Screen Printed Copper and Tantalum Modified Potassium Sodium Niobate Thick Films on Platinized Alumina Substrates Article Swipe
YOU?
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· 2021
· Open Access
·
· DOI: https://doi.org/10.3390/ma14237137
We show how sintering in different atmospheres affects the structural, microstructural, and functional properties of ~30 μm thick films of K0.5Na0.5NbO3 (KNN) modified with 0.38 mol% K5.4Cu1.3Ta10O29 and 1 mol% CuO. The films were screen printed on platinized alumina substrates and sintered at 1100 °C in oxygen or in air with or without the packing powder (PP). The films have a preferential crystallographic orientation of the monoclinic perovskite phase in the [100] and [−101] directions. Sintering in the presence of PP contributes to obtaining phase-pure films, which is not the case for the films sintered without any PP notwithstanding the sintering atmosphere. The latter group is characterized by a slightly finer grain size, from 0.1 μm to ~2 μm, and lower porosity, ~6% compared with ~13%. Using piezoresponse force microscopy (PFM) and electron backscatter diffraction (EBSD) analysis of oxygen-sintered films, we found that the perovskite grains are composed of multiple domains which are preferentially oriented. Thick films sintered in oxygen exhibit a piezoelectric d33 coefficient of 64 pm/V and an effective thickness coupling coefficient kt of 43%, as well as very low mechanical losses of less than 0.5%, making them promising candidates for lead-free piezoelectric energy harvesting applications.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.3390/ma14237137
- https://www.mdpi.com/1996-1944/14/23/7137/pdf?version=1638442893
- OA Status
- gold
- Cited By
- 5
- References
- 42
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3216166416
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W3216166416Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.3390/ma14237137Digital Object Identifier
- Title
-
Screen Printed Copper and Tantalum Modified Potassium Sodium Niobate Thick Films on Platinized Alumina SubstratesWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2021Year of publication
- Publication date
-
2021-11-24Full publication date if available
- Authors
-
Brigita Kmet, Danjela Kuščer, Soma Dutta, Hana Uršič, Aleksander Matavž, Franck Levassort, V. