Methods—Ampero-Coulometry: A New Technique for Understanding Lithium-Sulfur Electrochemistry Article Swipe
YOU?
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· 2023
· Open Access
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· DOI: https://doi.org/10.1149/1945-7111/acbca0
Despite limited commercial success, lithium sulfur technology (LST) is still far from competing existing Li-ion technology. One of the main reasons hindering the success of LST is the complexity of lithium-sulfur chemistry during electrochemical charging and discharging. Dissolution of sulfur species in the electrolyte solution exacerbates the difficulties of this system. Therefore, a comprehensive understanding of sulfur species and their kinetics during charge/discharge process is paramount for a high-performance lithium-sulfur battery. We present a new technique we refer to as Ampero-Coulometry, which takes the chronoamperometric (galvanostatic) charge-discharge curves and mathematically transforms them to a series of curves that reveal the cation diffusional rate inside carbon-sulfur porous electrodes at different states of charge/capacity. This technique allowed us to track the overall Li + ion diffusional rate inside a Li-S cell over a complete state of discharge. As dissolution of sulfur species and their interplay inside a porous sulfur electrode has a significant role in limiting Li-S battery capacity, and method allows correlation between the known mechanism of polysulfide dissolution, the kinetics of a sulfur electrode, and its response.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1149/1945-7111/acbca0
- https://iopscience.iop.org/article/10.1149/1945-7111/acbca0/pdf
- OA Status
- hybrid
- Cited By
- 3
- References
- 50
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4321018801
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4321018801Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1149/1945-7111/acbca0Digital Object Identifier
- Title
-
Methods—Ampero-Coulometry: A New Technique for Understanding Lithium-Sulfur ElectrochemistryWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2023Year of publication
- Publication date
-
2023-02-16Full publication date if available
- Authors
-
Umair Gulzar, Alex Lonergan, Vladimir Egorov, Yan Zhang, Alex Grant, Aoife Carroll, Colm O’DwyerList of authors in order
- Landing page
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https://doi.org/10.1149/1945-7111/acbca0Publisher landing page
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https://iopscience.iop.org/article/10.1149/1945-7111/acbca0/pdfDirect link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://iopscience.iop.org/article/10.1149/1945-7111/acbca0/pdfDirect OA link when available
- Concepts
-
Polysulfide, Sulfur, Dissolution, Coulometry, Electrolyte, Electrochemistry, Chemistry, Electrode, Inorganic chemistry, Lithium (medication), Carbon fibers, Materials science, Physical chemistry, Organic chemistry, Medicine, Endocrinology, Composite number, Composite materialTop concepts (fields/topics) attached by OpenAlex
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3Total citation count in OpenAlex
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2025: 1, 2024: 1, 2023: 1Per-year citation counts (last 5 years)
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50Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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