PdCu Electrocatalysts for Selective Nitrate and Nitrite Reduction to Nitrogen Article Swipe

View

Jeonghoon Lim , Yu Chen , David A. Cullen , Seung Woo Lee , Thomas P. Senftle , Marta C. Hatzell ·

YOU? · · 2022 · Open Access · · DOI: https://doi.org/10.1021/acscatal.2c04841

Electrocatalytic conversion of nitrate in waste can enable efficient waste remediation (NO₃^- to N₂) or waste valorization (NO₃^- to NH₄⁺) depending on the selectivity of the catalyst. Palladium and copper electrocatalysts typically exhibit ideal nitrate and nitrite binding properties, allowing for effective destruction of nitrate. However, rational steering of selectivity through material design remains a critical challenge for PdCu electrocatalyst. Here, we use the electrochemical underpotential deposition method to synthesize palladium nanocube electrocataysts with controlled copper surface coverage (e.g., partial and full copper coatings). We then examine the potential for NO₃^- destruction (conversion) and NO₂^- reduction reaction. We identify that partial copper-coated Pd nanocubes not only effectively facilitate the reduction of 95% of NO₃^- but also increase the reduction of NO₂^- to N₂ with 89% selectivity over 20 consecutive cycles (80 h). We also show that under these conditions, the Pd(100) surface facet is exposed. Complete copper-covered Pd nanocubes effectively facilitate the reduction of ~99% of NO₃^-. Complete coverage of copper; however, prevented exposure of Pd(100) surface facet, promoting the selective reduction of NO₂^- to NH₄⁺ with a 70% selectivity over 20 consecutive cycles (80 h). Density functional theory (DFT) calculations show that NO₃^- and NO₂^- adsorb more strongly on the Cu(100) surface compared to the Pd(100) surface, while the NO* intermediate generated from NO₃^- or NO₂^- reduction adsorbs more strongly on the Pd surface. Furthermore, barrier calculations show that NO* can readily migrate from the Cu domain to the Pd domain and that the N–N coupling barrier on Pd is significantly diminished at high NO* coverage. Together, these results suggest that the high N₂ selectivity observed on the PdCu electrocatalyst is caused by the spillover of NO* from the Cu domains to the Pd domains.

Related Topics

Concepts

Electrocatalyst Selectivity Copper Catalysis Underpotential deposition Inorganic chemistry Palladium Nitrate Nitrite Chemistry Electrochemistry Adsorption Materials science Cyclic voltammetry Electrode Physical chemistry Organic chemistry

Metadata

Type: article
Language: en
Landing Page: https://doi.org/10.1021/acscatal.2c04841
OA Status: green
Cited By: 76
References: 73
Related Works: 10
OpenAlex ID: https://openalex.org/W4312131157

All OpenAlex metadata

Raw OpenAlex JSON

OpenAlex ID: https://openalex.org/W4312131157

Canonical identifier for this work in OpenAlex
DOI: https://doi.org/10.1021/acscatal.2c04841

Digital Object Identifier
Title: PdCu Electrocatalysts for Selective Nitrate and Nitrite Reduction to Nitrogen

Work title
Type: article

OpenAlex work type
Language: en

Primary language
Publication year: 2022

Year of publication
Publication date: 2022-12-12

Full publication date if available
Authors: Jeonghoon Lim, Yu Chen, David A. Cullen, Seung Woo Lee, Thomas P. Senftle, Marta C. Hatzell

List of authors in order
Landing page: https://doi.org/10.1021/acscatal.2c04841

Publisher landing page
Open access: Yes

Whether a free full text is available
OA status: green

Open access status per OpenAlex
OA URL: https://www.osti.gov/biblio/1997736

Direct OA link when available
Concepts: Electrocatalyst, Selectivity, Copper, Catalysis, Underpotential deposition, Inorganic chemistry, Palladium, Nitrate, Nitrite, Chemistry, Electrochemistry, Adsorption, Materials science, Cyclic voltammetry, Electrode, Physical chemistry, Organic chemistry

Top concepts (fields/topics) attached by OpenAlex
Cited by: 76

Total citation count in OpenAlex
Citations by year (recent): 2025: 34, 2024: 28, 2023: 14

