Multi-stimuli-responsive and dynamic color tunable security ink for multilevel anticounterfeiting Article Swipe
Charu Dubey
,
Anjana Yadav
,
Diksha Baloni
,
Sachin Singh
,
Anjani Kumar Singh
,
Sunil Kumar Singh
,
Akhilesh Kumar Singh
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1088/2050-6120/acbe92
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1088/2050-6120/acbe92
Luminescent security features have been used for anticounterfeiting for a long time. However, constant effort is required to strengthen these security features to be ahead of counterfeiters. Here, we developed a multi-stimuli-responsive luminescent security ink containing Tb(ASA) 3 Phen, K 2 SiF 6 :Mn 4+, and NaYF 4 :Yb 3+ /Er 3+ luminescent materials in PVC gold medium. Tb(ASA) 3 Phen complex shows a broad excitation band in the UV region; upon UV light radiation it shows strong greenish emission of Tb 3+ ions through the antenna effect. K 2 SiF 6 :Mn 4+ , on the other hand, has three excitation bands with maxima at 248, 354, and 454 nm which emit red light after excitation through these bands. NaYF 4 :Yb 3+ /Er 3+ is used as an upconverting nanophosphor showing green emission under 976 nm laser excitation. Thus, the multi-stimuli-responsive luminescent security ink shows greenish, red, and green emissions under 367 nm, 450 nm, and 976 nm excitations, respectively. Furthermore, the distinct lifetimes of the activators in Tb(ASA) 3 Phen and K 2 SiF 6 :Mn 4+ , i.e. 0.1708 ms and 8.165 ms, respectively, under 380 nm excitation make this ink suitable for dynamic anticounterfeiting as well. The ink shows a change in the emission color with time delay, after the removal of the 380 nm excitation source, from greenish yellow (at 0 delays) to reddish color after a delay of 7.5 ms. These unique optical features along with excellent photo-, chemical- and environmental stability make this ink useful for advanced-level anticounterfeiting.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1088/2050-6120/acbe92
- OA Status
- hybrid
- Cited By
- 11
- References
- 42
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4321605863
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4321605863Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1088/2050-6120/acbe92Digital Object Identifier
- Title
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Multi-stimuli-responsive and dynamic color tunable security ink for multilevel anticounterfeitingWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-02-23Full publication date if available
- Authors
-
Charu Dubey, Anjana Yadav, Diksha Baloni, Sachin Singh, Anjani Kumar Singh, Sunil Kumar Singh, Akhilesh Kumar SinghList of authors in order
- Landing page
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https://doi.org/10.1088/2050-6120/acbe92Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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hybridOpen access status per OpenAlex
- OA URL
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https://doi.org/10.1088/2050-6120/acbe92Direct OA link when available
- Concepts
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Luminescence, Excitation, Inkwell, Materials science, Optically stimulated luminescence, Ion, Optoelectronics, Laser, Optics, Chemistry, Electrical engineering, Engineering, Organic chemistry, Physics, Composite materialTop concepts (fields/topics) attached by OpenAlex
- Cited by
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11Total citation count in OpenAlex
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2025: 7, 2024: 2, 2023: 2Per-year citation counts (last 5 years)
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42Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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