Preparation of Pd-Loaded Hierarchical FAU Membranes and Testing in Acetophenone Hydrogenation Article Swipe
Raffaele Molinari
,
Cristina Lavorato
,
Teresa F. Mastropietro
,
Pietro Argurio
,
Enrico Drioli
,
Teresa Poerio
·
YOU?
·
· 2016
· Open Access
·
· DOI: https://doi.org/10.3390/molecules21030394
YOU?
·
· 2016
· Open Access
·
· DOI: https://doi.org/10.3390/molecules21030394
Pd-loaded hierarchical FAU (Pd-FAU) membranes, containing an intrinsic secondary non-zeolitic (meso)porosity, were prepared and tested in the catalytic transfer hydrogenation of acetophenone (AP) to produce phenylethanol (PE), an industrially relevant product. The best operating conditions were preliminarily identified by testing different solvents and organic hydrogen donors in a batch hydrogenation process where micron-sized FAU seeds were employed as catalyst support. Water as solvent and formic acid as hydrogen source resulted to be the best choice in terms of conversion for the catalytic hydrogenation of AP, providing the basis for the design of a green and sustainable process. The best experimental conditions were selected and applied to the Pd-loaded FAU membrane finding enhanced catalytic performance such as a five-fold higher productivity than with the unsupported Pd-FAU crystals (11.0 vs. 2.2 mgproduct gcat−1·h−1). The catalytic performance of the membrane on the alumina support was also tested in a tangential flow system obtaining a productivity higher than that of the batch system (22.0 vs. 11.0 mgproduct gcat−1·h−1).
Related Topics
Concepts
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.3390/molecules21030394
- https://www.mdpi.com/1420-3049/21/3/394/pdf?version=1458639878
- OA Status
- gold
- Cited By
- 16
- References
- 60
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2309031863
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W2309031863Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.3390/molecules21030394Digital Object Identifier
- Title
-
Preparation of Pd-Loaded Hierarchical FAU Membranes and Testing in Acetophenone HydrogenationWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2016Year of publication
- Publication date
-
2016-03-22Full publication date if available
- Authors
-
Raffaele Molinari, Cristina Lavorato, Teresa F. Mastropietro, Pietro Argurio, Enrico Drioli, Teresa PoerioList of authors in order
- Landing page
-
https://doi.org/10.3390/molecules21030394Publisher landing page
- PDF URL
-
https://www.mdpi.com/1420-3049/21/3/394/pdf?version=1458639878Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://www.mdpi.com/1420-3049/21/3/394/pdf?version=1458639878Direct OA link when available
- Concepts
-
Acetophenone, Catalysis, Formic acid, Membrane, Chemical engineering, Solvent, Chemistry, Palladium, Hydrogen, Materials science, Porosity, Organic chemistry, Engineering, BiochemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
16Total citation count in OpenAlex
- Citations by year (recent)
-
2024: 1, 2023: 1, 2022: 1, 2021: 2, 2020: 3Per-year citation counts (last 5 years)
- References (count)
-
60Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
Full payload
| id | https://openalex.org/W2309031863 |
|---|---|
| doi | https://doi.org/10.3390/molecules21030394 |
| ids.doi | https://doi.org/10.3390/molecules21030394 |
| ids.mag | 2309031863 |
| ids.pmid | https://pubmed.ncbi.nlm.nih.gov/27011163 |
| ids.openalex | https://openalex.org/W2309031863 |
| fwci | 1.83145247 |
| mesh[0].qualifier_ui | Q000737 |
| mesh[0].descriptor_ui | D000098 |
| mesh[0].is_major_topic | False |
| mesh[0].qualifier_name | chemistry |
| mesh[0].descriptor_name | Acetophenones |
| mesh[1].qualifier_ui | |
| mesh[1].descriptor_ui | D002384 |
| mesh[1].is_major_topic | True |
| mesh[1].qualifier_name | |
| mesh[1].descriptor_name | Catalysis |
| mesh[2].qualifier_ui | |
| mesh[2].descriptor_ui | D006865 |
| mesh[2].is_major_topic | False |
| mesh[2].qualifier_name | |
| mesh[2].descriptor_name | Hydrogenation |
| mesh[3].qualifier_ui | Q000737 |
| mesh[3].descriptor_ui | D007659 |
| mesh[3].is_major_topic | False |
| mesh[3].qualifier_name | chemistry |
| mesh[3].descriptor_name | Ketones |
| mesh[4].qualifier_ui | Q000737 |
| mesh[4].descriptor_ui | D008566 |
| mesh[4].is_major_topic | False |
| mesh[4].qualifier_name | chemistry |
| mesh[4].descriptor_name | Membranes |
| mesh[5].qualifier_ui | |
| mesh[5].descriptor_ui | D016062 |
| mesh[5].is_major_topic | False |
| mesh[5].qualifier_name | |
| mesh[5].descriptor_name | Porosity |
| mesh[6].qualifier_ui | |
| mesh[6].descriptor_ui | D017641 |
| mesh[6].is_major_topic | False |
| mesh[6].qualifier_name | |
| mesh[6].descriptor_name | Zeolites |
| mesh[7].qualifier_ui | Q000737 |
| mesh[7].descriptor_ui | D000098 |
| mesh[7].is_major_topic | False |
| mesh[7].qualifier_name | chemistry |
| mesh[7].descriptor_name | Acetophenones |