Per-year citation counts (last 5 years)
References (count): 73

Number of works referenced by this work
Related works (count): 10

Other works algorithmically related by OpenAlex

Full payload

id	https://openalex.org/W4312131157
doi	https://doi.org/10.1021/acscatal.2c04841
ids.doi	https://doi.org/10.1021/acscatal.2c04841
ids.openalex	https://openalex.org/W4312131157
fwci	5.15575751
type	article
title	PdCu Electrocatalysts for Selective Nitrate and Nitrite Reduction to Nitrogen
biblio.issue	1
biblio.volume	13
biblio.last_page	98
biblio.first_page	87
grants[0].funder	https://openalex.org/F4320306202
grants[0].award_id	10615
grants[0].funder_display_name	Gordon and Betty Moore Foundation
grants[1].funder	https://openalex.org/F4320337390
grants[1].award_id	1846611
grants[1].funder_display_name	Division of Chemical, Bioengineering, Environmental, and Transport Systems
grants[2].funder	https://openalex.org/F4320337390
grants[2].award_id	1933646
grants[2].funder_display_name	Division of Chemical, Bioengineering, Environmental, and Transport Systems
grants[3].funder	https://openalex.org/F4320337390
grants[3].award_id	2133576
grants[3].funder_display_name	Division of Chemical, Bioengineering, Environmental, and Transport Systems
grants[4].funder	https://openalex.org/F4320337394
grants[4].award_id	EEC-1449500
grants[4].funder_display_name	Division of Engineering Education and Centers
topics[0].id	https://openalex.org/T12112
topics[0].field.id	https://openalex.org/fields/15
topics[0].field.display_name	Chemical Engineering
topics[0].score	0.9998999834060669
topics[0].domain.id	https://openalex.org/domains/3
topics[0].domain.display_name	Physical Sciences
topics[0].subfield.id	https://openalex.org/subfields/1503
topics[0].subfield.display_name	Catalysis
topics[0].display_name	Ammonia Synthesis and Nitrogen Reduction
topics[1].id	https://openalex.org/T11478
topics[1].field.id	https://openalex.org/fields/17
topics[1].field.display_name	Computer Science
topics[1].score	0.9857000112533569
topics[1].domain.id	https://openalex.org/domains/3
topics[1].domain.display_name	Physical Sciences
topics[1].subfield.id	https://openalex.org/subfields/1705
topics[1].subfield.display_name	Computer Networks and Communications
topics[1].display_name	Caching and Content Delivery
topics[2].id	https://openalex.org/T10078
topics[2].field.id	https://openalex.org/fields/21
topics[2].field.display_name	Energy
topics[2].score	0.975600004196167
topics[2].domain.id	https://openalex.org/domains/3
topics[2].domain.display_name	Physical Sciences
topics[2].subfield.id	https://openalex.org/subfields/2105
topics[2].subfield.display_name	Renewable Energy, Sustainability and the Environment
topics[2].display_name	Advanced Photocatalysis Techniques
funders[0].id	https://openalex.org/F4320306202
funders[0].ror	https://ror.org/006wxqw41
funders[0].display_name	Gordon and Betty Moore Foundation
funders[1].id	https://openalex.org/F4320337390
funders[1].ror	https://ror.org/0471zv972
funders[1].display_name	Division of Chemical, Bioengineering, Environmental, and Transport Systems
funders[2].id	https://openalex.org/F4320337394
funders[2].ror	https://ror.org/050rnw378
funders[2].display_name	Division of Engineering Education and Centers
is_xpac	False
apc_list
apc_paid
concepts[0].id	https://openalex.org/C33989665
concepts[0].level	4
concepts[0].score	0.6859971284866333
concepts[0].wikidata	https://www.wikidata.org/wiki/Q5357962
concepts[0].display_name	Electrocatalyst
concepts[1].id	https://openalex.org/C118792377
concepts[1].level	3
concepts[1].score	0.6724134087562561
concepts[1].wikidata	https://www.wikidata.org/wiki/Q108584245
concepts[1].display_name	Selectivity
concepts[2].id	https://openalex.org/C544778455
concepts[2].level	2
concepts[2].score	0.6313912272453308
concepts[2].wikidata	https://www.wikidata.org/wiki/Q753
concepts[2].display_name	Copper
concepts[3].id	https://openalex.org/C161790260
concepts[3].level	2
concepts[3].score	0.61857008934021
concepts[3].wikidata	https://www.wikidata.org/wiki/Q82264
concepts[3].display_name	Catalysis
concepts[4].id	https://openalex.org/C2776572004
concepts[4].level	5
concepts[4].score	0.6099201440811157
concepts[4].wikidata	https://www.wikidata.org/wiki/Q7883754
concepts[4].display_name	Underpotential deposition
concepts[5].id	https://openalex.org/C179104552
concepts[5].level	1
