Polyalkenamers as Drop-In Additives for Ring-Opening Metathesis Polymerization: A Promising Upcycling Paradigm Article Swipe
Jeffrey C. Foster
,
Joshua T. Damron
,
Jackie Zheng
,
Chao Guan
,
Ilja Popovs
,
Md Anisur Rahman
,
Nicholas J. Galan
,
Isaiah T. Dishner
,
Tomonori Saito
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/jacs.4c10588
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/jacs.4c10588
We report a distinct strategy to upcycle waste polyalkenamers such as polybutadiene into new, performance-advantaged materials by using them as drop-in additives for ring-opening metathesis polymerization (ROMP). The polyalkenamers serve as competent chain-transfer agents in ROMPs of common classes of cyclic olefin monomers, facilitating good molecular weight control, allowing low Ru catalyst loadings, and enabling efficient incorporation of the polyalkenamer into the synthesized polymeric material. We successfully demonstrate ROMP using model polyalkenamers and translate these learnings to leverage commercial polybutadiene and acrylonitrile butadiene styrene (ABS) as chain transfer agents for ROMP copolymerizations. Critically, our strategy is shown to be highly efficient and operationally simple, quantitatively incorporating the polyalkenamer and inheriting aspects of its thermomechanical performance. Our results highlight a promising pathway for the upcycling of polyalkenamers and provide an alternative to existing deconstruction and functional upcycling strategies.
Related Topics
Concepts
Chemistry
Polymerization
Metathesis
Ring-opening metathesis polymerisation
Drop (telecommunication)
Ring-opening polymerization
Nanotechnology
Ring (chemistry)
Polymer chemistry
Polymer science
Chemical engineering
Organic chemistry
Polymer
Engineering
Telecommunications
Materials science
Computer science
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/jacs.4c10588
- OA Status
- green
- Cited By
- 8
- References
- 49
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4403867347
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4403867347Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/jacs.4c10588Digital Object Identifier
- Title
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Polyalkenamers as Drop-In Additives for Ring-Opening Metathesis Polymerization: A Promising Upcycling ParadigmWork title
- Type
-
articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-10-29Full publication date if available
- Authors
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Jeffrey C. Foster, Joshua T. Damron, Jackie Zheng, Chao Guan, Ilja Popovs, Md Anisur Rahman, Nicholas J. Galan, Isaiah T. Dishner, Tomonori SaitoList of authors in order
- Landing page
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https://doi.org/10.1021/jacs.4c10588Publisher landing page
- Open access
-
YesWhether a free full text is available
- OA status
-
greenOpen access status per OpenAlex
- OA URL
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https://www.osti.gov/servlets/purl/2538330Direct OA link when available
- Concepts
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Chemistry, Polymerization, Metathesis, Ring-opening metathesis polymerisation, Drop (telecommunication), Ring-opening polymerization, Nanotechnology, Ring (chemistry), Polymer chemistry, Polymer science, Chemical engineering, Organic chemistry, Polymer, Engineering, Telecommunications, Materials science, Computer scienceTop concepts (fields/topics) attached by OpenAlex
- Cited by
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8Total citation count in OpenAlex
- Citations by year (recent)
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2025: 8Per-year citation counts (last 5 years)
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49Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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