| mesh[8].qualifier_ui | |
| mesh[8].descriptor_ui | D002384 |
| mesh[8].is_major_topic | True |
| mesh[8].qualifier_name | |
| mesh[8].descriptor_name | Catalysis |
| mesh[9].qualifier_ui | |
| mesh[9].descriptor_ui | D006865 |
| mesh[9].is_major_topic | False |
| mesh[9].qualifier_name | |
| mesh[9].descriptor_name | Hydrogenation |
| mesh[10].qualifier_ui | Q000737 |
| mesh[10].descriptor_ui | D007659 |
| mesh[10].is_major_topic | False |
| mesh[10].qualifier_name | chemistry |
| mesh[10].descriptor_name | Ketones |
| mesh[11].qualifier_ui | Q000737 |
| mesh[11].descriptor_ui | D008566 |
| mesh[11].is_major_topic | False |
| mesh[11].qualifier_name | chemistry |
| mesh[11].descriptor_name | Membranes |
| mesh[12].qualifier_ui | |
| mesh[12].descriptor_ui | D016062 |
| mesh[12].is_major_topic | False |
| mesh[12].qualifier_name | |
| mesh[12].descriptor_name | Porosity |
| mesh[13].qualifier_ui | |
| mesh[13].descriptor_ui | D017641 |
| mesh[13].is_major_topic | False |
| mesh[13].qualifier_name | |
| mesh[13].descriptor_name | Zeolites |
| type | article |
| title | Preparation of Pd-Loaded Hierarchical FAU Membranes and Testing in Acetophenone Hydrogenation |
| biblio.issue | 3 |
| biblio.volume | 21 |
| biblio.last_page | 394 |
| biblio.first_page | 394 |
| topics[0].id | https://openalex.org/T11281 |
| topics[0].field.id | https://openalex.org/fields/16 |
| topics[0].field.display_name | Chemistry |
| topics[0].score | 0.9998999834060669 |
| topics[0].domain.id | https://openalex.org/domains/3 |
| topics[0].domain.display_name | Physical Sciences |
| topics[0].subfield.id | https://openalex.org/subfields/1604 |
| topics[0].subfield.display_name | Inorganic Chemistry |
| topics[0].display_name | Asymmetric Hydrogenation and Catalysis |
| topics[1].id | https://openalex.org/T12240 |
| topics[1].field.id | https://openalex.org/fields/16 |
| topics[1].field.display_name | Chemistry |
| topics[1].score | 0.9997000098228455 |
| topics[1].domain.id | https://openalex.org/domains/3 |
| topics[1].domain.display_name | Physical Sciences |
| topics[1].subfield.id | https://openalex.org/subfields/1605 |
| topics[1].subfield.display_name | Organic Chemistry |
| topics[1].display_name | Nanomaterials for catalytic reactions |
| topics[2].id | https://openalex.org/T11009 |
| topics[2].field.id | https://openalex.org/fields/22 |
| topics[2].field.display_name | Engineering |
| topics[2].score | 0.9995999932289124 |
| topics[2].domain.id | https://openalex.org/domains/3 |
| topics[2].domain.display_name | Physical Sciences |
| topics[2].subfield.id | https://openalex.org/subfields/2204 |
| topics[2].subfield.display_name | Biomedical Engineering |
| topics[2].display_name | Catalysis for Biomass Conversion |
| is_xpac | False |
| apc_list.value | 2300 |
| apc_list.currency | CHF |
| apc_list.value_usd | 2490 |
| apc_paid.value | 2300 |
| apc_paid.currency | CHF |
| apc_paid.value_usd | 2490 |
| concepts[0].id | https://openalex.org/C2775888733 |
| concepts[0].level | 3 |
| concepts[0].score | 0.8513497710227966 |
| concepts[0].wikidata | https://www.wikidata.org/wiki/Q375112 |
| concepts[0].display_name | Acetophenone |
| concepts[1].id | https://openalex.org/C161790260 |
| concepts[1].level | 2 |
| concepts[1].score | 0.8356771469116211 |
| concepts[1].wikidata | https://www.wikidata.org/wiki/Q82264 |
| concepts[1].display_name | Catalysis |
| concepts[2].id | https://openalex.org/C2777379063 |
| concepts[2].level | 2 |
| concepts[2].score | 0.6758333444595337 |
| concepts[2].wikidata | https://www.wikidata.org/wiki/Q161233 |
| concepts[2].display_name | Formic acid |
| concepts[3].id | https://openalex.org/C41625074 |
| concepts[3].level | 2 |
| concepts[3].score | 0.6430951356887817 |
| concepts[3].wikidata | https://www.wikidata.org/wiki/Q176088 |
| concepts[3].display_name | Membrane |
| concepts[4].id | https://openalex.org/C42360764 |
| concepts[4].level | 1 |
| concepts[4].score | 0.5373654961585999 |
| concepts[4].wikidata | https://www.wikidata.org/wiki/Q83588 |
| concepts[4].display_name | Chemical engineering |
| concepts[5].id | https://openalex.org/C2780471494 |
| concepts[5].level | 2 |
| concepts[5].score | 0.49750450253486633 |
| concepts[5].wikidata | https://www.wikidata.org/wiki/Q146505 |
| concepts[5].display_name | Solvent |
| concepts[6].id | https://openalex.org/C185592680 |
| concepts[6].level | 0 |
| concepts[6].score | 0.4911443889141083 |
| concepts[6].wikidata | https://www.wikidata.org/wiki/Q2329 |
| concepts[6].display_name | Chemistry |
| concepts[7].id | https://openalex.org/C502130503 |
| concepts[7].level | 3 |
| concepts[7].score | 0.4593491852283478 |
| concepts[7].wikidata | https://www.wikidata.org/wiki/Q1089 |
| concepts[7].display_name | Palladium |
| concepts[8].id | https://openalex.org/C512968161 |
| concepts[8].level | 2 |
| concepts[8].score | 0.449907124042511 |