concepts[5].score	0.5920720100402832
concepts[5].wikidata	https://www.wikidata.org/wiki/Q11165
concepts[5].display_name	Inorganic chemistry
concepts[6].id	https://openalex.org/C502130503
concepts[6].level	3
concepts[6].score	0.5799617767333984
concepts[6].wikidata	https://www.wikidata.org/wiki/Q1089
concepts[6].display_name	Palladium
concepts[7].id	https://openalex.org/C2776384668
concepts[7].level	2
concepts[7].score	0.563819408416748
concepts[7].wikidata	https://www.wikidata.org/wiki/Q182168
concepts[7].display_name	Nitrate
concepts[8].id	https://openalex.org/C2776179834
concepts[8].level	3
concepts[8].score	0.5450003147125244
concepts[8].wikidata	https://www.wikidata.org/wiki/Q72158415
concepts[8].display_name	Nitrite
concepts[9].id	https://openalex.org/C185592680
concepts[9].level	0
concepts[9].score	0.5448631048202515
concepts[9].wikidata	https://www.wikidata.org/wiki/Q2329
concepts[9].display_name	Chemistry
concepts[10].id	https://openalex.org/C52859227
concepts[10].level	3
concepts[10].score	0.5303602814674377
concepts[10].wikidata	https://www.wikidata.org/wiki/Q7877
concepts[10].display_name	Electrochemistry
concepts[11].id	https://openalex.org/C150394285
concepts[11].level	2
concepts[11].score	0.4552645981311798
concepts[11].wikidata	https://www.wikidata.org/wiki/Q180254
concepts[11].display_name	Adsorption
concepts[12].id	https://openalex.org/C192562407
concepts[12].level	0
concepts[12].score	0.35927239060401917
concepts[12].wikidata	https://www.wikidata.org/wiki/Q228736
concepts[12].display_name	Materials science
concepts[13].id	https://openalex.org/C2777869211
concepts[13].level	4
concepts[13].score	0.12740200757980347
concepts[13].wikidata	https://www.wikidata.org/wiki/Q1147647
concepts[13].display_name	Cyclic voltammetry
concepts[14].id	https://openalex.org/C17525397
concepts[14].level	2
concepts[14].score	0.11210569739341736
concepts[14].wikidata	https://www.wikidata.org/wiki/Q176140
concepts[14].display_name	Electrode
concepts[15].id	https://openalex.org/C147789679
concepts[15].level	1
concepts[15].score	0.08595967292785645
concepts[15].wikidata	https://www.wikidata.org/wiki/Q11372
concepts[15].display_name	Physical chemistry
concepts[16].id	https://openalex.org/C178790620
concepts[16].level	1
concepts[16].score	0.08202502131462097
concepts[16].wikidata	https://www.wikidata.org/wiki/Q11351
concepts[16].display_name	Organic chemistry
keywords[0].id	https://openalex.org/keywords/electrocatalyst
keywords[0].score	0.6859971284866333
keywords[0].display_name	Electrocatalyst
keywords[1].id	https://openalex.org/keywords/selectivity
keywords[1].score	0.6724134087562561
keywords[1].display_name	Selectivity
keywords[2].id	https://openalex.org/keywords/copper
keywords[2].score	0.6313912272453308
keywords[2].display_name	Copper
keywords[3].id	https://openalex.org/keywords/catalysis
keywords[3].score	0.61857008934021
keywords[3].display_name	Catalysis
keywords[4].id	https://openalex.org/keywords/underpotential-deposition
keywords[4].score	0.6099201440811157
keywords[4].display_name	Underpotential deposition
keywords[5].id	https://openalex.org/keywords/inorganic-chemistry
keywords[5].score	0.5920720100402832
keywords[5].display_name	Inorganic chemistry
keywords[6].id	https://openalex.org/keywords/palladium
keywords[6].score	0.5799617767333984
keywords[6].display_name	Palladium
keywords[7].id	https://openalex.org/keywords/nitrate
keywords[7].score	0.563819408416748
keywords[7].display_name	Nitrate
keywords[8].id	https://openalex.org/keywords/nitrite
keywords[8].score	0.5450003147125244
keywords[8].display_name	Nitrite
keywords[9].id	https://openalex.org/keywords/chemistry
keywords[9].score	0.5448631048202515
keywords[9].display_name	Chemistry
keywords[10].id	https://openalex.org/keywords/electrochemistry
keywords[10].score	0.5303602814674377
keywords[10].display_name	Electrochemistry
keywords[11].id	https://openalex.org/keywords/adsorption
keywords[11].score	0.4552645981311798
keywords[11].display_name	Adsorption
keywords[12].id	https://openalex.org/keywords/materials-science
keywords[12].score	0.35927239060401917
keywords[12].display_name	Materials science
keywords[13].id	https://openalex.org/keywords/cyclic-voltammetry
keywords[13].score	0.12740200757980347
keywords[13].display_name	Cyclic voltammetry
keywords[14].id	https://openalex.org/keywords/electrode
keywords[14].score	0.11210569739341736
keywords[14].display_name	Electrode
keywords[15].id	https://openalex.org/keywords/physical-chemistry
keywords[15].score	0.08595967292785645
keywords[15].display_name	Physical chemistry
keywords[16].id	https://openalex.org/keywords/organic-chemistry
keywords[16].score	0.08202502131462097
keywords[16].display_name	Organic chemistry
language	en
locations[0].id	doi:10.1021/acscatal.2c04841
locations[0].is_oa	False
locations[0].source.id	https://openalex.org/S37391459
locations[0].source.issn	2155-5435
locations[0].source.type	journal
locations[0].source.is_oa	False
locations[0].source.issn_l	2155-5435
locations[0].source.is_core	True
locations[0].source.is_in_doaj	False
locations[0].source.display_name	ACS Catalysis
locations[0].source.host_organization	https://openalex.org/P4310320006
locations[0].source.host_organization_name	American Chemical Society
locations[0].source.host_organization_lineage	https://openalex.org/P4310320006
locations[0].license
locations[0].pdf_url
locations[0].version	publishedVersion
locations[0].raw_type	journal-article
locations[0].license_id
locations[0].is_accepted	True
locations[0].is_published	True
locations[0].raw_source_name	ACS Catalysis
locations[0].landing_page_url	https://doi.org/10.1021/acscatal.2c04841
locations[1].id	pmh:oai:osti.gov:1997736
locations[1].is_oa	True
locations[1].source.id	https://openalex.org/S4306402487
locations[1].source.issn
locations[1].source.type	repository
locations[1].source.is_oa	False
locations[1].source.issn_l
locations[1].source.is_core	False
locations[1].source.is_in_doaj	False
locations[1].source.display_name	OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)
locations[1].source.host_organization	https://openalex.org/I139351228
locations[1].source.host_organization_name	Office of Scientific and Technical Information
locations[1].source.host_organization_lineage	https://openalex.org/I139351228
locations[1].license
locations[1].pdf_url
locations[1].version	submittedVersion
locations[1].raw_type
locations[1].license_id
locations[1].is_accepted	False
locations[1].is_published	False
locations[1].raw_source_name
locations[1].landing_page_url	https://www.osti.gov/biblio/1997736
indexed_in	crossref
authorships[0].author.id	https://openalex.org/A5077774633
authorships[0].author.orcid	https://orcid.org/0000-0002-5254-2296
authorships[0].author.display_name	Jeonghoon Lim
authorships[0].countries	US
authorships[0].affiliations[0].institution_ids	https://openalex.org/I130701444
authorships[0].affiliations[0].raw_affiliation_string	George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia30313, United States
authorships[0].institutions[0].id	https://openalex.org/I130701444
authorships[0].institutions[0].ror	https://ror.org/01zkghx44
authorships[0].institutions[0].type	education
authorships[0].institutions[0].lineage	https://openalex.org/I130701444
authorships[0].institutions[0].country_code	US
authorships[0].institutions[0].display_name	Georgia Institute of Technology
authorships[0].author_position	first
authorships[0].raw_author_name	Jeonghoon Lim
authorships[0].is_corresponding	False
authorships[0].raw_affiliation_strings	George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia30313, United States
authorships[1].author.id	https://openalex.org/A5100401978
authorships[1].author.orcid	https://orcid.org/0000-0001-9545-6761
authorships[1].author.display_name	Yu Chen
authorships[1].countries	US
authorships[1].affiliations[0].institution_ids	https://openalex.org/I74775410
authorships[1].affiliations[0].raw_affiliation_string	Department of Chemical and Biomolecular Engineering, Rice University, Houston, Texas77005, United States
authorships[1].institutions[0].id	https://openalex.org/I74775410
authorships[1].institutions[0].ror	https://ror.org/008zs3103
authorships[1].institutions[0].type	education
authorships[1].institutions[0].lineage	https://openalex.org/I74775410
authorships[1].institutions[0].country_code	US
authorships[1].institutions[0].display_name	Rice University
authorships[1].author_position	middle
authorships[1].raw_author_name	Yu Chen
authorships[1].is_corresponding	False
authorships[1].raw_affiliation_strings	Department of Chemical and Biomolecular Engineering, Rice University, Houston, Texas77005, United States
