PCEs containing C5 and C6 based PEO side chains: A comparison on the synthesized polymers and the resulting dispersing effectivenesss Article Swipe
Serina Ng
,
Ke Feng
,
Zhaoyang Liu
·
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1088/1742-6596/2206/1/012042
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1088/1742-6596/2206/1/012042
The reactivity of C5 and C6 based PEO macromonomers in the synthesis of PCE superplasticizers, followed by the dispersing abilities of such PCEs on cement pastes were analysed and compared in this study. It was found that free radical compolymerisation of C5 macromonomers and acrylic acid (AA) produced PCEs with less controlled block compolymers characteristics, which were highly sensitive to reaction conditions such as the rate of polymer additions, etc. This can be attributed to the difference in reactivity constants of the monomers, where AA was highly reactive. The orderness became more dominant when the temperature of synthesis was suitably controlled. The ease in adapting the molecular architecture of C6 based PCEs as compared to C5 based PCEs enabled better prediction of cement dispersing ability, as confirmed by the slump flow tests performed. It was thus shown through this study that using C6 macromonmers, PCE with tailormade acrhitecture could be developed easier than with C5 macromonomers, potentially to adapt to different types of cement on the market.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1088/1742-6596/2206/1/012042
- OA Status
- diamond
- References
- 22
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4213186786
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4213186786Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1088/1742-6596/2206/1/012042Digital Object Identifier
- Title
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PCEs containing C5 and C6 based PEO side chains: A comparison on the synthesized polymers and the resulting dispersing effectivenesssWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2022Year of publication
- Publication date
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2022-02-01Full publication date if available
- Authors
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Serina Ng, Ke Feng, Zhaoyang LiuList of authors in order
- Landing page
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https://doi.org/10.1088/1742-6596/2206/1/012042Publisher landing page
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YesWhether a free full text is available
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diamondOpen access status per OpenAlex
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https://doi.org/10.1088/1742-6596/2206/1/012042Direct OA link when available
- Concepts
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Superplasticizer, Monomer, Macromonomer, Reactivity (psychology), Polymer, Dispersant, Acrylic acid, Materials science, Polymer chemistry, Chemical engineering, Chemistry, Cement, Composite material, Dispersion (optics), Engineering, Medicine, Alternative medicine, Optics, Physics, PathologyTop concepts (fields/topics) attached by OpenAlex
- Cited by
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0Total citation count in OpenAlex
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22Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.easier | 152 |
| abstract_inverted_index.highly | 58, 87 |
| abstract_inverted_index.pastes | 26 |
| abstract_inverted_index.study. | 33 |
| abstract_inverted_index.acrylic | 45 |
| abstract_inverted_index.enabled | 119 |
| abstract_inverted_index.market. | 167 |
| abstract_inverted_index.polymer | 68 |
| abstract_inverted_index.radical | 39 |
| abstract_inverted_index.through | 138 |
| abstract_inverted_index.Abstract | 0 |
| abstract_inverted_index.ability, | 125 |
| abstract_inverted_index.adapting | 105 |
| abstract_inverted_index.analysed | 28 |
| abstract_inverted_index.compared | 30, 114 |
| abstract_inverted_index.dominant | 93 |
| abstract_inverted_index.followed | 16 |
| abstract_inverted_index.produced | 48 |
| abstract_inverted_index.reaction | 61 |
| abstract_inverted_index.suitably | 100 |
| abstract_inverted_index.abilities | 20 |
| abstract_inverted_index.confirmed | 127 |
| abstract_inverted_index.constants | 80 |
| abstract_inverted_index.developed | 151 |
| abstract_inverted_index.different | 161 |
| abstract_inverted_index.molecular | 107 |
| abstract_inverted_index.monomers, | 83 |
| abstract_inverted_index.orderness | 90 |
| abstract_inverted_index.reactive. | 88 |
| abstract_inverted_index.sensitive | 59 |
| abstract_inverted_index.synthesis | 12, 98 |
| abstract_inverted_index.additions, | 69 |
| abstract_inverted_index.attributed | 74 |
| abstract_inverted_index.conditions | 62 |
| abstract_inverted_index.controlled | 52 |
| abstract_inverted_index.difference | 77 |
| abstract_inverted_index.dispersing | 19, 124 |
| abstract_inverted_index.performed. | 133 |
| abstract_inverted_index.prediction | 121 |
| abstract_inverted_index.reactivity | 2, 79 |
| abstract_inverted_index.tailormade | 147 |
| abstract_inverted_index.compolymers | 54 |
| abstract_inverted_index.controlled. | 101 |
| abstract_inverted_index.potentially | 157 |
| abstract_inverted_index.temperature | 96 |
| abstract_inverted_index.acrhitecture | 148 |
| abstract_inverted_index.architecture | 108 |
| abstract_inverted_index.macromonmers, | 144 |
| abstract_inverted_index.macromonomers | 9, 43 |
| abstract_inverted_index.macromonomers, | 156 |
| abstract_inverted_index.characteristics, | 55 |
| abstract_inverted_index.compolymerisation | 40 |
| abstract_inverted_index.superplasticizers, | 15 |
| cited_by_percentile_year | |
| corresponding_author_ids | https://openalex.org/A5100603519, https://openalex.org/A5053892976 |
| countries_distinct_count | 0 |
| institutions_distinct_count | 3 |
| citation_normalized_percentile.value | 0.013593 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |