Reusable Hollow Polymer Microreactors Incorporated with Anisotropic Nanoparticles for Catalysis Application Article Swipe
YOU?
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· 2019
· Open Access
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· DOI: https://doi.org/10.1021/acsomega.8b02820
We report a methodology to encapsulate gold nanorods (AuNRs) and gold bipyramids (AuBPs) into polyelectrolyte capsules for catalytic application. Microreactors (capsules with encapsulated NRs or BPs) were fabricated by sequential deposition of poly(allylamine hydrochloride) and dextran sulfate on modified sacrificial template, followed by core dissolution. AuNRs and AuBPs of size 25-30 nm were successfully encapsulated in the fabricated polyelectrolyte capsules and were stable and distributed uniformly in the interior. Fabricated microreactors were investigated as catalysts for the reduction of p-nitrophenol to p-aminophenol in the presence of sodium borohydride in aqueous phase. Reaction parameters such as order, conversion, and rate constants were estimated for microreactors and compared to free anisotropic nanoparticles in suspension. The reaction rate was higher for NRs in both free and capsule forms compared to BPs. Microreactors demonstrated excellent catalytic activity even after three times of use. Such capsules have high potential for use as microreactors in applications such as catalysis, drug delivery, imaging, and cancer chemo-photothermal therapy.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acsomega.8b02820
- OA Status
- gold
- Cited By
- 28
- References
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- Related Works
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- OpenAlex ID
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Raw OpenAlex JSON
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https://openalex.org/W2909824890Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acsomega.8b02820Digital Object Identifier
- Title
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Reusable Hollow Polymer Microreactors Incorporated with Anisotropic Nanoparticles for Catalysis ApplicationWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2019Year of publication
- Publication date
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2019-01-09Full publication date if available
- Authors
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Varsha Sharma, Anandhakumar SundaramurthyList of authors in order
- Landing page
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https://doi.org/10.1021/acsomega.8b02820Publisher landing page
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YesWhether a free full text is available
- OA status
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goldOpen access status per OpenAlex
- OA URL
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https://doi.org/10.1021/acsomega.8b02820Direct OA link when available
- Concepts
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Microreactor, Nanoparticle, Polymer, Catalysis, Materials science, Nanotechnology, Chemical engineering, Chemistry, Organic chemistry, Composite material, EngineeringTop concepts (fields/topics) attached by OpenAlex
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28Total citation count in OpenAlex
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2025: 1, 2024: 3, 2023: 5, 2022: 10, 2021: 2Per-year citation counts (last 5 years)
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38Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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| referenced_works | https://openalex.org/W2607362556, https://openalex.org/W2504000235, https://openalex.org/W2401424569, https://openalex.org/W1533548687, https://openalex.org/W2130166533, https://openalex.org/W1990633787, https://openalex.org/W2096189061, https://openalex.org/W2186263721, https://openalex.org/W2064312871, https://openalex.org/W2618809001, https://openalex.org/W2799805127, https://openalex.org/W2080338428, https://openalex.org/W2765285079, https://openalex.org/W2749132894, https://openalex.org/W2804569358, https://openalex.org/W2314727100, https://openalex.org/W2068580698, https://openalex.org/W2013067561, https://openalex.org/W2791269183, https://openalex.org/W2153962966, https://openalex.org/W2209939222, https://openalex.org/W2951666951, https://openalex.org/W2562773531, https://openalex.org/W2034127130, https://openalex.org/W2345181535, https://openalex.org/W2031633335, https://openalex.org/W2795130849, https://openalex.org/W2805977284, https://openalex.org/W2128321159, https://openalex.org/W2149708065, https://openalex.org/W2517106716, https://openalex.org/W2334056373, https://openalex.org/W2476123226, https://openalex.org/W2036401470, https://openalex.org/W2025295644, https://openalex.org/W2055158065, https://openalex.org/W2071721047, https://openalex.org/W2066067383 |
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