| concepts[8].wikidata | https://www.wikidata.org/wiki/Q556 |
| concepts[8].display_name | Hydrogen |
| concepts[9].id | https://openalex.org/C192562407 |
| concepts[9].level | 0 |
| concepts[9].score | 0.42885512113571167 |
| concepts[9].wikidata | https://www.wikidata.org/wiki/Q228736 |
| concepts[9].display_name | Materials science |
| concepts[10].id | https://openalex.org/C6648577 |
| concepts[10].level | 2 |
| concepts[10].score | 0.41085970401763916 |
| concepts[10].wikidata | https://www.wikidata.org/wiki/Q622669 |
| concepts[10].display_name | Porosity |
| concepts[11].id | https://openalex.org/C178790620 |
| concepts[11].level | 1 |
| concepts[11].score | 0.39010798931121826 |
| concepts[11].wikidata | https://www.wikidata.org/wiki/Q11351 |
| concepts[11].display_name | Organic chemistry |
| concepts[12].id | https://openalex.org/C127413603 |
| concepts[12].level | 0 |
| concepts[12].score | 0.0 |
| concepts[12].wikidata | https://www.wikidata.org/wiki/Q11023 |
| concepts[12].display_name | Engineering |
| concepts[13].id | https://openalex.org/C55493867 |
| concepts[13].level | 1 |
| concepts[13].score | 0.0 |
| concepts[13].wikidata | https://www.wikidata.org/wiki/Q7094 |
| concepts[13].display_name | Biochemistry |
| keywords[0].id | https://openalex.org/keywords/acetophenone |
| keywords[0].score | 0.8513497710227966 |
| keywords[0].display_name | Acetophenone |
| keywords[1].id | https://openalex.org/keywords/catalysis |
| keywords[1].score | 0.8356771469116211 |
| keywords[1].display_name | Catalysis |
| keywords[2].id | https://openalex.org/keywords/formic-acid |
| keywords[2].score | 0.6758333444595337 |
| keywords[2].display_name | Formic acid |
| keywords[3].id | https://openalex.org/keywords/membrane |
| keywords[3].score | 0.6430951356887817 |
| keywords[3].display_name | Membrane |
| keywords[4].id | https://openalex.org/keywords/chemical-engineering |
| keywords[4].score | 0.5373654961585999 |
| keywords[4].display_name | Chemical engineering |
| keywords[5].id | https://openalex.org/keywords/solvent |
| keywords[5].score | 0.49750450253486633 |
| keywords[5].display_name | Solvent |
| keywords[6].id | https://openalex.org/keywords/chemistry |
| keywords[6].score | 0.4911443889141083 |
| keywords[6].display_name | Chemistry |
| keywords[7].id | https://openalex.org/keywords/palladium |
| keywords[7].score | 0.4593491852283478 |
| keywords[7].display_name | Palladium |
| keywords[8].id | https://openalex.org/keywords/hydrogen |
| keywords[8].score | 0.449907124042511 |
| keywords[8].display_name | Hydrogen |
| keywords[9].id | https://openalex.org/keywords/materials-science |
| keywords[9].score | 0.42885512113571167 |
| keywords[9].display_name | Materials science |
| keywords[10].id | https://openalex.org/keywords/porosity |
| keywords[10].score | 0.41085970401763916 |
| keywords[10].display_name | Porosity |
| keywords[11].id | https://openalex.org/keywords/organic-chemistry |
| keywords[11].score | 0.39010798931121826 |
| keywords[11].display_name | Organic chemistry |
| language | en |
| locations[0].id | doi:10.3390/molecules21030394 |
| locations[0].is_oa | True |
| locations[0].source.id | https://openalex.org/S108911230 |
| locations[0].source.issn | 1420-3049, 1433-1373 |
| locations[0].source.type | journal |
| locations[0].source.is_oa | True |
| locations[0].source.issn_l | 1420-3049 |
| locations[0].source.is_core | True |
| locations[0].source.is_in_doaj | True |
| locations[0].source.display_name | Molecules |
| locations[0].source.host_organization | https://openalex.org/P4310310987 |
| locations[0].source.host_organization_name | Multidisciplinary Digital Publishing Institute |
| locations[0].source.host_organization_lineage | https://openalex.org/P4310310987 |
| locations[0].license | cc-by |
| locations[0].pdf_url | https://www.mdpi.com/1420-3049/21/3/394/pdf?version=1458639878 |
| locations[0].version | publishedVersion |
| locations[0].raw_type | journal-article |
| locations[0].license_id | https://openalex.org/licenses/cc-by |
| locations[0].is_accepted | True |
| locations[0].is_published | True |
| locations[0].raw_source_name | Molecules |
| locations[0].landing_page_url | https://doi.org/10.3390/molecules21030394 |
| locations[1].id | pmid:27011163 |
| locations[1].is_oa | False |
| locations[1].source.id | https://openalex.org/S4306525036 |
| locations[1].source.issn | |
| locations[1].source.type | repository |
| locations[1].source.is_oa | False |
| locations[1].source.issn_l | |
| locations[1].source.is_core | False |
| locations[1].source.is_in_doaj | False |
| locations[1].source.display_name | PubMed |
| locations[1].source.host_organization | https://openalex.org/I1299303238 |
| locations[1].source.host_organization_name | National Institutes of Health |
| locations[1].source.host_organization_lineage | https://openalex.org/I1299303238 |