authorships[2].author.id	https://openalex.org/A5078427681
authorships[2].author.orcid	https://orcid.org/0000-0002-2593-7866
authorships[2].author.display_name	David A. Cullen
authorships[2].countries	US
authorships[2].affiliations[0].institution_ids	https://openalex.org/I1289243028
authorships[2].affiliations[0].raw_affiliation_string	Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee37831, United States
authorships[2].institutions[0].id	https://openalex.org/I1289243028
authorships[2].institutions[0].ror	https://ror.org/01qz5mb56
authorships[2].institutions[0].type	facility
authorships[2].institutions[0].lineage	https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294
authorships[2].institutions[0].country_code	US
authorships[2].institutions[0].display_name	Oak Ridge National Laboratory
authorships[2].author_position	middle
authorships[2].raw_author_name	David A. Cullen
authorships[2].is_corresponding	False
authorships[2].raw_affiliation_strings	Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee37831, United States
authorships[3].author.id	https://openalex.org/A5100671067
authorships[3].author.orcid	https://orcid.org/0000-0002-2695-7105
authorships[3].author.display_name	Seung Woo Lee
authorships[3].countries	US
authorships[3].affiliations[0].institution_ids	https://openalex.org/I130701444
authorships[3].affiliations[0].raw_affiliation_string	George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia30313, United States
authorships[3].institutions[0].id	https://openalex.org/I130701444
authorships[3].institutions[0].ror	https://ror.org/01zkghx44
authorships[3].institutions[0].type	education
authorships[3].institutions[0].lineage	https://openalex.org/I130701444
authorships[3].institutions[0].country_code	US
authorships[3].institutions[0].display_name	Georgia Institute of Technology
authorships[3].author_position	middle
authorships[3].raw_author_name	Seung Woo Lee
authorships[3].is_corresponding	True
authorships[3].raw_affiliation_strings	George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia30313, United States
authorships[4].author.id	https://openalex.org/A5067754249
authorships[4].author.orcid	https://orcid.org/0000-0002-5889-5009
authorships[4].author.display_name	Thomas P. Senftle
authorships[4].countries	US
authorships[4].affiliations[0].institution_ids	https://openalex.org/I74775410
authorships[4].affiliations[0].raw_affiliation_string	Department of Chemical and Biomolecular Engineering, Rice University, Houston, Texas77005, United States
authorships[4].institutions[0].id	https://openalex.org/I74775410
authorships[4].institutions[0].ror	https://ror.org/008zs3103
authorships[4].institutions[0].type	education
authorships[4].institutions[0].lineage	https://openalex.org/I74775410
authorships[4].institutions[0].country_code	US
authorships[4].institutions[0].display_name	Rice University
authorships[4].author_position	middle
authorships[4].raw_author_name	Thomas P. Senftle
authorships[4].is_corresponding	True
authorships[4].raw_affiliation_strings	Department of Chemical and Biomolecular Engineering, Rice University, Houston, Texas77005, United States
authorships[5].author.id	https://openalex.org/A5014967427
authorships[5].author.orcid	https://orcid.org/0000-0002-5144-4969
authorships[5].author.display_name	Marta C. Hatzell
authorships[5].countries	US
authorships[5].affiliations[0].institution_ids	https://openalex.org/I130701444
authorships[5].affiliations[0].raw_affiliation_string	George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia30313, United States
authorships[5].affiliations[1].institution_ids	https://openalex.org/I130701444
authorships[5].affiliations[1].raw_affiliation_string	Department of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia30313, United States
authorships[5].institutions[0].id	https://openalex.org/I130701444
authorships[5].institutions[0].ror	https://ror.org/01zkghx44
authorships[5].institutions[0].type	education
authorships[5].institutions[0].lineage	https://openalex.org/I130701444
authorships[5].institutions[0].country_code	US
authorships[5].institutions[0].display_name	Georgia Institute of Technology
authorships[5].author_position	last
authorships[5].raw_author_name	Marta C. Hatzell
authorships[5].is_corresponding	True
authorships[5].raw_affiliation_strings	Department of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia30313, United States, George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia30313, United States
