Revealing the Elusive Structure and Reactivity of Iron Boride α-FeB Article Swipe
YOU?
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· 2023
· Open Access
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· DOI: https://doi.org/10.1021/acs.inorgchem.2c03709
Crystal structures can strongly deviate from bulk states when confined into nanodomains. These deviations may deeply affect properties and reactivity and then call for a close examination. In this work, we address the case where extended crystal defects spread through a whole solid and then yield an aperiodic structure and specific reactivity. We focus on iron boride, α-FeB, whose structure has not been elucidated yet, thus hindering the understanding of its properties. We synthesize the two known phases, α-FeB and β-FeB, in molten salts at 600 and 1100 °C, respectively. The experimental X-ray diffraction (XRD) data cannot be satisfactorily accounted for by a periodic crystal structure. We then model the compound as a stochastic assembly of layers of two structure types. Refinement of the powder XRD pattern by considering the explicit scattering interference of the different layers allows quantitative evaluation of the size of these domains and of the stacking faults between them. We, therefore, demonstrate that α-FeB is an intergrowth of nanometer-thick slabs of two structure types, β-FeB and CrB-type structures, in similar proportions. We finally discuss the implications of this novel structure on the reactivity of the material and its ability to perform insertion reactions by comparing the reactivities of α-FeB and β-FeB as reagents in the synthesis of a model layered material: Fe2AlB2. Using synchrotron-based in situ X-ray diffraction, we elucidate the mechanisms of the formation of Fe2AlB2. We highlight the higher reactivity of the intergrowth α-FeB in agreement with structural relationships.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.inorgchem.2c03709
- OA Status
- green
- Cited By
- 11
- References
- 60
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4318169235
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4318169235Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.inorgchem.2c03709Digital Object Identifier
- Title
-
Revealing the Elusive Structure and Reactivity of Iron Boride α-FeBWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-01-26Full publication date if available
- Authors
-
Fernando Igoa, Emile Defoy, Daniel Janisch, Gwenaëlle Rousse, Pierre‐Olivier Autran, Anissa Ghoridi, Amandine Séné, M. Baron, Leopoldo Suescun, Yann Le Godec, David PortehaultList of authors in order
- Landing page
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https://doi.org/10.1021/acs.inorgchem.2c03709Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
-
greenOpen access status per OpenAlex
- OA URL
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https://hal.science/hal-04047556Direct OA link when available
- Concepts
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Chemistry, Reactivity (psychology), Crystal structure, Crystallography, Diffraction, Stacking, Synchrotron, Crystal (programming language), Aperiodic graph, Organic chemistry, Physics, Optics, Combinatorics, Pathology, Alternative medicine, Programming language, Medicine, Computer science, MathematicsTop concepts (fields/topics) attached by OpenAlex
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11Total citation count in OpenAlex
- Citations by year (recent)
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2025: 3, 2024: 2, 2023: 6Per-year citation counts (last 5 years)
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60Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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