Phosphonium-Based Polyzwitterions: Influence of Ionic Structure and Association on Mechanical Properties Article Swipe
Philip J. Scott
,
Glenn A. Spiering
,
Yangyang Wang
,
Zach D. Seibers
,
Robert B. Moore
,
Rajeev Kumar
,
Bradley S. Lokitz
,
Timothy E. Long
·
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1021/acs.macromol.0c02166
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1021/acs.macromol.0c02166
This manuscript describes a synthetic strategy and structure–property investigation of unprecedented phosphonium-based zwitterionic homopolymers (polyzwitterions) and random copolymers (zwitterionomers). Free radical polymerization of 4-(diphenylphosphino)styrene (DPPS) provided neutral polymers containing reactive triarylphosphines. Quantitative postpolymerization alkylation of these pendant functionalities generated a library of polymers containing various concentrations of neutral phosphines, phosphonium ions, and phosphonium sulfobetaine zwitterions. The zwitterionic homo- and copolymers exhibited significantly higher glass transition temperatures (Tg) and enhanced mechanical reinforcement in comparison to neutral and phosphonium analogues. These changes in Tg and mechanical properties were attributed to nanoscale morphological domains, which formed due to electrostatic interactions between zwitterionic groups, as revealed by X-ray scattering and broadband dielectric spectroscopy (BDS). BDS revealed increased static dielectric constants (>25) for the phosphonium zwitterionomers compared to ionomeric or neutral analogues. These high static dielectric constants for the solvent-free polyzwitterions supported their stronger polarization response in comparison with polymers containing neutral phosphines and phosphonium ions, and these interactions accounted for morphological differences and enhanced mechanical behavior. This work describes a versatile strategy for modulating electrostatic interactions with tunable mechanical properties for an unprecedented family of zwitterionic polymers.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.macromol.0c02166
- OA Status
- green
- Cited By
- 21
- References
- 59
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3108693819
All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W3108693819Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.macromol.0c02166Digital Object Identifier
- Title
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Phosphonium-Based Polyzwitterions: Influence of Ionic Structure and Association on Mechanical PropertiesWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2020Year of publication
- Publication date
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2020-12-03Full publication date if available
- Authors
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Philip J. Scott, Glenn A. Spiering, Yangyang Wang, Zach D. Seibers, Robert B. Moore, Rajeev Kumar, Bradley S. Lokitz, Timothy E. LongList of authors in order
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https://doi.org/10.1021/acs.macromol.0c02166Publisher landing page
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
- OA URL
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https://www.osti.gov/biblio/1822093Direct OA link when available
- Concepts
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Phosphonium, Polymer chemistry, Polymer, Chemistry, Copolymer, Polymerization, Materials science, Organic chemistryTop concepts (fields/topics) attached by OpenAlex
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21Total citation count in OpenAlex
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2025: 4, 2024: 2, 2023: 5, 2022: 5, 2021: 5Per-year citation counts (last 5 years)
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59Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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