has_content.pdf	False
has_content.grobid_xml	False
is_paratext	False
open_access.is_oa	True
open_access.oa_url	https://www.osti.gov/biblio/1997736
open_access.oa_status	green
open_access.any_repository_has_fulltext	False
created_date	2025-10-10T00:00:00
display_name	PdCu Electrocatalysts for Selective Nitrate and Nitrite Reduction to Nitrogen
has_fulltext	False
is_retracted	False
updated_date	2025-11-06T03:46:38.306776
primary_topic.id	https://openalex.org/T12112
primary_topic.field.id	https://openalex.org/fields/15
primary_topic.field.display_name	Chemical Engineering
primary_topic.score	0.9998999834060669
primary_topic.domain.id	https://openalex.org/domains/3
primary_topic.domain.display_name	Physical Sciences
primary_topic.subfield.id	https://openalex.org/subfields/1503
primary_topic.subfield.display_name	Catalysis
primary_topic.display_name	Ammonia Synthesis and Nitrogen Reduction
related_works	https://openalex.org/W2422268761, https://openalex.org/W2377014924, https://openalex.org/W2349417293, https://openalex.org/W2001030372, https://openalex.org/W2469871545, https://openalex.org/W2014641966, https://openalex.org/W1997280067, https://openalex.org/W2353906574, https://openalex.org/W2008411648, https://openalex.org/W2133855736
cited_by_count	76
counts_by_year[0].year	2025
counts_by_year[0].cited_by_count	34
counts_by_year[1].year	2024
counts_by_year[1].cited_by_count	28
counts_by_year[2].year	2023
counts_by_year[2].cited_by_count	14
locations_count	2
best_oa_location.id	pmh:oai:osti.gov:1997736
best_oa_location.is_oa	True
best_oa_location.source.id	https://openalex.org/S4306402487
best_oa_location.source.issn
best_oa_location.source.type	repository
best_oa_location.source.is_oa	False
best_oa_location.source.issn_l
best_oa_location.source.is_core	False
best_oa_location.source.is_in_doaj	False
best_oa_location.source.display_name	OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)
best_oa_location.source.host_organization	https://openalex.org/I139351228
best_oa_location.source.host_organization_name	Office of Scientific and Technical Information
best_oa_location.source.host_organization_lineage	https://openalex.org/I139351228
best_oa_location.license
best_oa_location.pdf_url
best_oa_location.version	submittedVersion
best_oa_location.raw_type
best_oa_location.license_id
best_oa_location.is_accepted	False
best_oa_location.is_published	False
best_oa_location.raw_source_name
best_oa_location.landing_page_url	https://www.osti.gov/biblio/1997736
primary_location.id	doi:10.1021/acscatal.2c04841
primary_location.is_oa	False
primary_location.source.id	https://openalex.org/S37391459
primary_location.source.issn	2155-5435
primary_location.source.type	journal
primary_location.source.is_oa	False
primary_location.source.issn_l	2155-5435
primary_location.source.is_core	True
primary_location.source.is_in_doaj	False
primary_location.source.display_name	ACS Catalysis
primary_location.source.host_organization	https://openalex.org/P4310320006
primary_location.source.host_organization_name	American Chemical Society
primary_location.source.host_organization_lineage	https://openalex.org/P4310320006
primary_location.license
primary_location.pdf_url
primary_location.version	publishedVersion
primary_location.raw_type	journal-article
primary_location.license_id
primary_location.is_accepted	True
primary_location.is_published	True
primary_location.raw_source_name	ACS Catalysis
primary_location.landing_page_url	https://doi.org/10.1021/acscatal.2c04841
publication_date	2022-12-12
publication_year	2022
referenced_works	https://openalex.org/W2056965215, https://openalex.org/W2059682795, https://openalex.org/W2586571084, https://openalex.org/W3119611281, https://openalex.org/W1223267532, https://openalex.org/W3183258394, https://openalex.org/W2916417291, https://openalex.org/W2168604844, https://openalex.org/W1967933041, https://openalex.org/W3162716597, https://openalex.org/W3007496678, https://openalex.org/W2324412451, https://openalex.org/W2315205495, https://openalex.org/W2042013708, https://openalex.org/W2334838983, https://openalex.org/W1846931294, https://openalex.org/W2066912155, https://openalex.org/W2803724286, https://openalex.org/W3082685031, https://openalex.org/W2967943