Ni-Doped MnO2 Nanosheet Arrays for Efficient Urea Oxidation Article Swipe
YOU?
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· 2023
· Open Access
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· DOI: https://doi.org/10.1021/acs.inorgchem.3c00234
Urea oxidation reaction (UOR), with a low thermodynamic potential, offers great promise for replacing anodic oxygen evolution reaction of electrolysis systems such as water splitting, carbon dioxide reduction, etc., thus reducing the overall energy consumption. To promote the sluggish kinetics of UOR, highly efficient electrocatalysts are required, and Ni-based materials have been widely investigated. However, most of these reported Ni-based catalysts suffer from large overpotentials, as they generally undergo self-oxidation to form NiOOH species at high potentials, which act as catalytically active sites for UOR. Herein, Ni-doped MnO2 (Ni-MnO2) nanosheet arrays were successfully prepared on nickel foam. The as-fabricated Ni-MnO2 shows distinct UOR behavior with most of the previously reported Ni-based catalysts, as urea oxidation on Ni-MnO2 proceeds before the formation of NiOOH. Notably, a low potential of 1.388 V vs reversible hydrogen electrode was required to achieve a high current density of 100 mA cm-2 on Ni-MnO2. It is suggested that both Ni doping and nanosheet array configuration are responsible for the high UOR activities on Ni-MnO2. The introduction of Ni modifies the electronic structure of Mn atoms, and more Mn3+ species are generated in Ni-MnO2, contributing to its outstanding UOR performance.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.inorgchem.3c00234
- OA Status
- green
- Cited By
- 45
- References
- 62
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4323819428
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4323819428Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.inorgchem.3c00234Digital Object Identifier
- Title
-
Ni-Doped MnO2 Nanosheet Arrays for Efficient Urea OxidationWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-03-10Full publication date if available
- Authors
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Huaiyu Zhang, Yu Bai, Xue Feng Lu, Liang Wang, Yan Zou, Yujia Tang, Dongdong ZhuList of authors in order
- Landing page
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https://doi.org/10.1021/acs.inorgchem.3c00234Publisher landing page
- Open access
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YesWhether a free full text is available
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greenOpen access status per OpenAlex
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https://research-repository.griffith.edu.au/bitstreams/2de3c319-f7d4-4edb-9ebe-33746082a141/downloadDirect OA link when available
- Concepts
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Nanosheet, Chemistry, Anode, Oxygen evolution, Catalysis, Inorganic chemistry, Nickel, Electrolysis, Urea, Redox, Electrochemistry, Doping, Chemical engineering, Electrode, Physical chemistry, Materials science, Organic chemistry, Optoelectronics, Engineering, ElectrolyteTop concepts (fields/topics) attached by OpenAlex
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45Total citation count in OpenAlex
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2025: 11, 2024: 26, 2023: 8Per-year citation counts (last 5 years)
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62Number of works referenced by this work
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-
10Other works algorithmically related by OpenAlex
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