Metal–Organic Pt(II) Hexagonal-Prism Macrocycles and Their Photophysical Properties Article Swipe

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Jian‐Hong Tang , Ruidong Ni , Yan‐Qin He , Ryan T. VanderLinden , Yanrong Li , Bingbing Shi , Zhongyu Li , Heng Wang , Xiaopeng Li , Yue Sun , Yu‐Wu Zhong , Peter J. Stang ·

YOU? · · 2019 · Open Access · · DOI: https://doi.org/10.1021/acs.inorgchem.9b02267

In this work, we present the formation of two open-ended hexagonal-prism tubular macrocycles by the [6 + 12] self-assembly of the symmetric ∼120° organic ligand donor with ∼90° Pt(II) acceptor in a 1:2 ratio. The assembled structures were characterized by multinuclear NMR (¹H NMR, ³¹P{¹H} NMR, and ¹H-¹H COSY NMR), electrospray ionization mass spectrometry (ESI-TOF-MS), traveling wave ion mobility-mass spectrometry (TWIM-MS), and transmission electron microscopy. Molecular modeling was further conducted to get insight into their structured characteristics. We also examined their photophysical properties.

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Chemistry Hexagonal prism Metal Prism Hexagonal crystal system Porphyrin Crystallography Photochemistry Triangular prism Organic chemistry Optics Physics

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Type: article
Language: en
Landing Page: https://doi.org/10.1021/acs.inorgchem.9b02267
OA Status: green
Cited By: 20
References: 52
Related Works: 10
OpenAlex ID: https://openalex.org/W2973507649

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DOI: https://doi.org/10.1021/acs.inorgchem.9b02267

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Title: Metal–Organic Pt(II) Hexagonal-Prism Macrocycles and Their Photophysical Properties

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Language: en

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Publication year: 2019

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Publication date: 2019-09-18

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Authors: Jian‐Hong Tang, Ruidong Ni, Yan‐Qin He, Ryan T. VanderLinden, Yanrong Li, Bingbing Shi, Zhongyu Li, Heng Wang, Xiaopeng Li, Yue Sun, Yu‐Wu Zhong, Peter J. Stang

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Landing page: https://doi.org/10.1021/acs.inorgchem.9b02267

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OA URL: https://www.ncbi.nlm.nih.gov/pmc/articles/6988834

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Concepts: Chemistry, Hexagonal prism, Metal, Prism, Hexagonal crystal system, Porphyrin, Crystallography, Photochemistry, Triangular prism, Organic chemistry, Optics, Physics

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Cited by: 20

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