904, https://openalex.org/W3130708786, https://openalex.org/W3011424054, https://openalex.org/W2151201269, https://openalex.org/W1982564281, https://openalex.org/W2583319567, https://openalex.org/W3089344870, https://openalex.org/W2751278640, https://openalex.org/W2063523063, https://openalex.org/W2069118064, https://openalex.org/W2134568909, https://openalex.org/W1918473099, https://openalex.org/W2084384441, https://openalex.org/W3026130639, https://openalex.org/W2957867822, https://openalex.org/W3166266210, https://openalex.org/W2515441543, https://openalex.org/W2581493313, https://openalex.org/W3183937053, https://openalex.org/W4254607243, https://openalex.org/W3162642496, https://openalex.org/W2769259860, https://openalex.org/W3101519145, https://openalex.org/W2289106567, https://openalex.org/W2057252025, https://openalex.org/W4206215482, https://openalex.org/W2069579692, https://openalex.org/W2991620613, https://openalex.org/W2062930349, https://openalex.org/W2023356345, https://openalex.org/W2955271045, https://openalex.org/W2098360158, https://openalex.org/W2588496490, https://openalex.org/W4206269059, https://openalex.org/W2093954283, https://openalex.org/W2095309853, https://openalex.org/W2154531412, https://openalex.org/W2083222334, https://openalex.org/W2007395042, https://openalex.org/W1970127494, https://openalex.org/W1979544533, https://openalex.org/W1981368803, https://openalex.org/W2092157292, https://openalex.org/W2036113194, https://openalex.org/W2064807075, https://openalex.org/W2122427541, https://openalex.org/W2031430816, https://openalex.org/W2004751437, https://openalex.org/W2332877952, https://openalex.org/W1965092590, https://openalex.org/W2167035995, https://openalex.org/W4243280602, https://openalex.org/W4298852971, https://openalex.org/W4250431566
referenced_works_count	73
abstract_inverted_index.a	54, 177
abstract_inverted_index.20	127, 181
abstract_inverted_index.Cu	236, 280
abstract_inverted_index.Pd	102, 147, 223, 240, 249, 284
abstract_inverted_index.We	84, 97, 132
abstract_inverted_index.at	253
abstract_inverted_index.by	273
abstract_inverted_index.in	4
abstract_inverted_index.is	143, 250, 271
abstract_inverted_index.of	2, 24, 43, 48, 110, 112, 119, 153, 155, 159, 164, 172, 276
abstract_inverted_index.on	21, 199, 221, 248, 267
abstract_inverted_index.or	14, 215
abstract_inverted_index.to	12, 18, 68, 121, 174, 204, 238, 282
abstract_inverted_index.we	61
abstract_inverted_index.(80	130, 184
abstract_inverted_index.70%	178
abstract_inverted_index.89%	124
abstract_inverted_index.95%	111
abstract_inverted_index.NO*	210, 230, 255, 277
abstract_inverted_index.and	28, 35, 80, 93, 194, 242
abstract_inverted_index.but	114
abstract_inverted_index.can	6, 231
abstract_inverted_index.for	40, 57, 89
abstract_inverted_index.h).	131, 185
abstract_inverted_index.not	104
abstract_inverted_index.the	22, 25, 63, 87, 108, 117, 139, 151, 169, 200, 205, 209, 222, 235, 239, 244, 262, 268, 274, 279, 283
abstract_inverted_index.use	62
abstract_inverted_index.PdCu	58, 269
abstract_inverted_index.also	115, 133
abstract_inverted_index.from	213, 234, 278
abstract_inverted_index.full	81
abstract_inverted_index.high	254, 263
abstract_inverted_index.more	197, 219
abstract_inverted_index.only	105
abstract_inverted_index.over	126, 180
abstract_inverted_index.show	134, 191, 228
abstract_inverted_index.that	99, 135, 192, 229, 243, 261
abstract_inverted_index.then	85
abstract_inverted_index.with	73, 123, 176
abstract_inverted_index.~99%	154
abstract_inverted_index.(DFT)	189
abstract_inverted_index.Here,	60
abstract_inverted_index.N–N	245
abstract_inverted_index.facet	142
abstract_inverted_index.ideal	33
abstract_inverted_index.these	137, 258
abstract_inverted_index.under	136
abstract_inverted_index.waste	5, 9, 15
abstract_inverted_index.while	208
abstract_inverted_index.(e.g.,	78
abstract_inverted_index.adsorb	196
abstract_inverted_index.caused	272
abstract_inverted_index.copper	29, 75, 82
abstract_inverted_index.cycles	129, 183
abstract_inverted_index.design	52
abstract_inverted_index.domain	237, 241
abstract_inverted_index.enable	7
abstract_inverted_index.facet,	167
abstract_inverted_index.method	67
abstract_inverted_index.theory	188
abstract_inverted_index.Cu(100)	201
abstract_inverted_index.Density	186
abstract_inverted_index.Pd(100)	140, 165, 206
