Room-temperature magnetocaloric properties of yLa0.67Ca0.27Sr0.06MnO3/1−yLa0.7Sr0.3Mn0.95Cu0.05O3 composites Article Swipe
Selda Kılıç Çetin
,
Gönül Akça
,
Mehmet Selim Aslan
,
Ahmet Ekicibil
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1007/s10973-024-13014-w
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1007/s10973-024-13014-w
In this study, we have characterized the magnetic and magnetocaloric (MC) properties of composites formed by two manganites with appropriate Curie temperatures ( T C ) and acceptable maximum magnetic entropy change ( $$-\Delta {S}_{{\text{M}}}^{{\text{max}}}$$ ) values. The composites have similar diffraction patterns obtained for the main phases La 0.67 Ca 0.27 Sr 0.06 MnO 3 (LCSM) and La 0.7 Sr 0.3 Mn 0.95 Cu 0.05 O 3 (LSMC) overlapping the diffraction peaks of the perovskite structure. The absence of any diffraction peaks distinct from the main phases in the XRD patterns of the composites indicates that there is no third phase besides the main ones. It is understood from the SEM images that the composites are composed of particles of different shapes and that the interparticle spacing decreases and the grain boundaries become clear, indicating that the interaction between particles becomes stronger with the increase of the y ratio. A gradual transition is seen from the M ( T ) curves, which specify that the composites consist of phases with discrete transition temperatures. The magnetic phase transition of the samples is second order. The $$-\Delta {S}_{{\text{M}}}^{{\text{max}}}$$ value has been calculated as 3.18, 3.24, and 4.05 J kg −1 K −1 at 5 T magnetic field for the composites 0.25LCSM/0.75LSMC, 0.50LCSM/0.50LSMC, and 0.75LCSM/0.25LSMC, respectively. Since the RCP value of 0.5LCSM/0.5LSMC composite is 301.61 J kg −1 under 5 T, it can be considered as a promising candidate for use in various magnetic cooling technologies at room temperature.
Related Topics
Concepts
Magnetic refrigeration
Materials science
Composite material
Magnetic field
Magnetization
Physics
Quantum mechanics
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1007/s10973-024-13014-w
- https://link.springer.com/content/pdf/10.1007/s10973-024-13014-w.pdf
- OA Status
- hybrid
- Cited By
- 2
- References
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- Related Works
- 10
- OpenAlex ID
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All OpenAlex metadata
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https://doi.org/10.1007/s10973-024-13014-wDigital Object Identifier
- Title
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Room-temperature magnetocaloric properties of yLa0.67Ca0.27Sr0.06MnO3/1−yLa0.7Sr0.3Mn0.95Cu0.05O3 compositesWork title
- Type
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articleOpenAlex work type
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-03-24Full publication date if available
- Authors
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Selda Kılıç Çetin, Gönül Akça, Mehmet Selim Aslan, Ahmet EkicibilList of authors in order
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https://doi.org/10.1007/s10973-024-13014-wPublisher landing page
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https://link.springer.com/content/pdf/10.1007/s10973-024-13014-w.pdfDirect link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://link.springer.com/content/pdf/10.1007/s10973-024-13014-w.pdfDirect OA link when available
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Magnetic refrigeration, Materials science, Composite material, Magnetic field, Magnetization, Physics, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
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2025: 1, 2024: 1Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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