| locations[1].license | |
| locations[1].pdf_url | |
| locations[1].version | publishedVersion |
| locations[1].raw_type | |
| locations[1].license_id | |
| locations[1].is_accepted | True |
| locations[1].is_published | True |
| locations[1].raw_source_name | Molecules (Basel, Switzerland) |
| locations[1].landing_page_url | https://pubmed.ncbi.nlm.nih.gov/27011163 |
| locations[2].id | pmh:oai:doaj.org/article:38511af4937340f2a71808c7fe0ae7d8 |
| locations[2].is_oa | True |
| locations[2].source.id | https://openalex.org/S4306401280 |
| locations[2].source.issn | |
| locations[2].source.type | repository |
| locations[2].source.is_oa | False |
| locations[2].source.issn_l | |
| locations[2].source.is_core | False |
| locations[2].source.is_in_doaj | False |
| locations[2].source.display_name | DOAJ (DOAJ: Directory of Open Access Journals) |
| locations[2].source.host_organization | |
| locations[2].source.host_organization_name | |
| locations[2].source.host_organization_lineage | |
| locations[2].license | cc-by-sa |
| locations[2].pdf_url | |
| locations[2].version | submittedVersion |
| locations[2].raw_type | article |
| locations[2].license_id | https://openalex.org/licenses/cc-by-sa |
| locations[2].is_accepted | False |
| locations[2].is_published | False |
| locations[2].raw_source_name | Molecules, Vol 21, Iss 3, p 394 (2016) |
| locations[2].landing_page_url | https://doaj.org/article/38511af4937340f2a71808c7fe0ae7d8 |
| locations[3].id | pmh:oai:mdpi.com:/1420-3049/21/3/394/ |
| locations[3].is_oa | True |
| locations[3].source.id | https://openalex.org/S4306400947 |
| locations[3].source.issn | |
| locations[3].source.type | repository |
| locations[3].source.is_oa | True |
| locations[3].source.issn_l | |
| locations[3].source.is_core | False |
| locations[3].source.is_in_doaj | False |
| locations[3].source.display_name | MDPI (MDPI AG) |
| locations[3].source.host_organization | https://openalex.org/I4210097602 |
| locations[3].source.host_organization_name | Multidisciplinary Digital Publishing Institute (Switzerland) |
| locations[3].source.host_organization_lineage | https://openalex.org/I4210097602 |
| locations[3].license | cc-by |
| locations[3].pdf_url | |
| locations[3].version | submittedVersion |
| locations[3].raw_type | Text |
| locations[3].license_id | https://openalex.org/licenses/cc-by |
| locations[3].is_accepted | False |
| locations[3].is_published | False |
| locations[3].raw_source_name | Molecules; Volume 21; Issue 3; Pages: 394 |
| locations[3].landing_page_url | https://dx.doi.org/10.3390/molecules21030394 |
| locations[4].id | pmh:oai:europepmc.org:5278270 |
| locations[4].is_oa | True |
| locations[4].source.id | https://openalex.org/S4306400806 |
| locations[4].source.issn | |
| locations[4].source.type | repository |
| locations[4].source.is_oa | False |
| locations[4].source.issn_l | |
| locations[4].source.is_core | False |
| locations[4].source.is_in_doaj | False |
| locations[4].source.display_name | Europe PMC (PubMed Central) |
| locations[4].source.host_organization | https://openalex.org/I1303153112 |
| locations[4].source.host_organization_name | European Bioinformatics Institute |
| locations[4].source.host_organization_lineage | https://openalex.org/I1303153112 |
| locations[4].license | other-oa |
| locations[4].pdf_url | |
| locations[4].version | submittedVersion |
| locations[4].raw_type | Text |
| locations[4].license_id | https://openalex.org/licenses/other-oa |
| locations[4].is_accepted | False |
| locations[4].is_published | False |
| locations[4].raw_source_name | |
| locations[4].landing_page_url | https://www.ncbi.nlm.nih.gov/pmc/articles/6273915 |
| indexed_in | crossref, doaj, pubmed |
| authorships[0].author.id | https://openalex.org/A5039897041 |
| authorships[0].author.orcid | https://orcid.org/0000-0001-9627-0969 |
| authorships[0].author.display_name | Raffaele Molinari |
| authorships[0].countries | IT |
| authorships[0].affiliations[0].institution_ids | https://openalex.org/I45204951 |
| authorships[0].affiliations[0].raw_affiliation_string | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[0].institutions[0].id | https://openalex.org/I45204951 |
| authorships[0].institutions[0].ror | https://ror.org/02rc97e94 |
| authorships[0].institutions[0].type | education |
| authorships[0].institutions[0].lineage | https://openalex.org/I45204951 |
| authorships[0].institutions[0].country_code | IT |
| authorships[0].institutions[0].display_name | University of Calabria |
| authorships[0].author_position | first |
| authorships[0].raw_author_name | Raffaele Molinari |
| authorships[0].is_corresponding | True |
| authorships[0].raw_affiliation_strings | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[1].author.id | https://openalex.org/A5057118010 |
| authorships[1].author.orcid | https://orcid.org/0000-0002-8590-9250 |