abstract_inverted_index.adsorbs	218
abstract_inverted_index.barrier	226, 247
abstract_inverted_index.binding	37
abstract_inverted_index.copper;	160
abstract_inverted_index.domains	281
abstract_inverted_index.examine	86
abstract_inverted_index.exhibit	32
abstract_inverted_index.migrate	233
abstract_inverted_index.nitrate	3, 34
abstract_inverted_index.nitrite	36
abstract_inverted_index.partial	79, 100
abstract_inverted_index.readily	232
abstract_inverted_index.remains	53
abstract_inverted_index.results	259
abstract_inverted_index.suggest	260
abstract_inverted_index.surface	76, 141, 166, 202
abstract_inverted_index.through	50
abstract_inverted_index.Complete	145, 157
abstract_inverted_index.However,	45
abstract_inverted_index.allowing	39
abstract_inverted_index.compared	203
abstract_inverted_index.coupling	246
abstract_inverted_index.coverage	77, 158
abstract_inverted_index.critical	55
abstract_inverted_index.domains.	285
abstract_inverted_index.exposed.	144
abstract_inverted_index.exposure	163
abstract_inverted_index.however,	161
abstract_inverted_index.identify	98
abstract_inverted_index.increase	116
abstract_inverted_index.material	51
abstract_inverted_index.nanocube	71
abstract_inverted_index.nitrate.	44
abstract_inverted_index.observed	266
abstract_inverted_index.rational	46
abstract_inverted_index.steering	47
abstract_inverted_index.strongly	198, 220
abstract_inverted_index.surface,	207
abstract_inverted_index.surface.	224
abstract_inverted_index.Palladium	27
abstract_inverted_index.Together,	257
abstract_inverted_index.catalyst.	26
abstract_inverted_index.challenge	56
abstract_inverted_index.coverage.	256
abstract_inverted_index.depending	20
abstract_inverted_index.effective	41
abstract_inverted_index.efficient	8
abstract_inverted_index.generated	212
abstract_inverted_index.nanocubes	103, 148
abstract_inverted_index.palladium	70
abstract_inverted_index.potential	88
abstract_inverted_index.prevented	162
abstract_inverted_index.promoting	168
abstract_inverted_index.reaction.	96
abstract_inverted_index.reduction	95, 109, 118, 152, 171, 217
abstract_inverted_index.selective	170
abstract_inverted_index.spillover	275
abstract_inverted_index.typically	31
abstract_inverted_index.coatings).	83
abstract_inverted_index.controlled	74
abstract_inverted_index.conversion	1
abstract_inverted_index.deposition	66
abstract_inverted_index.diminished	252
abstract_inverted_index.facilitate	107, 150
abstract_inverted_index.functional	187
abstract_inverted_index.synthesize	69
abstract_inverted_index.conditions,	138
abstract_inverted_index.consecutive	128, 182
abstract_inverted_index.destruction	42, 91
abstract_inverted_index.effectively	106, 149
abstract_inverted_index.properties,	38
abstract_inverted_index.remediation	10
abstract_inverted_index.selectivity	23, 49, 125, 179, 265
abstract_inverted_index.(conversion)	92
abstract_inverted_index.Furthermore,	225
abstract_inverted_index.calculations	190, 227
abstract_inverted_index.intermediate	211
abstract_inverted_index.valorization	16
abstract_inverted_index.copper-coated	101
abstract_inverted_index.significantly	251
abstract_inverted_index.copper-covered	146
abstract_inverted_index.underpotential	65
abstract_inverted_index.electrocatalyst	270
abstract_inverted_index.electrocataysts	72
abstract_inverted_index.electrochemical	64
abstract_inverted_index.Electrocatalytic	0
abstract_inverted_index.electrocatalyst.	59
abstract_inverted_index.electrocatalysts	30
abstract_inverted_index.N<sub>2</sub>	122, 264
abstract_inverted_index.N<sub>2</sub>)	13
abstract_inverted_index.NH<sub>4</sub><sup>+</sup>	175
abstract_inverted_index.NO<sub>2</sub><sup>-</sup>	94, 120, 173, 195, 216
abstract_inverted_index.NO<sub>3</sub><sup>-</sup>	90, 113, 193, 214
abstract_inverted_index.(NO<sub>3</sub><sup>-</sup>	11, 17
abstract_inverted_index.NH<sub>4</sub><sup>+</sup>)	19
abstract_inverted_index.NO<sub>3</sub><sup>-</sup>.	156
cited_by_percentile_year.max	100
cited_by_percentile_year.min	99
corresponding_author_ids	https://openalex.org/A5100671067, https://openalex.org/A5067754249, https://openalex.org/A5014967427
countries_distinct_count	1
institutions_distinct_count	6
corresponding_institution_ids	https://openalex.org/I130701444, https://openalex.org/I74775410
citation_normalized_percentile.value	0.955931
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	True