RAFT with Light: A User Guide to Using Thiocarbonylthio Compounds in Photopolymerizations Article Swipe
Magdalena A. Bereś
,
Cyrille Boyer
,
Matthias Hartlieb
,
Dominik Konkolewicz
,
Greg G. Qiao
,
Brent S. Sumerlin
,
Sébastien Perrier
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1021/acspolymersau.4c00101
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1021/acspolymersau.4c00101
This perspective offers an in-depth guide to photopolymerizations mediated with thiocarbonylthio compounds, with a particular focus on photoiniferter and photoinduced energy/electron transfer RAFT (PET-RAFT) polymerizations, focusing on practical considerations. It is designed to provide both newcomers and experts with the practical knowledge needed to harness light-mediated polymerizations for innovative applications. The discussion begins with an overview of conventional RAFT polymerization and proceeds to highlight the distinctive advantages of the photomediated processes. The photochemical behavior of thiocarbonylthio compounds, along with the selection of appropriate light wavelengths, is critically examined for its impact on polymerization kinetics and optimization of polymer properties. Key parameters influencing polymerization successsuch as catalyst selection, solvent choice, light intensity, and temperatureare explored in detail. The importance of oxygen tolerance and end-group fidelity is also addressed, as these factors are essential for achieving well-defined polymers. Additionally, reactor configurations are reviewed, focusing on the roles of light sources, reactor geometry (batch versus flow systems), and temperature control in optimizing the reaction efficiency. The article concludes by integrating these concepts into a comprehensive framework for optimizing photoiniferter and PET-RAFT polymerizations.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acspolymersau.4c00101
- https://pubs.acs.org/doi/pdf/10.1021/acspolymersau.4c00101?ref=article_openPDF
- OA Status
- gold
- Cited By
- 25
- References
- 218
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4408897377
All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W4408897377Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acspolymersau.4c00101Digital Object Identifier
- Title
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RAFT with Light: A User Guide to Using Thiocarbonylthio Compounds in PhotopolymerizationsWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-03-27Full publication date if available
- Authors
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Magdalena A. Bereś, Cyrille Boyer, Matthias Hartlieb, Dominik Konkolewicz, Greg G. Qiao, Brent S. Sumerlin, Sébastien PerrierList of authors in order
- Landing page
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https://doi.org/10.1021/acspolymersau.4c00101Publisher landing page
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https://pubs.acs.org/doi/pdf/10.1021/acspolymersau.4c00101?ref=article_openPDFDirect link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://pubs.acs.org/doi/pdf/10.1021/acspolymersau.4c00101?ref=article_openPDFDirect OA link when available
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Raft, Photopolymer, Computer graphics (images), Computer science, Chemistry, Materials science, Polymerization, Composite material, PolymerTop concepts (fields/topics) attached by OpenAlex
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25Total citation count in OpenAlex
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2025: 25Per-year citation counts (last 5 years)
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218Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.polymerization | 59, 92, 102 |
| abstract_inverted_index.successsuch | 103 |
| abstract_inverted_index.considerations. | 28 |
| abstract_inverted_index.energy/electron | 20 |
| abstract_inverted_index.polymerizations | 46 |
| abstract_inverted_index.polymerizations, | 24 |
| abstract_inverted_index.polymerizations. | 178 |
| abstract_inverted_index.thiocarbonylthio | 10, 75 |
| abstract_inverted_index.temperatureare | 112 |
| abstract_inverted_index.photopolymerizations | 7 |
| cited_by_percentile_year.max | 100 |
| cited_by_percentile_year.min | 99 |
| corresponding_author_ids | https://openalex.org/A5014057252 |
| countries_distinct_count | 4 |
| institutions_distinct_count | 7 |
| corresponding_institution_ids | https://openalex.org/I2801239119, https://openalex.org/I39555362, https://openalex.org/I56590836 |
| citation_normalized_percentile.value | 0.99929806 |
| citation_normalized_percentile.is_in_top_1_percent | True |
| citation_normalized_percentile.is_in_top_10_percent | True |