| authorships[1].author.display_name | Cristina Lavorato |
| authorships[1].countries | IT |
| authorships[1].affiliations[0].institution_ids | https://openalex.org/I45204951 |
| authorships[1].affiliations[0].raw_affiliation_string | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[1].institutions[0].id | https://openalex.org/I45204951 |
| authorships[1].institutions[0].ror | https://ror.org/02rc97e94 |
| authorships[1].institutions[0].type | education |
| authorships[1].institutions[0].lineage | https://openalex.org/I45204951 |
| authorships[1].institutions[0].country_code | IT |
| authorships[1].institutions[0].display_name | University of Calabria |
| authorships[1].author_position | middle |
| authorships[1].raw_author_name | Cristina Lavorato |
| authorships[1].is_corresponding | False |
| authorships[1].raw_affiliation_strings | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[2].author.id | https://openalex.org/A5090398342 |
| authorships[2].author.orcid | https://orcid.org/0000-0003-1851-9591 |
| authorships[2].author.display_name | Teresa F. Mastropietro |
| authorships[2].countries | IT |
| authorships[2].affiliations[0].institution_ids | https://openalex.org/I45204951 |
| authorships[2].affiliations[0].raw_affiliation_string | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[2].institutions[0].id | https://openalex.org/I45204951 |
| authorships[2].institutions[0].ror | https://ror.org/02rc97e94 |
| authorships[2].institutions[0].type | education |
| authorships[2].institutions[0].lineage | https://openalex.org/I45204951 |
| authorships[2].institutions[0].country_code | IT |
| authorships[2].institutions[0].display_name | University of Calabria |
| authorships[2].author_position | middle |
| authorships[2].raw_author_name | Teresa Mastropietro |
| authorships[2].is_corresponding | False |
| authorships[2].raw_affiliation_strings | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[3].author.id | https://openalex.org/A5023888266 |
| authorships[3].author.orcid | https://orcid.org/0000-0002-5656-4986 |
| authorships[3].author.display_name | Pietro Argurio |
| authorships[3].countries | IT |
| authorships[3].affiliations[0].institution_ids | https://openalex.org/I45204951 |
| authorships[3].affiliations[0].raw_affiliation_string | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[3].institutions[0].id | https://openalex.org/I45204951 |
| authorships[3].institutions[0].ror | https://ror.org/02rc97e94 |
| authorships[3].institutions[0].type | education |
| authorships[3].institutions[0].lineage | https://openalex.org/I45204951 |
| authorships[3].institutions[0].country_code | IT |
| authorships[3].institutions[0].display_name | University of Calabria |
| authorships[3].author_position | middle |
| authorships[3].raw_author_name | Pietro Argurio |
| authorships[3].is_corresponding | False |
| authorships[3].raw_affiliation_strings | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[4].author.id | https://openalex.org/A5028704968 |
| authorships[4].author.orcid | https://orcid.org/0000-0003-1092-5368 |
| authorships[4].author.display_name | Enrico Drioli |
| authorships[4].countries | IT |
| authorships[4].affiliations[0].institution_ids | https://openalex.org/I4210155236, https://openalex.org/I4210164317, https://openalex.org/I45204951 |
| authorships[4].affiliations[0].raw_affiliation_string | National Research Council—Institute for Membrane Technology (ITM–CNR) c/o University of Calabria, cubo 17C, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[4].affiliations[1].institution_ids | https://openalex.org/I45204951 |
| authorships[4].affiliations[1].raw_affiliation_string | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[4].institutions[0].id | https://openalex.org/I4210164317 |
| authorships[4].institutions[0].ror | https://ror.org/058nrs650 |
| authorships[4].institutions[0].type | facility |
| authorships[4].institutions[0].lineage | https://openalex.org/I4210155236, https://openalex.org/I4210164317 |
| authorships[4].institutions[0].country_code | IT |
| authorships[4].institutions[0].display_name | Institute on Membrane Technology |
| authorships[4].institutions[1].id | https://openalex.org/I4210155236 |
| authorships[4].institutions[1].ror | https://ror.org/04zaypm56 |
| authorships[4].institutions[1].type | nonprofit |
| authorships[4].institutions[1].lineage | https://openalex.org/I4210155236 |
| authorships[4].institutions[1].country_code | IT |
| authorships[4].institutions[1].display_name | National Research Council |
| authorships[4].institutions[2].id | https://openalex.org/I45204951 |
| authorships[4].institutions[2].ror | https://ror.org/02rc97e94 |
| authorships[4].institutions[2].type | education |
| authorships[4].institutions[2].lineage | https://openalex.org/I45204951 |
| authorships[4].institutions[2].country_code | IT |
