MOF‐Based Solid‐State Proton Conductors Obtained by Intertwining Protic Ionic Liquid Polymers with MIL‐101 Article Swipe

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Shunlin Zhang , Yuxin Xie , Rosie J. Somerville , Farzaneh Fadaei‐Tirani , Rosario Scopelliti , Zhaofu Fei , Dunru Zhu , Paul J. Dyson ·

YOU? · · 2023 · Open Access · · DOI: https://doi.org/10.1002/smll.202206999

Solid‐state proton conductors based on the use of metal–organic framework (MOF) materials as proton exchange membranes are being investigated as alternatives to the current state of the art. This study reports a new family of proton conductors based on MIL‐101 and protic ionic liquid polymers (PILPs) containing different anions. By first installing protic ionic liquid (PIL) monomers inside the hierarchical pores of a highly stable MOF, MIL‐101, then carrying out polymerization in situ, a series of PILP@MIL‐101 composites was synthesized. The resulting PILP@MIL‐101 composites not only maintain the nanoporous cavities and water stability of MIL‐101, but the intertwined PILPs provide a number of opportunities for much‐improved proton transport compared to MIL‐101. The PILP@MIL‐101 composite with HSO 4 − anions shows superprotonic conductivity (6.3 × 10 −2 S cm −1 ) at 85 °C and 98% relative humidity. The mechanism of proton conduction is proposed. In addition, the structures of the PIL monomers were determined by single crystal X‐ray analysis, which reveals many strong hydrogen bonding interactions with O/NH···O distances below 2.6 Å.

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Monomer Materials science Proton Ionic liquid Nanoporous Polymerization Polymer Conductivity Ionic bonding Polymer chemistry Ionic conductivity Electrical conductor Chemical engineering Nanotechnology Physical chemistry Chemistry Composite material Electrode Organic chemistry Ion Physics Electrolyte Catalysis Engineering Quantum mechanics

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Type: article
Language: en
Landing Page: https://doi.org/10.1002/smll.202206999
PDF: https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/smll.202206999
OA Status: hybrid
Cited By: 25
References: 69
Related Works: 10
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DOI: https://doi.org/10.1002/smll.202206999

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Title: MOF‐Based Solid‐State Proton Conductors Obtained by Intertwining Protic Ionic Liquid Polymers with MIL‐101

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Language: en

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Publication year: 2023

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Publication date: 2023-06-14

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Authors: Shunlin Zhang, Yuxin Xie, Rosie J. Somerville, Farzaneh Fadaei‐Tirani, Rosario Scopelliti, Zhaofu Fei, Dunru Zhu, Paul J. Dyson

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Landing page: https://doi.org/10.1002/smll.202206999

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Concepts: Monomer, Materials science, Proton, Ionic liquid, Nanoporous, Polymerization, Polymer, Conductivity, Ionic bonding, Polymer chemistry, Ionic conductivity, Electrical conductor, Chemical engineering, Nanotechnology, Physical chemistry, Chemistry, Composite material, Electrode, Organic chemistry, Ion, Physics, Electrolyte, Catalysis, Engineering, Quantum mechanics

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Cited by: 25

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