Multiscale quantum-defect theory and its application to atomic spectrum Article Swipe
Haixiang Fu
,
Mingzhe Li
,
Meng Khoon Tey
,
Li You
,
Bo Gao
·
YOU?
·
· 2016
· Open Access
·
· DOI: https://doi.org/10.1088/1367-2630/18/10/103016
YOU?
·
· 2016
· Open Access
·
· DOI: https://doi.org/10.1088/1367-2630/18/10/103016
We present a multiscale quantum-defect theory based on the first analytic\nsolution for a two-scale long range potential consisting of a Coulomb potential\nand a polarization potential. In its application to atomic structure, the\ntheory extends the systematic understanding of atomic Rydberg states, as\nafforded by the standard single-scale quantum-defect theory, to a much greater\nrange of energies to include the first few excited states and even the ground\nstate. Such a level of understanding has important implications not only on\natomic structure, but also on the electronic structure of molecules and on\natomic and molecular interactions and reactions. We demonstrate the theory by\nshowing that it provides an analytic description of the energy variations of\nthe standard Coulomb quantum defects for alkali-metal atoms.\n
Related Topics
Concepts
Physics
Quantum defect
Rydberg formula
Excited state
Coulomb
Quantum mechanics
Quantum
Atomic units
Atomic physics
Electron
Ionization
Ion
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1088/1367-2630/18/10/103016
- https://iopscience.iop.org/article/10.1088/1367-2630/18/10/103016/pdf
- OA Status
- gold
- Cited By
- 11
- References
- 45
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W126440229
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W126440229Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1088/1367-2630/18/10/103016Digital Object Identifier
- Title
-
Multiscale quantum-defect theory and its application to atomic spectrumWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2016Year of publication
- Publication date
-
2016-10-12Full publication date if available
- Authors
-
Haixiang Fu, Mingzhe Li, Meng Khoon Tey, Li You, Bo GaoList of authors in order
- Landing page
-
https://doi.org/10.1088/1367-2630/18/10/103016Publisher landing page
- PDF URL
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https://iopscience.iop.org/article/10.1088/1367-2630/18/10/103016/pdfDirect link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
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https://iopscience.iop.org/article/10.1088/1367-2630/18/10/103016/pdfDirect OA link when available
- Concepts
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Physics, Quantum defect, Rydberg formula, Excited state, Coulomb, Quantum mechanics, Quantum, Atomic units, Atomic physics, Electron, Ionization, IonTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
11Total citation count in OpenAlex
- Citations by year (recent)
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2025: 2, 2024: 1, 2022: 1, 2020: 2, 2019: 2Per-year citation counts (last 5 years)
- References (count)
-
45Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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