| authorships[4].institutions[2].display_name | University of Calabria |
| authorships[4].author_position | middle |
| authorships[4].raw_author_name | Enrico Drioli |
| authorships[4].is_corresponding | False |
| authorships[4].raw_affiliation_strings | Department of Environmental and Chemical Engineering, University of Calabria, cubo 44A, Via Pietro BUCCI, 87036 Rende (CS), Italy, National Research Council—Institute for Membrane Technology (ITM–CNR) c/o University of Calabria, cubo 17C, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[5].author.id | https://openalex.org/A5064373917 |
| authorships[5].author.orcid | https://orcid.org/0000-0001-8449-9344 |
| authorships[5].author.display_name | Teresa Poerio |
| authorships[5].countries | IT |
| authorships[5].affiliations[0].institution_ids | https://openalex.org/I4210155236, https://openalex.org/I4210164317, https://openalex.org/I45204951 |
| authorships[5].affiliations[0].raw_affiliation_string | National Research Council—Institute for Membrane Technology (ITM–CNR) c/o University of Calabria, cubo 17C, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| authorships[5].institutions[0].id | https://openalex.org/I4210164317 |
| authorships[5].institutions[0].ror | https://ror.org/058nrs650 |
| authorships[5].institutions[0].type | facility |
| authorships[5].institutions[0].lineage | https://openalex.org/I4210155236, https://openalex.org/I4210164317 |
| authorships[5].institutions[0].country_code | IT |
| authorships[5].institutions[0].display_name | Institute on Membrane Technology |
| authorships[5].institutions[1].id | https://openalex.org/I4210155236 |
| authorships[5].institutions[1].ror | https://ror.org/04zaypm56 |
| authorships[5].institutions[1].type | nonprofit |
| authorships[5].institutions[1].lineage | https://openalex.org/I4210155236 |
| authorships[5].institutions[1].country_code | IT |
| authorships[5].institutions[1].display_name | National Research Council |
| authorships[5].institutions[2].id | https://openalex.org/I45204951 |
| authorships[5].institutions[2].ror | https://ror.org/02rc97e94 |
| authorships[5].institutions[2].type | education |
| authorships[5].institutions[2].lineage | https://openalex.org/I45204951 |
| authorships[5].institutions[2].country_code | IT |
| authorships[5].institutions[2].display_name | University of Calabria |
| authorships[5].author_position | last |
| authorships[5].raw_author_name | Teresa Poerio |
| authorships[5].is_corresponding | False |
| authorships[5].raw_affiliation_strings | National Research Council—Institute for Membrane Technology (ITM–CNR) c/o University of Calabria, cubo 17C, Via Pietro BUCCI, 87036 Rende (CS), Italy |
| has_content.pdf | True |
| has_content.grobid_xml | True |
| is_paratext | False |
| open_access.is_oa | True |
| open_access.oa_url | https://www.mdpi.com/1420-3049/21/3/394/pdf?version=1458639878 |
| open_access.oa_status | gold |
| open_access.any_repository_has_fulltext | False |
| created_date | 2025-10-10T00:00:00 |
| display_name | Preparation of Pd-Loaded Hierarchical FAU Membranes and Testing in Acetophenone Hydrogenation |
| has_fulltext | True |
| is_retracted | False |
| updated_date | 2025-11-06T03:46:38.306776 |
| primary_topic.id | https://openalex.org/T11281 |
| primary_topic.field.id | https://openalex.org/fields/16 |
| primary_topic.field.display_name | Chemistry |
| primary_topic.score | 0.9998999834060669 |
| primary_topic.domain.id | https://openalex.org/domains/3 |
| primary_topic.domain.display_name | Physical Sciences |
| primary_topic.subfield.id | https://openalex.org/subfields/1604 |
| primary_topic.subfield.display_name | Inorganic Chemistry |
| primary_topic.display_name | Asymmetric Hydrogenation and Catalysis |
| related_works | https://openalex.org/W2184748586, https://openalex.org/W1967233295, https://openalex.org/W1967825231, https://openalex.org/W2359142192, https://openalex.org/W2377354253, https://openalex.org/W2373195857, https://openalex.org/W1972118184, https://openalex.org/W2018823693, https://openalex.org/W2094087377, https://openalex.org/W2006070393 |
| cited_by_count | 16 |
| counts_by_year[0].year | 2024 |
| counts_by_year[0].cited_by_count | 1 |
| counts_by_year[1].year | 2023 |
| counts_by_year[1].cited_by_count | 1 |
| counts_by_year[2].year | 2022 |
| counts_by_year[2].cited_by_count | 1 |
| counts_by_year[3].year | 2021 |
| counts_by_year[3].cited_by_count | 2 |
| counts_by_year[4].year | 2020 |
| counts_by_year[4].cited_by_count | 3 |
| counts_by_year[5].year | 2019 |
| counts_by_year[5].cited_by_count | 1 |
| counts_by_year[6].year | 2018 |
| counts_by_year[6].cited_by_count | 3 |
| counts_by_year[7].year | 2017 |
| counts_by_year[7].cited_by_count | 2 |
| counts_by_year[8].year | 2016 |
| counts_by_year[8].cited_by_count | 2 |
| locations_count | 5 |
| best_oa_location.id | doi:10.3390/molecules21030394 |
