Nitrogen-rich cobalt (II) MOFs as efficient bifunctional catalysts for single or tandem oxidation and CO2 conversion reactions Article Swipe
Antonio Valverde‐González
,
M. Carmen Borrallo-Aniceto
,
Urbano Díaz
,
Eva M. Maya
,
Felipe Gándara
,
Félix Sánchez
,
M. Iglesias
·
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1016/j.jcou.2022.102298
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1016/j.jcou.2022.102298
The development of efficient catalysts that include the advantages of homogeneous and heterogeneous catalysts is a challenge that can be achieved with metal-organic frameworks (MOFs) since they can incorporate different functionalities in their structure that make them promising catalysts for different processes. Herein, two new isoreticular nitrogen-rich naphthalene cobalt-MOFs, Co-NDTz and Co-NDPhTz, were successfully prepared under solvothermal conditions from the corresponding linkers (H2NDTz=2,6-naphthaleneditetrazole and H2NDPhTz=2,6-bis(4-(1H-tetrazol-5-yl)phenyl)naphthalene). These Co-tetrazole-based MOFs combine Lewis acid and redox functionalities and good CO2 adsorption and after being thermally activated resulted to be excellent efficient catalysts for the epoxidation of alkenes and CO2 cycloaddition to epoxides yielding cyclic carbonates, reaching turnover numbers up to 2500. Furthermore, these two reactions take place following a highly desired one-pot tandem process and a cyclic carbonate was obtained from styrene and CO2 under solvent-free conditions. In addition, the heterogeneous catalysts are easily recycled without noticeable loss of catalytic activity and without important structural deterioration.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1016/j.jcou.2022.102298
- https://ars.els-cdn.com/content/image/1-s2.0-S2212982022004176-ga1_lrg.jpg
- OA Status
- hybrid
- Cited By
- 35
- References
- 64
- Related Works
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- OpenAlex ID
- https://openalex.org/W4308347219
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- OpenAlex ID
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https://openalex.org/W4308347219Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1016/j.jcou.2022.102298Digital Object Identifier
- Title
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Nitrogen-rich cobalt (II) MOFs as efficient bifunctional catalysts for single or tandem oxidation and CO2 conversion reactionsWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2022Year of publication
- Publication date
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2022-11-03Full publication date if available
- Authors
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Antonio Valverde‐González, M. Carmen Borrallo-Aniceto, Urbano Díaz, Eva M. Maya, Felipe Gándara, Félix Sánchez, M. IglesiasList of authors in order
- Landing page
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https://doi.org/10.1016/j.jcou.2022.102298Publisher landing page
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https://ars.els-cdn.com/content/image/1-s2.0-S2212982022004176-ga1_lrg.jpgDirect link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://ars.els-cdn.com/content/image/1-s2.0-S2212982022004176-ga1_lrg.jpgDirect OA link when available
- Concepts
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Catalysis, Cobalt, Bifunctional, Tandem, Chemistry, Naphthalene, Redox, Tetrazole, Lewis acids and bases, Cycloaddition, Metal-organic framework, Adsorption, Combinatorial chemistry, Organic chemistry, Materials science, Composite materialTop concepts (fields/topics) attached by OpenAlex
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35Total citation count in OpenAlex
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2025: 11, 2024: 12, 2023: 12Per-year citation counts (last 5 years)
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64Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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