Plasticizing Effects of Epoxidized Palm Oil on Mechanical and Thermal Properties of Poly(3-hydroxybutyrate-co-hydroxyvalerate)/Poly(caprolactone) Blends Article Swipe
Siti Aishah Ramli
,
Norhayani Othman
,
Aznizam Abu Bakar
,
Azman Hassan
·
YOU?
·
· 2021
· Open Access
·
· DOI: https://doi.org/10.3303/cet2183094
YOU?
·
· 2021
· Open Access
·
· DOI: https://doi.org/10.3303/cet2183094
Poly(hydroxybutyrate-co-valerate) (PHBV), a biodegradable thermoplastic polymer, has attracted much attention because of increasing interest in protection of environment. PHBV is brittle, thus has restricted application. Improvement of its toughness has been attempted by blending poly (caprolactone (PCL). In this study, PCL helps in improving elongation at break and impact properties of PHBV. PHBV/PCL blends were blended using internal mixer. Differential scanning calorimetry (DSC) was used to determine the thermal properties of the blends and tensile and impact test for the mechanical test of the blends. There are two melting peaks shown in the DSC data of PHBV/PCL due to melting of PHBV and PCL. 60/40 ratio of PHBV/PCL was chosen as the optimum composition as it showed the highest elongation at break with 4.2 % improvement compared to pure PHBV. This blend ratio also has the lowest melting temperature of PHBV among ratio studied. Although the properties of PHBV/PCL blends were better than those of neat PHBV, the immiscibility of PHBV and PCL shown from DSC results inhibits further improvement of the properties of the blend. To improve the miscibility of the blends, 1 phr of epoxidized palm oil (EPO) was added to 60/40 blends. EPO has been proven to act as a plasticizer that increased the elongation at break and impact strength of the PHBV/PCL blends. This indicates that although both PHBV and PCL blends are not fully miscible, interaction exists between PHBV, PCL and EPO.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doaj.org/article/80bd7eee3b804cd6859b67a2d64e757b
- OA Status
- green
- Cited By
- 7
- Related Works
- 20
- OpenAlex ID
- https://openalex.org/W3127485679
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W3127485679Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.3303/cet2183094Digital Object Identifier
- Title
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Plasticizing Effects of Epoxidized Palm Oil on Mechanical and Thermal Properties of Poly(3-hydroxybutyrate-co-hydroxyvalerate)/Poly(caprolactone) BlendsWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2021Year of publication
- Publication date
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2021-02-01Full publication date if available
- Authors
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Siti Aishah Ramli, Norhayani Othman, Aznizam Abu Bakar, Azman HassanList of authors in order
- Landing page
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https://doaj.org/article/80bd7eee3b804cd6859b67a2d64e757bPublisher landing page
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
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https://www.cetjournal.it/index.php/cet/article/view/CET2183094Direct OA link when available
- Concepts
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Materials science, Differential scanning calorimetry, Miscibility, Plasticizer, Composite material, Ultimate tensile strength, Thermoplastic, Polymer blend, Elongation, Polycaprolactone, Polymer, Copolymer, Physics, ThermodynamicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
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7Total citation count in OpenAlex
- Citations by year (recent)
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2025: 2, 2024: 1, 2023: 2, 2021: 2Per-year citation counts (last 5 years)
- Related works (count)
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20Other works algorithmically related by OpenAlex
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| abstract_inverted_index.(PHBV), | 1 |
| abstract_inverted_index.because | 10 |
| abstract_inverted_index.between | 232 |
| abstract_inverted_index.blended | 55 |
| abstract_inverted_index.blends, | 182 |
| abstract_inverted_index.blends. | 84, 194, 216 |
| abstract_inverted_index.further | 168 |
| abstract_inverted_index.highest | 118 |
| abstract_inverted_index.improve | 177 |
| abstract_inverted_index.melting | 88, 99, 137 |
| abstract_inverted_index.optimum | 112 |
| abstract_inverted_index.results | 166 |
| abstract_inverted_index.tensile | 74 |
| abstract_inverted_index.thermal | 68 |
| abstract_inverted_index.Although | 144 |
| abstract_inverted_index.PHBV/PCL | 52, 96, 107, 148, 215 |
| abstract_inverted_index.although | 220 |
| abstract_inverted_index.blending | 33 |
| abstract_inverted_index.brittle, | 20 |
| abstract_inverted_index.compared | 126 |
| abstract_inverted_index.inhibits | 167 |
| abstract_inverted_index.interest | 13 |
| abstract_inverted_index.internal | 57 |
| abstract_inverted_index.polymer, | 5 |
| abstract_inverted_index.scanning | 60 |
| abstract_inverted_index.strength | 212 |
| abstract_inverted_index.studied. | 143 |
| abstract_inverted_index.attempted | 31 |
| abstract_inverted_index.attention | 9 |
| abstract_inverted_index.attracted | 7 |
| abstract_inverted_index.determine | 66 |
| abstract_inverted_index.improving | 43 |
| abstract_inverted_index.increased | 205 |
| abstract_inverted_index.indicates | 218 |
| abstract_inverted_index.miscible, | 229 |
| abstract_inverted_index.toughness | 28 |
| abstract_inverted_index.elongation | 44, 119, 207 |
| abstract_inverted_index.epoxidized | 186 |
| abstract_inverted_index.increasing | 12 |
| abstract_inverted_index.mechanical | 80 |
| abstract_inverted_index.properties | 49, 69, 146, 172 |
| abstract_inverted_index.protection | 15 |
| abstract_inverted_index.restricted | 23 |
| abstract_inverted_index.Improvement | 25 |
| abstract_inverted_index.calorimetry | 61 |
| abstract_inverted_index.composition | 113 |
| abstract_inverted_index.improvement | 125, 169 |
| abstract_inverted_index.interaction | 230 |
| abstract_inverted_index.miscibility | 179 |
| abstract_inverted_index.plasticizer | 203 |
| abstract_inverted_index.temperature | 138 |
| abstract_inverted_index.Differential | 59 |
| abstract_inverted_index.application. | 24 |
| abstract_inverted_index.environment. | 17 |
| abstract_inverted_index.(caprolactone | 35 |
| abstract_inverted_index.biodegradable | 3 |
| abstract_inverted_index.immiscibility | 158 |
| abstract_inverted_index.thermoplastic | 4 |
| abstract_inverted_index.Poly(hydroxybutyrate-co-valerate) | 0 |
| cited_by_percentile_year.max | 97 |
| cited_by_percentile_year.min | 90 |
| countries_distinct_count | 0 |
| institutions_distinct_count | 4 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/15 |
| sustainable_development_goals[0].score | 0.47999998927116394 |
| sustainable_development_goals[0].display_name | Life in Land |
| citation_normalized_percentile.value | 0.54049301 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |