Palladium-Catalyzed Addition of Aryl Halides to N-Sulfinylamines for the Synthesis of Sulfinamides Article Swipe
Ming-Kai Wei
,
Daniel. F. Moseley
,
Robin M. Bär
,
Yeshua Sempere
,
Michael C. Willis
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/jacs.4c06726
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/jacs.4c06726
Sulfinamides are versatile, synthetically useful intermediates, and final motifs. Traditional methods to synthesize sulfinamides generally require substrates with preinstalled sulfur centers. However, these precursors have limited commercial availability, and the associated synthetic routes often require harsh reaction conditions and highly reactive reagents, thus severely limiting their application. Herein, we report the synthesis of sulfinamides from aryl and alkenyl (pseudo)halides and N-sulfinylamines, enabled by palladium catalysis. The reactions use mild conditions and are achieved without the use of highly reactive preformed organometallic reagents, resulting in transformations of broad generality and high functional group tolerance. In particular, substrates featuring protic and electrophilic functional groups can be used successfully. The modification of complex aryl cores and natural product derivatives demonstrates the utility of this method.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/jacs.4c06726
- https://pubs.acs.org/doi/pdf/10.1021/jacs.4c06726
- OA Status
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- Cited By
- 24
- References
- 52
- Related Works
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- OpenAlex ID
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All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W4400585428Canonical identifier for this work in OpenAlex
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https://doi.org/10.1021/jacs.4c06726Digital Object Identifier
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Palladium-Catalyzed Addition of Aryl Halides to N-Sulfinylamines for the Synthesis of SulfinamidesWork title
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articleOpenAlex work type
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enPrimary language
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2024Year of publication
- Publication date
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2024-07-12Full publication date if available
- Authors
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Ming-Kai Wei, Daniel. F. Moseley, Robin M. Bär, Yeshua Sempere, Michael C. WillisList of authors in order
- Landing page
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https://doi.org/10.1021/jacs.4c06726Publisher landing page
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https://pubs.acs.org/doi/pdf/10.1021/jacs.4c06726Direct link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://pubs.acs.org/doi/pdf/10.1021/jacs.4c06726Direct OA link when available
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Chemistry, Aryl, Palladium, Halide, Catalysis, Combinatorial chemistry, Organic chemistry, AlkylTop concepts (fields/topics) attached by OpenAlex
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24Total citation count in OpenAlex
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2025: 22, 2024: 2Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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| referenced_works | https://openalex.org/W2588865896, https://openalex.org/W4205576972, https://openalex.org/W2005619234, https://openalex.org/W1991071994, https://openalex.org/W2168679251, https://openalex.org/W2075813623, https://openalex.org/W2030852656, https://openalex.org/W2034206570, https://openalex.org/W2952549589, https://openalex.org/W4386952500, https://openalex.org/W3200930660, https://openalex.org/W2940292178, https://openalex.org/W3146191650, https://openalex.org/W3177269428, https://openalex.org/W2395303858, https://openalex.org/W2801472139, https://openalex.org/W2590729009, https://openalex.org/W2996924534, https://openalex.org/W2937482900, https://openalex.org/W2118737630, https://openalex.org/W2119039945, https://openalex.org/W2180145553, https://openalex.org/W2097675597, https://openalex.org/W2322281537, https://openalex.org/W3087728210, https://openalex.org/W2066412521, https://openalex.org/W4290013936, https://openalex.org/W2754263024, https://openalex.org/W2967911677, https://openalex.org/W3081474970, https://openalex.org/W3109213167, https://openalex.org/W3153314886, https://openalex.org/W4213385287, https://openalex.org/W4307697616, https://openalex.org/W4388484366, https://openalex.org/W3015376042, https://openalex.org/W4389406135, https://openalex.org/W3162277460, https://openalex.org/W2981137491, https://openalex.org/W4310421924, https://openalex.org/W4391346436, https://openalex.org/W4323804506, https://openalex.org/W4285077125, https://openalex.org/W2317164595, https://openalex.org/W2144061504, https://openalex.org/W2531761328, https://openalex.org/W2980550352, https://openalex.org/W2580289787, https://openalex.org/W3154551870, https://openalex.org/W2801152464, https://openalex.org/W2169303530, https://openalex.org/W2074274985 |
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| corresponding_author_ids | https://openalex.org/A5003952861 |
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