One trityl, two trityl, three trityl groups – Structural differences of differently substituted triethanolamines Article Swipe

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Tabea Lenz , Marcus Layh , Marian Hebenbrock ·

YOU? · · 2025 · Open Access · · DOI: https://doi.org/10.1515/zkri-2024-0112

Trityl-protected triethanolamines were synthesized and their structures evaluated with regard to the planarization of the central nitrogen atom. Although the steric influence of the side groups was found to affect the geometry around the nitrogen atom, this influence was only minor. In addition to the intramolecular interactions, the intermolecular interactions in these crystals were identified on the basis of the solid state structures. These are dominated by short H⋯H contacts and C–H···π interactions. Overall, this study demonstrates the individual influence of distant sterically demanding groups on geometrical parameters and contributes to the understanding of these influences.

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Type: article
Language: en
Landing Page: https://doi.org/10.1515/zkri-2024-0112
OA Status: hybrid
References: 19
Related Works: 10
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DOI: https://doi.org/10.1515/zkri-2024-0112

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Title: One trityl, two trityl, three trityl groups – Structural differences of differently substituted triethanolamines

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Language: en

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Publication year: 2025

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Publication date: 2025-02-25

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Authors: Tabea Lenz, Marcus Layh, Marian Hebenbrock

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Landing page: https://doi.org/10.1515/zkri-2024-0112

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OA URL: https://doi.org/10.1515/zkri-2024-0112

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Concepts: Chemistry

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Cited by: 0

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References (count): 19

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