Roadmap on multivalent batteries Article Swipe
M. Rosa Palacín
,
Patrik Johansson
,
Robert Dominko
,
Ben Dlugatch
,
Doron Aurbach
,
Zhenyou Li
,
Maximilian Fichtner
,
Olivera Lužanin
,
Jan Bitenc
,
Zhixuan Wei
,
Clarissa Glaser
,
Jürgen Janek
,
Ana Fernández‐Barquín
,
Aroa R. Mainar
,
Olatz Leonet
,
Idoia Urdampilleta
,
J. Alberto Blázquez
,
Deyana S. Tchitchekova
,
Alexandre Ponrouch
,
Pieremanuele Canepa
,
Gopalakrishnan Sai Gautam
,
Raúl San Román Gallego Casilda
,
Cynthia S. Martínez-Cisneros
,
Nieves Ureña Torres
,
A. Várez
,
Jean‐Yves Sanchez
,
Kostiantyn V. Kravchyk
,
Maksym V. Kovalenko
,
Anastasia A. Teck
,
Huw Shiel
,
Ifan E. L. Stephens
,
Mary P. Ryan
,
Eugen Zemlyanushin
,
Sonia Dsoke
,
Rebecca Grieco
,
Nagaraj Patil
,
Rebeca Marcilla
,
Xuan Gao
,
Claire J. Carmalt
,
Guanjie He
,
Maria‐Magdalena Titirici
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1088/2515-7655/ad34fc
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1088/2515-7655/ad34fc
Battery technologies based in multivalent charge carriers with ideally two or three electrons transferred per ion exchanged between the electrodes have large promises in raw performance numbers, most often expressed as high energy density, and are also ideally based on raw materials that are widely abundant and less expensive. Yet, these are still globally in their infancy, with some concepts (e.g. Mg metal) being more technologically mature. The challenges to address are derived on one side from the highly polarizing nature of multivalent ions when compared to single valent concepts such as Li + or Na + present in Li-ion or Na-ion batteries, and on the other, from the difficulties in achieving efficient metal plating/stripping (which remains the holy grail for lithium). Nonetheless, research performed to date has given some fruits and a clearer view of the challenges ahead. These include technological topics (production of thin and ductile metal foil anodes) but also chemical aspects (electrolytes with high conductivity enabling efficient plating/stripping) or high-capacity cathodes with suitable kinetics (better inorganic hosts for intercalation of such highly polarizable multivalent ions). This roadmap provides an extensive review by experts in the different technologies, which exhibit similarities but also striking differences, of the current state of the art in 2023 and the research directions and strategies currently underway to develop multivalent batteries. The aim is to provide an opinion with respect to the current challenges, potential bottlenecks, and also emerging opportunities for their practical deployment.
Related Topics
Concepts
Anode
Nanotechnology
Holy Grail
Battery (electricity)
Materials science
Stripping (fiber)
Cathode
Computer science
Engineering physics
Process engineering
Chemistry
Electrode
Electrical engineering
Engineering
Physics
Physical chemistry
Power (physics)
Composite material
World Wide Web
Quantum mechanics
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1088/2515-7655/ad34fc
- https://iopscience.iop.org/article/10.1088/2515-7655/ad34fc/pdf
- OA Status
- gold
- Cited By
- 25
- References
- 320
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4392900419
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4392900419Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1088/2515-7655/ad34fcDigital Object Identifier
- Title
-
Roadmap on multivalent batteriesWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-03-18Full publication date if available
- Authors
-
M. Rosa Palacín, Patrik Johansson, Robert Dominko, Ben Dlugatch, Doron Aurbach, Zhenyou Li, Maximilian Fichtner, Olivera Lužanin, Jan Bitenc, Zhixuan Wei, Clarissa Glaser, Jürgen Janek, Ana Fernández‐Barquín, Aroa R. Mainar, Olatz Leonet, Idoia Urdampilleta, J. Alberto Blázquez, Deyana S. Tchitchekova, Alexandre Ponrouch, Pieremanuele Canepa, Gopalakrishnan Sai Gautam, Raúl San Román Gallego Casilda, Cynthia S. Martínez-Cisneros, Nieves Ureña Torres, A. Várez, Jean‐Yves Sanchez, Kostiantyn V. Kravchyk, Maksym V. Kovalenko, Anastasia A. Teck, Huw Shiel, Ifan E. L. Stephens, Mary P. Ryan, Eugen Zemlyanushin, Sonia Dsoke, Rebecca Grieco, Nagaraj Patil, Rebeca Marcilla, Xuan Gao, Claire J. Carmalt, Guanjie He, Maria‐Magdalena TitiriciList of authors in order
- Landing page
-
https://doi.org/10.1088/2515-7655/ad34fcPublisher landing page
- PDF URL
-
https://iopscience.iop.org/article/10.1088/2515-7655/ad34fc/pdfDirect link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
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https://iopscience.iop.org/article/10.1088/2515-7655/ad34fc/pdfDirect OA link when available
- Concepts
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Anode, Nanotechnology, Holy Grail, Battery (electricity), Materials science, Stripping (fiber), Cathode, Computer science, Engineering physics, Process engineering, Chemistry, Electrode, Electrical engineering, Engineering, Physics, Physical chemistry, Power (physics), Composite material, World Wide Web, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
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25Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 18, 2024: 7Per-year citation counts (last 5 years)
- References (count)
-
320Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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