110, 142 |
| abstract_inverted_index.different | 18 |
| abstract_inverted_index.emphasize | 219 |
| abstract_inverted_index.formation | 170 |
| abstract_inverted_index.hindering | 192 |
| abstract_inverted_index.increased | 138 |
| abstract_inverted_index.influence | 27 |
| abstract_inverted_index.insoluble | 172 |
| abstract_inverted_index.magnesium | 150 |
| abstract_inverted_index.materials | 26 |
| abstract_inverted_index.objective | 31 |
| abstract_inverted_index.practical | 212 |
| abstract_inverted_index.published | 231 |
| abstract_inverted_index.resulting | 94 |
| abstract_inverted_index.substrate | 22, 130 |
| abstract_inverted_index.Phosphorus | 115 |
| abstract_inverted_index.ammonium-N | 108 |
| abstract_inverted_index.complexity | 222 |
| abstract_inverted_index.decreased, | 117 |
| abstract_inverted_index.especially | 118 |
| abstract_inverted_index.fertilizer | 89, 216 |
| abstract_inverted_index.highlights | 234 |
| abstract_inverted_index.influenced | 249 |
| abstract_inverted_index.management | 217 |
| abstract_inverted_index.peat-based | 67 |
| abstract_inverted_index.real-world | 221 |
| abstract_inverted_index.solubility | 41, 137, 151, 184, 206, 226 |
| abstract_inverted_index.substrates | 68 |
| abstract_inverted_index.components, | 23 |
| abstract_inverted_index.discrepancy | 247 |
| abstract_inverted_index.equilibrium | 163 |
| abstract_inverted_index.highlighted | 168 |
| abstract_inverted_index.illustrates | 197 |
| abstract_inverted_index.pH-nutrient | 40 |
| abstract_inverted_index.simulations | 164 |
| abstract_inverted_index.solubility. | 29, 245 |
| abstract_inverted_index.substrates, | 14 |
| abstract_inverted_index.treatments. | 161 |
| abstract_inverted_index.vermiculite | 80 |
| abstract_inverted_index.widely-used | 224 |
| abstract_inverted_index.availability | 11, 126, 209 |
| abstract_inverted_index.formulations | 90 |
| abstract_inverted_index.horticulture | 49, 215 |
| abstract_inverted_index.implications | 213 |
| abstract_inverted_index.interactions | 6 |
| abstract_inverted_index.investigated | 3 |
| abstract_inverted_index.substrate-pH | 58 |
| abstract_inverted_index.Macronutrient | 51 |
| abstract_inverted_index.concentration | 52, 98, 116, 157 |
| abstract_inverted_index.formulations, | 21 |
| abstract_inverted_index.macronutrient | 28, 97, 205 |
| abstract_inverted_index.modifications | 258 |
| abstract_inverted_index.relationships | 42 |
| abstract_inverted_index.root-secreted | 254 |
| abstract_inverted_index.sophisticated | 37 |
| abstract_inverted_index.Sulfate-sulfur | 156 |
| abstract_inverted_index.concentrations | 109, 238 |
| abstract_inverted_index.professionals. | 50 |
| abstract_inverted_index.representation | 38 |
| cited_by_percentile_year.max | 99 |
| cited_by_percentile_year.min | 98 |
| countries_distinct_count | 0 |
| institutions_distinct_count | 5 |
| citation_normalized_percentile.value | 0.98334068 |
| citation_normalized_percentile.is_in_top_1_percent | True |
| citation_normalized_percentile.is_in_top_10_percent | True |