Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit Article Swipe
Stavroula Kampouri
,
Mingxuan Zhang
,
Tianyang Chen
,
Julius J. Oppenheim
,
Alexandra C. Brown
,
Michael T. Payne
,
Justin L. Andrews
,
Junliang Sun
,
Mircea Dincă
·
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1002/anie.202213960
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1002/anie.202213960
We report a metal–organic framework (MOF) with a rare two‐dimensional (2D) secondary building unit (SBU). The SBU comprises mixed‐valent Fe 2+ and Fe 3+ metal ions bridged by oxygen atoms pertaining to the polytopic ligand 3,3′,4,4′,5,5′‐hexahydroxybiphenyl, which also define the iron‐oxide 2D layers. Overall, the anionic framework exhibits rare topology and evidences strong electronic communication between the mixed‐valence iron sites. These results highlight the importance of dimensionality control of MOF SBUs for discovering new topologies in reticular chemistry, and especially for improving electronic communication within the MOF skeleton.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/anie.202213960
- OA Status
- green
- Cited By
- 8
- References
- 44
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4298088480
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4298088480Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/anie.202213960Digital Object Identifier
- Title
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Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building UnitWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2022Year of publication
- Publication date
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2022-09-30Full publication date if available
- Authors
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Stavroula Kampouri, Mingxuan Zhang, Tianyang Chen, Julius J. Oppenheim, Alexandra C. Brown, Michael T. Payne, Justin L. Andrews, Junliang Sun, Mircea DincăList of authors in order
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https://doi.org/10.1002/anie.202213960Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
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https://pmc.ncbi.nlm.nih.gov/articles/PMC10100382/pdf/ANIE-61-0.pdfDirect OA link when available
- Concepts
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SBus, Metal-organic framework, Valence (chemistry), Topology (electrical circuits), Metal, Reticular connective tissue, Materials science, Chemistry, Inorganic chemistry, Crystallography, Mathematics, Physical chemistry, Organic chemistry, Combinatorics, Adsorption, Medicine, PathologyTop concepts (fields/topics) attached by OpenAlex
- Cited by
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8Total citation count in OpenAlex
- Citations by year (recent)
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2025: 1, 2024: 4, 2023: 2, 2022: 1Per-year citation counts (last 5 years)
- References (count)
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44Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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