Recognition and order of multiple sidechains by metal–organic framework enhances the separation of hexane isomers Article Swipe
Datta Markad
,
Laurence J. Kershaw Cook
,
Rémi Pétuya
,
Yong Yan
,
Oliver Gilford
,
Ajay Verma
,
Bhupendra Mali
,
Craig M. Robertson
,
Neil G. Berry
,
George R. Darling
,
Matthew S. Dyer
,
Dmytro Antypov
,
Alexandros P. Katsoulidis
,
Matthew J. Rosseinsky
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/ange.202411960
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/ange.202411960
Porous materials perform molecular sorting, separation and transformation by interaction between their framework structures and the substrates. Proteins also interact with molecules to effect chemical transformations, but rely on the precise sequence of the amino acid building units along a common polypeptide backbone to maximise their performance. Design strategies that positionally order sidechains over a defined porous framework to diversify the internal surface chemistry would enhance control of substrate processing. Here we show that different sidechains can be ordered over a metal–organic framework through recognition of their distinct chemistries during synthesis. The sidechains are recognised because each one forces the common building unit that defines the backbone of the framework into a different conformation in order to form the extended structure. The resulting sidechain ordering affords hexane isomer separation performance superior to that of the same framework decorated only with sidechains of a single kind. The separated molecules adopt distinct arrangements within the resulting modified pore geometry, reflecting their strongly differentiated environments precisely created by the ordered sidechains. The development of frameworks that recognize and order multiple sidechain functionality by conformational control offers tailoring of the internal surfaces within families of porous materials to direct interactions at the molecular level.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/ange.202411960
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202411960
- OA Status
- hybrid
- Cited By
- 1
- References
- 26
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4401780530
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4401780530Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/ange.202411960Digital Object Identifier
- Title
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Recognition and order of multiple sidechains by metal–organic framework enhances the separation of hexane isomersWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-08-21Full publication date if available
- Authors
-
Datta Markad, Laurence J. Kershaw Cook, Rémi Pétuya, Yong Yan, Oliver Gilford, Ajay Verma, Bhupendra Mali, Craig M. Robertson, Neil G. Berry, George R. Darling, Matthew S. Dyer, Dmytro Antypov, Alexandros P. Katsoulidis, Matthew J. RosseinskyList of authors in order
- Landing page
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https://doi.org/10.1002/ange.202411960Publisher landing page
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202411960Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
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hybridOpen access status per OpenAlex
- OA URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ange.202411960Direct OA link when available
- Concepts
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Molecule, Metal-organic framework, Chemistry, Hexane, Porosity, Molecular recognition, Computational chemistry, Combinatorial chemistry, Chemical physics, Topology (electrical circuits), Organic chemistry, Adsorption, Mathematics, CombinatoricsTop concepts (fields/topics) attached by OpenAlex
- Cited by
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1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
- References (count)
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26Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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