Radical Additions of Carbyne to Achieve Metalla-aromatic Radicals Article Swipe
Zhihong Deng
,
Shengfa Ye
,
Xue‐Lian Jiang
,
Xinchao Zhang
,
Dafa Chen
,
Zhe Huang
,
Lizhi Tao
,
Jiaojiao Liu
,
Yong Ni
,
Jun Li
,
Haiping Xia
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.26434/chemrxiv-2025-gw265
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.26434/chemrxiv-2025-gw265
Transition metal-carbynes are efficient catalysts or key intermediates in a variety of chemical transformations. Significant research has focused on exploring their reactivity, aiming to understand the bonding characters and develop new applications. However, the radical addition reactions of metal-carbynes remain unknown, mainly due to the high polarity of metal-carbyne bonds, which is prone to electrophilic or nucleophilic additions. In this study, we report for the first time the radical addition reaction of metal-carbyne through the reactions of an osmium-carbyne located in aromatic ring with various radicals. The delocalized electronic structure and substantially steric hindrance of metallacycle provide sufficient stability for spectroscopic and/or structural characterizations of the radical addition intermediates, and endow high selectivity for the subsequent transformations. Notably, through this newly developed reaction, a spin-delocalized metalla-aromatic radical was achieved, which represents the first example of metal d-orbital participating in spin delocalization of open-shell π conjugated molecules, although considerable efforts have been dedicated to this field. This work not only opens up an avenue for the radical chemistry of metal-carbynes, but also provides a conceptually new strategy for preparing metal-contained open-shell π conjugated molecules in material science.
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Metadata
- Type
- preprint
- Language
- en
- Landing Page
- https://doi.org/10.26434/chemrxiv-2025-gw265
- https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/67ff9e16927d1c2e6639c262/original/radical-additions-of-carbyne-to-achieve-metalla-aromatic-radicals.pdf
- OA Status
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- Related Works
- 10
- OpenAlex ID
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All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W4409619170Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.26434/chemrxiv-2025-gw265Digital Object Identifier
- Title
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Radical Additions of Carbyne to Achieve Metalla-aromatic RadicalsWork title
- Type
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preprintOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-04-21Full publication date if available
- Authors
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Zhihong Deng, Shengfa Ye, Xue‐Lian Jiang, Xinchao Zhang, Dafa Chen, Zhe Huang, Lizhi Tao, Jiaojiao Liu, Yong Ni, Jun Li, Haiping XiaList of authors in order
- Landing page
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https://doi.org/10.26434/chemrxiv-2025-gw265Publisher landing page
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https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/67ff9e16927d1c2e6639c262/original/radical-additions-of-carbyne-to-achieve-metalla-aromatic-radicals.pdfDirect link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/67ff9e16927d1c2e6639c262/original/radical-additions-of-carbyne-to-achieve-metalla-aromatic-radicals.pdfDirect OA link when available
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Carbyne, Radical, Chemistry, Photochemistry, Organic chemistry, Catalysis, CarbeneTop concepts (fields/topics) attached by OpenAlex
- Cited by
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0Total citation count in OpenAlex
- Related works (count)
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10Other works algorithmically related by OpenAlex
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