| best_oa_location.is_oa | True |
| best_oa_location.source.id | https://openalex.org/S108911230 |
| best_oa_location.source.issn | 1420-3049, 1433-1373 |
| best_oa_location.source.type | journal |
| best_oa_location.source.is_oa | True |
| best_oa_location.source.issn_l | 1420-3049 |
| best_oa_location.source.is_core | True |
| best_oa_location.source.is_in_doaj | True |
| best_oa_location.source.display_name | Molecules |
| best_oa_location.source.host_organization | https://openalex.org/P4310310987 |
| best_oa_location.source.host_organization_name | Multidisciplinary Digital Publishing Institute |
| best_oa_location.source.host_organization_lineage | https://openalex.org/P4310310987 |
| best_oa_location.license | cc-by |
| best_oa_location.pdf_url | https://www.mdpi.com/1420-3049/21/3/394/pdf?version=1458639878 |
| best_oa_location.version | publishedVersion |
| best_oa_location.raw_type | journal-article |
| best_oa_location.license_id | https://openalex.org/licenses/cc-by |
| best_oa_location.is_accepted | True |
| best_oa_location.is_published | True |
| best_oa_location.raw_source_name | Molecules |
| best_oa_location.landing_page_url | https://doi.org/10.3390/molecules21030394 |
| primary_location.id | doi:10.3390/molecules21030394 |
| primary_location.is_oa | True |
| primary_location.source.id | https://openalex.org/S108911230 |
| primary_location.source.issn | 1420-3049, 1433-1373 |
| primary_location.source.type | journal |
| primary_location.source.is_oa | True |
| primary_location.source.issn_l | 1420-3049 |
| primary_location.source.is_core | True |
| primary_location.source.is_in_doaj | True |
| primary_location.source.display_name | Molecules |
| primary_location.source.host_organization | https://openalex.org/P4310310987 |
| primary_location.source.host_organization_name | Multidisciplinary Digital Publishing Institute |
| primary_location.source.host_organization_lineage | https://openalex.org/P4310310987 |
| primary_location.license | cc-by |
| primary_location.pdf_url | https://www.mdpi.com/1420-3049/21/3/394/pdf?version=1458639878 |
| primary_location.version | publishedVersion |
| primary_location.raw_type | journal-article |
| primary_location.license_id | https://openalex.org/licenses/cc-by |
| primary_location.is_accepted | True |
| primary_location.is_published | True |
| primary_location.raw_source_name | Molecules |
| primary_location.landing_page_url | https://doi.org/10.3390/molecules21030394 |
| publication_date | 2016-03-22 |
| publication_year | 2016 |
| referenced_works | https://openalex.org/W2312657495, https://openalex.org/W1663516079, https://openalex.org/W2092816490, https://openalex.org/W2032294243, https://openalex.org/W2950091125, https://openalex.org/W2024869919, https://openalex.org/W2134487800, https://openalex.org/W2950969828, https://openalex.org/W2110841889, https://openalex.org/W2032643359, https://openalex.org/W2057523140, https://openalex.org/W2045124984, https://openalex.org/W1987128854, https://openalex.org/W2152310475, https://openalex.org/W2025839312, https://openalex.org/W2160983370, https://openalex.org/W2952383610, https://openalex.org/W2011003931, https://openalex.org/W2092014708, https://openalex.org/W236591192, https://openalex.org/W2331743035, https://openalex.org/W2043350157, https://openalex.org/W2335481189, https://openalex.org/W2021802936, https://openalex.org/W1998546439, https://openalex.org/W2119213820, https://openalex.org/W2072370870, https://openalex.org/W2140713685, https://openalex.org/W1963837762, https://openalex.org/W2010830341, https://openalex.org/W2061915461, https://openalex.org/W6686335546, https://openalex.org/W2094449515, https://openalex.org/W4300555443, https://openalex.org/W2110425745, https://openalex.org/W2070998300, https://openalex.org/W2067128093, https://openalex.org/W2010180210, https://openalex.org/W1964164333, https://openalex.org/W2076408530, https://openalex.org/W2950521031, https://openalex.org/W1992000391, https://openalex.org/W2017599661, https://openalex.org/W2053634461, https://openalex.org/W1989216753, https://openalex.org/W2022519860, https://openalex.org/W1981275120, https://openalex.org/W1950847074, https://openalex.org/W2078112572, https://openalex.org/W2121350205, https://openalex.org/W2051060151, https://openalex.org/W2000818451, https://openalex.org/W359312463, https://openalex.org/W1573290787, https://openalex.org/W417020462, https://openalex.org/W2470385253, https://openalex.org/W2183984171, https://openalex.org/W2952211873, https://openalex.org/W188741706, https://openalex.org/W4245779216 |
| referenced_works_count | 60 |
| abstract_inverted_index.a | 47, 92, 116, 145, 150 |
| abstract_inverted_index.an | 6, 27 |
| abstract_inverted_index.as | 57, 61, 66, 115 |
| abstract_inverted_index.be | 71 |
| abstract_inverted_index.by | 38 |
| abstract_inverted_index.in | 15, 46, 75, 144 |
