Probing the Dipole-Bound State in the 9-Phenanthrolate Anion by Photodetachment Spectroscopy, Resonant Two-Photon Photoelectron Imaging, and Resonant Photoelectron Spectroscopy Article Swipe
Dao-Fu Yuan
,
Yue-Rou Zhang
,
Chen‐Hui Qian
,
Yuan Liu
,
Lai‐Sheng Wang
·
YOU?
·
· 2021
· Open Access
·
· DOI: https://doi.org/10.1021/acs.jpca.1c01563
YOU?
·
· 2021
· Open Access
·
· DOI: https://doi.org/10.1021/acs.jpca.1c01563
Valence-bound anions with a dipolar core can support dipole-bound states (DBSs) below the electron detachment threshold. The highly diffuse DBS observed is usually of σ symmetry with an s-like orbital. Recently, a π-type DBS was observed experimentally in the 9-anthrolate anion (9AT-) and it was shown to be stabilized due to the large anisotropic polarizability of the 9AT core. To confirm the general existence of π-DBS and its structural dependence, here we report an investigation of the 9-phenanthrolate anion (9PT-), which has a different structure and lower symmetry than 9AT-. Photodetachment spectroscopy revealed a DBS 257 cm-1 below the detachment threshold of 9PT- at 19 627 cm-1 (2.4334 eV). Resonant two-photon photoelectron imaging indeed showed a π symmetry for the DBS. Similar to that observed in 9AT-, the π-DBS in 9PT- is also stabilized by the anisotropic polarizability of the 9PT core and accessed via nonadiabatic population transfer from the initially populated σ-DBS. Photodetachment spectroscopy unveiled nine above-threshold vibrational resonances of the DBS, resulting in nine highly non-Franck-Condon resonant photoelectron spectra by tuning the detachment laser to the vibrational resonances. The combination of photodetachment spectroscopy and resonant photoelectron spectroscopy allowed frequencies for nine vibrational modes of the 9-phenathroxy radical to be measured, including the six lowest frequency bending modes.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.jpca.1c01563
- OA Status
- green
- Cited By
- 17
- References
- 82
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3145781983
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- OpenAlex ID
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https://openalex.org/W3145781983Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.jpca.1c01563Digital Object Identifier
- Title
-
Probing the Dipole-Bound State in the 9-Phenanthrolate Anion by Photodetachment Spectroscopy, Resonant Two-Photon Photoelectron Imaging, and Resonant Photoelectron SpectroscopyWork title
- Type
-
articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2021Year of publication
- Publication date
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2021-04-02Full publication date if available
- Authors
-
Dao-Fu Yuan, Yue-Rou Zhang, Chen‐Hui Qian, Yuan Liu, Lai‐Sheng WangList of authors in order
- Landing page
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https://doi.org/10.1021/acs.jpca.1c01563Publisher landing page
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YesWhether a free full text is available
- OA status
-
greenOpen access status per OpenAlex
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https://www.osti.gov/biblio/1775307Direct OA link when available
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Polarizability, X-ray photoelectron spectroscopy, Atomic physics, Ion, Spectroscopy, Chemistry, Anisotropy, Shape resonance, Photoemission spectroscopy, Dipole, Population, Molecular physics, Nuclear magnetic resonance, Physics, Molecule, Optics, Sociology, Organic chemistry, Demography, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
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17Total citation count in OpenAlex
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2025: 3, 2024: 2, 2023: 4, 2022: 5, 2021: 3Per-year citation counts (last 5 years)
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82Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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