Quantifying the Hydration‐Dependent Dynamics of Cu Migration and Activity in Zeolite Omega for the Partial Oxidation of Methane Article Swipe
Johannes Wieser
,
Dariusz Wardecki
,
Jörg W. A. Fischer
,
Mark A. Newton
,
Catherine Dejoie
,
Amy J. Knorpp
,
Thomas C. Hansen
,
Gunnar Jeschke
,
Przemysław Rzepka
,
Jeroen A. van Bokhoven
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/ange.202407395
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/ange.202407395
Copper‐exchanged zeolite omega (Cu‐omega) is a potent material for the selective conversion of methane‐to‐methanol (MtM) via the oxygen looping approach. However, its performance exhibits substantial variation depending on the operational conditions. Under an isothermal temperature regime, Cu‐omega demonstrates subdued activity below 230 °C, but experiences a remarkable increase in activity at 290 °C. Applying a high‐temperature activation protocol at 450 °C causes a rapid deactivation of the material. This behavioral divergence is investigated by combining reactivity studies, neutron diffraction and in situ high‐resolution anomalous X‐ray powder diffraction (HR‐AXRPD), as well as electron paramagnetic resonance spectroscopy, to reveal that the migration of Cu throughout the framework is the primary cause of these behaviors, which in turn is predominantly governed by the degree of hydration of the system. This work suggests that control over the Cu migration throughout the zeolite framework may be harnessed to significantly increase the activity of Cu‐omega by generating more active sites for the MtM conversion. These results underscore the power of in situ HR‐AXRPD for unraveling the behavior of materials under reaction conditions and suggest that a re‐evaluation of Cu‐zeolites priorly deemed inactive for the MtM conversion across a broader range of conditions and looping protocols may be warranted.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/ange.202407395
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202407395
- OA Status
- hybrid
- Cited By
- 1
- References
- 44
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4401539481
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Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4401539481Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/ange.202407395Digital Object Identifier
- Title
-
Quantifying the Hydration‐Dependent Dynamics of Cu Migration and Activity in Zeolite Omega for the Partial Oxidation of MethaneWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-08-13Full publication date if available
- Authors
-
Johannes Wieser, Dariusz Wardecki, Jörg W. A. Fischer, Mark A. Newton, Catherine Dejoie, Amy J. Knorpp, Thomas C. Hansen, Gunnar Jeschke, Przemysław Rzepka, Jeroen A. van BokhovenList of authors in order
- Landing page
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https://doi.org/10.1002/ange.202407395Publisher landing page
- PDF URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202407395Direct link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
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hybridOpen access status per OpenAlex
- OA URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202407395Direct OA link when available
- Concepts
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Zeolite, Copper, Methane, Anaerobic oxidation of methane, Omega, Methanol, Chemistry, Isothermal process, Electron paramagnetic resonance, Catalysis, Materials science, Nuclear magnetic resonance, Thermodynamics, Organic chemistry, Physics, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
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1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
- References (count)
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44Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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