Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy Article Swipe
Kavipriya Thangavel
,
Matthias Mendt
,
Bikash Garai
,
Andrea Folli
,
Volodymyr Bon
,
Damien M. Murphy
,
Stefan Kaskel
,
Andreas Pöppl
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1063/9.0000532
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1063/9.0000532
EPR measurements at X- (9.5 GHz), Q- (34 GHz) and W-band (94 GHz) on paddlewheel (PW) type post-synthetic metal exchanged DUT-49(M,M): M- Zn, Mn, Cu MOFs are here reported (DUT–Dresden University of Technology). Temperature-dependent X-band measurements are recorded from T = 7 K to T = 170 K on monometallic DUT-49(Cu), DUT-49(Mn), and bimetallic DUT-49(Cu0.7Zn0.3), DUT-49(Cu0.5Mn0.5) MOFs. In the case of the CuII - CuII dimers in DUT-49(Cu), an isotropic exchange coupling of the metal ions (2J = −240(11) cm−1) determined from the EPR intensity of the S = 1 spin state of the CuII–CuII dimers using the Bleaney Blowers equation. The sign of the found isotropic exchange coupling constant confirms an antiferromagnetic coupling between the cupric ions. Also, the MnII ions in the paddle wheels of DUT-49(Mn) are antiferromagnetically coupled. However, at low temperatures, EPR measurements reveal the presence of CuII and MnII monomers in DUT-49(Cu) and DUT-49(Mn), respectively, either associated with extra framework sites or defective paddle wheels. Otherwise, EPR signals observed for bimetallic DUT-49(Cu0.7Zn0.3) and DUT-49(Cu0.5Mn0.5) MOFs reveal the formation of mixed ion CuII–ZnII and CuII–MnII paddle wheels with SCuZn =1/2 and SCuMn = 2 spin states, respectively.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1063/9.0000532
- https://aip.scitation.org/doi/pdf/10.1063/9.0000532
- OA Status
- gold
- Cited By
- 4
- References
- 17
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4317435685
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- OpenAlex ID
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https://openalex.org/W4317435685Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1063/9.0000532Digital Object Identifier
- Title
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Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopyWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-01-01Full publication date if available
- Authors
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Kavipriya Thangavel, Matthias Mendt, Bikash Garai, Andrea Folli, Volodymyr Bon, Damien M. Murphy, Stefan Kaskel, Andreas PöpplList of authors in order
- Landing page
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https://doi.org/10.1063/9.0000532Publisher landing page
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https://aip.scitation.org/doi/pdf/10.1063/9.0000532Direct link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://aip.scitation.org/doi/pdf/10.1063/9.0000532Direct OA link when available
- Concepts
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Bimetallic strip, Electron paramagnetic resonance, Chemistry, Metal, Materials science, Crystallography, Ion, Antiferromagnetism, Coupling (piping), Analytical Chemistry (journal), Nuclear magnetic resonance, Condensed matter physics, Physics, Metallurgy, Organic chemistry, ChromatographyTop concepts (fields/topics) attached by OpenAlex
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4Total citation count in OpenAlex
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2023: 4Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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