| abstract_inverted_index.of | 20, 77, 83, 91, 134, 155 |
| abstract_inverted_index.on | 137 |
| abstract_inverted_index.to | 23, 70, 105 |
| abstract_inverted_index.2.2 | 128 |
| abstract_inverted_index.AP, | 84 |
| abstract_inverted_index.FAU | 2, 53, 108 |
| abstract_inverted_index.The | 31, 97, 131 |
| abstract_inverted_index.and | 13, 42, 63, 94, 103 |
| abstract_inverted_index.for | 79, 88 |
| abstract_inverted_index.the | 16, 72, 80, 86, 89, 106, 122, 135, 138, 156 |
| abstract_inverted_index.vs. | 127, 160 |
| abstract_inverted_index.was | 141 |
| abstract_inverted_index.(AP) | 22 |
| abstract_inverted_index.11.0 | 161 |
| abstract_inverted_index.acid | 65 |
| abstract_inverted_index.also | 142 |
| abstract_inverted_index.best | 32, 73, 98 |
| abstract_inverted_index.flow | 147 |
| abstract_inverted_index.such | 114 |
| abstract_inverted_index.than | 120, 153 |
| abstract_inverted_index.that | 154 |
| abstract_inverted_index.were | 11, 35, 55, 101 |
| abstract_inverted_index.with | 121 |
| abstract_inverted_index.(11.0 | 126 |
| abstract_inverted_index.(22.0 | 159 |
| abstract_inverted_index.(PE), | 26 |
| abstract_inverted_index.Water | 60 |
| abstract_inverted_index.basis | 87 |
| abstract_inverted_index.batch | 48, 157 |
| abstract_inverted_index.green | 93 |
| abstract_inverted_index.seeds | 54 |
| abstract_inverted_index.terms | 76 |
| abstract_inverted_index.where | 51 |
| abstract_inverted_index.Pd-FAU | 124 |
| abstract_inverted_index.choice | 74 |
| abstract_inverted_index.design | 90 |
| abstract_inverted_index.donors | 45 |
| abstract_inverted_index.formic | 64 |
| abstract_inverted_index.higher | 118, 152 |
| abstract_inverted_index.source | 68 |
| abstract_inverted_index.system | 148, 158 |
| abstract_inverted_index.tested | 14, 143 |
| abstract_inverted_index.alumina | 139 |
| abstract_inverted_index.applied | 104 |
| abstract_inverted_index.finding | 110 |
| abstract_inverted_index.organic | 43 |
| abstract_inverted_index.process | 50 |
| abstract_inverted_index.produce | 24 |
| abstract_inverted_index.solvent | 62 |
| abstract_inverted_index.support | 140 |
| abstract_inverted_index.testing | 39 |
| abstract_inverted_index.(Pd-FAU) | 3 |
| abstract_inverted_index.catalyst | 58 |
| abstract_inverted_index.crystals | 125 |
| abstract_inverted_index.employed | 56 |
| abstract_inverted_index.enhanced | 111 |
| abstract_inverted_index.hydrogen | 44, 67 |
| abstract_inverted_index.membrane | 109, 136 |
| abstract_inverted_index.prepared | 12 |
| abstract_inverted_index.process. | 96 |
| abstract_inverted_index.product. | 30 |
| abstract_inverted_index.relevant | 29 |
| abstract_inverted_index.resulted | 69 |
| abstract_inverted_index.selected | 102 |
| abstract_inverted_index.solvents | 41 |
| abstract_inverted_index.support. | 59 |
| abstract_inverted_index.transfer | 18 |
| abstract_inverted_index.Pd-loaded | 0, 107 |
| abstract_inverted_index.catalytic | 17, 81, 112, 132 |
| abstract_inverted_index.different | 40 |
| abstract_inverted_index.five-fold | 117 |
| abstract_inverted_index.intrinsic | 7 |
| abstract_inverted_index.mgproduct | 129, 162 |
| abstract_inverted_index.obtaining | 149 |
| abstract_inverted_index.operating | 33 |
| abstract_inverted_index.providing | 85 |
| abstract_inverted_index.secondary | 8 |
| abstract_inverted_index.conditions | 34, 100 |
| abstract_inverted_index.containing | 5 |
| abstract_inverted_index.conversion | 78 |
| abstract_inverted_index.identified | 37 |
| abstract_inverted_index.membranes, | 4 |
| abstract_inverted_index.tangential | 146 |
| abstract_inverted_index.performance | 113, 133 |
| abstract_inverted_index.sustainable | 95 |
| abstract_inverted_index.unsupported | 123 |
| abstract_inverted_index.acetophenone | 21 |
| abstract_inverted_index.experimental | 99 |
| abstract_inverted_index.hierarchical | 1 |
| abstract_inverted_index.industrially | 28 |
| abstract_inverted_index.micron-sized | 52 |
| abstract_inverted_index.non-zeolitic | 9 |
| abstract_inverted_index.productivity | 119, 151 |
| abstract_inverted_index.hydrogenation | 19, 49, 82 |
| abstract_inverted_index.phenylethanol | 25 |
| abstract_inverted_index.preliminarily | 36 |
| abstract_inverted_index.(meso)porosity, | 10 |
| abstract_inverted_index.gcat−1·h−1). | 130, 163 |
| cited_by_percentile_year.max | 97 |
| cited_by_percentile_year.min | 89 |
| corresponding_author_ids | https://openalex.org/A5039897041 |
| countries_distinct_count | 1 |
| institutions_distinct_count | 6 |
| corresponding_institution_ids | https://openalex.org/I45204951 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/12 |
| sustainable_development_goals[0].score | 0.4399999976158142 |
| sustainable_development_goals[0].display_name | Responsible consumption and production |
| citation_normalized_percentile.value | 0.83379121 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |