Macroscale Conjugated Microporous Polymers: Controlling Versatile Functionalities Over Several Dimensions Article Swipe
Weiyi Zhang
,
Hongyu Zuo
,
Zhonghua Cheng
,
Yu Shi
,
Zhengjun Guo
,
Nan Meng
,
Arne Thomas
,
Yaozu Liao
·
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1002/adma.202104952
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1002/adma.202104952
Since discovered in 2007, conjugated microporous polymers (CMPs) have been developed for numerous applications including gas adsorption, sensing, organic and photoredox catalysis, energy storage, etc. While featuring abundant micropores, the structural rigidity derived from CMPs’ stable π‐conjugated skeleton leads to insolubility and thus poor processability, which severely limits their applicability, e.g., in CMP‐based devices. Hence, the development of CMPs whose structure can not only be controlled on the micro‐ but also on the macroscale have attracted tremendous interest. In conventional synthesis procedures, CMPs are obtained as powders, but in recent years various bottom‐up synthesis strategies have been developed, which yield CMPs as thin films on substrates or as hybrid materials, allowing to span length scales from individual conjugated monomers to micro‐/macrostructures. This review surveys recent advances on the construction of CMPs into macroscale structures, including membranes, films, aerogels, sponges, and other architectures. The focus is to describe the underlying fabrication techniques and the implications which follow from the macroscale morphologies, involving new chemistry and physics in such materials for applications like molecular separation/filtration/adsorption, energy storage and conversion, photothermal transformation, sensing, or catalysis.
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- Type
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- Language
- en
- Landing Page
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- OA Status
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- Cited By
- 153
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- Related Works
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- OpenAlex ID
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https://openalex.org/W4213011050Canonical identifier for this work in OpenAlex
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https://doi.org/10.1002/adma.202104952Digital Object Identifier
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Macroscale Conjugated Microporous Polymers: Controlling Versatile Functionalities Over Several DimensionsWork title
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reviewOpenAlex work type
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enPrimary language
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2022Year of publication
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2022-02-19Full publication date if available
- Authors
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Weiyi Zhang, Hongyu Zuo, Zhonghua Cheng, Yu Shi, Zhengjun Guo, Nan Meng, Arne Thomas, Yaozu LiaoList of authors in order
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https://doi.org/10.1002/adma.202104952Publisher landing page
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hybridOpen access status per OpenAlex
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https://doi.org/10.1002/adma.202104952Direct OA link when available
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Materials science, Conjugated microporous polymer, Microporous material, Conjugated system, Polymer, Nanotechnology, Polymer science, Chemical engineering, Composite material, EngineeringTop concepts (fields/topics) attached by OpenAlex
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153Total citation count in OpenAlex
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2025: 34, 2024: 58, 2023: 42, 2022: 19Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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