Predicting the detectability of sulphur-bearing molecules in the solid phase with simulated spectra of JWST instruments Article Swipe
A. Taillard
,
R. Martín-Doménech
,
H. Carrascosa
,
Jennifer A. Noble
,
G. M. Muñoz
,
E. Dartois
,
D. Navarro-Almaida
,
Bruno Escribano
,
A. Sanchez-Monge
,
A. Fuente
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1051/0004-6361/202452900
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1051/0004-6361/202452900
To date, gas phase observations of sulphur in dense interstellar environments have only constrained the molecular carriers of ~1% of its predicted cosmic abundance. An additional ~5% is known to be locked up in molecular solids in dense clouds, leaving the main reservoir of depleted sulphur in the solid phase yet to be identified. Overall, OCS is the only S-bearing molecule unambiguously detected in interstellar ices thus far with infrared telescopes, although an absorption feature of SO 2 has been plausibly identified at 7.5 µm. The spectral resolution and sensitivity of the James Webb Space Telescope (JWST) could make a substantial difference in detecting part of this missing sulphur. The wavelength coverage of the JWST includes vibrational absorption features of the S-carriers H 2 S, OCS, SO 2 , CS 2 , SO, CS, and S 8 are found. The aim of this study is to determine whether these molecules may be viable candidates for detection. We carried out new laboratory measurements of the IR absorption spectra of CS 2 and S 8 to update the IR band strength of the most intense CS 2 absorption feature at 6.8 µm, as well as to determine that of S 8 at 20.3 µm for the first time. These data, along with values previously reported in the literature for H 2 S, OCS, and SO 2 , allow us to evaluate which S-bearing species could be potentially detected with JWST in interstellar ices. Taking the literature abundances of the major ice species determined by previous IR observations towards starless cores, low-mass young stellar objects (LYSOs) and massive young stellar objects (MYSOs), we generated simulated IR spectra using the characteristics of the instruments on the JWST. Thus, we have been able to establish a case study for three stages of the star formation process. These spectra were simulated using a tool that produces synthetic ice spectra, with the aim of studying the feasibility of detecting S-bearing species with the JWST by artificially adding S-bearing molecules to the simulated spectra. We conclude that the detection of S-bearing molecules remains challenging due to a variety of parameters; principally, the overlap of absorption features with those of other species and the mixing of molecular species in the ice impacting the profile and central position of the targeted bands. Despite these obstacles, the detection of H 2 S in dense clouds – and potentially SO 2 in LYSOs and MYSOs – should be possible in regions with favourable physical and chemical conditions, but not necessarily in the same region. In contrast, the large allotrope S 8 would remain undetected even in the unrealistic case that all the available sulphur atoms were involved in its formation. Although the sensitivity of JWST is insufficient to determine the sulphur budget in the solid state, the detection of (or setting of significant upper limits on the abundance of) an additional icy sulphur compound (H 2 S, SO 2 ) would enable us to validate a state-of-the-art approach in our knowledge of sulphur chemistry, offering a unique opportunity to make comparisons against future developments.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1051/0004-6361/202452900
- OA Status
- hybrid
- Cited By
- 6
- References
- 100
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4406970469
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4406970469Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1051/0004-6361/202452900Digital Object Identifier
- Title
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Predicting the detectability of sulphur-bearing molecules in the solid phase with simulated spectra of JWST instrumentsWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-01-30Full publication date if available
- Authors
-
A. Taillard, R. Martín-Doménech, H. Carrascosa, Jennifer A. Noble, G. M. Muñoz, E. Dartois, D. Navarro-Almaida, Bruno Escribano, A. Sanchez-Monge, A. FuenteList of authors in order
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https://doi.org/10.1051/0004-6361/202452900Publisher landing page
- Open access
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
- OA URL
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https://doi.org/10.1051/0004-6361/202452900Direct OA link when available
- Concepts
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Physics, Astrophysics, Spectral line, Sulfur, Phase (matter), Bearing (navigation), Molecule, James Webb Space Telescope, Astronomy, Galaxy, Chemistry, Quantum mechanics, Organic chemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
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6Total citation count in OpenAlex
- Citations by year (recent)
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2025: 6Per-year citation counts (last 5 years)
- References (count)
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100Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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