Polymer Physics behind the Gel‐Spinning of UHMWPE Fibers Article Swipe
Zefan Wang
,
Leire Sangroniz
,
Jian Xu
,
Caizhen Zhu
,
Alejandro J. Müller
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/marc.202400124
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/marc.202400124
Gel‐spinning of ultra‐high molecular weight polyethylene (UHMWPE) fibers has attracted great interest in academia and industry since its birth and commercialization in the 1980s, due to unique properties such as high modulus, low density, and excellent chemical resistance. However, the high viscosity and long relaxation time greatly complicate processing. In industry, solvents, like decalin and paraffin oil, usually disentangle the physical networks and promote final drawability. From extruding the polymer solution to post‐solid‐stretching, many polymer physics problems that accompany high‐modulus fiber gel‐spinning should be understood and addressed. In this review, by detailed discussions about the effect of entanglements and intracrystalline chain dynamics on the mechanical properties of UHMWPE, theoretical descriptions of the structure formation of disentangled UHMWPE crystals, and the origin of high modulus and strength of final fibers are provided. Several physical intrinsic key factors are also discussed, revealing why UHMWPE is an ideal material for producing high‐performance fibers.
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Metadata
- Type
- review
- Language
- en
- Landing Page
- https://doi.org/10.1002/marc.202400124
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/marc.202400124
- OA Status
- hybrid
- Cited By
- 21
- References
- 70
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4394718391
All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W4394718391Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/marc.202400124Digital Object Identifier
- Title
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Polymer Physics behind the Gel‐Spinning of UHMWPE FibersWork title
- Type
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reviewOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-04-11Full publication date if available
- Authors
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Zefan Wang, Leire Sangroniz, Jian Xu, Caizhen Zhu, Alejandro J. MüllerList of authors in order
- Landing page
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https://doi.org/10.1002/marc.202400124Publisher landing page
- PDF URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/marc.202400124Direct link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/marc.202400124Direct OA link when available
- Concepts
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Spinning, Polymer science, Polymer, Materials science, Synthetic fiber, Composite material, Polymer physics, Polymer chemistry, FiberTop concepts (fields/topics) attached by OpenAlex
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21Total citation count in OpenAlex
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2025: 13, 2024: 8Per-year citation counts (last 5 years)
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70Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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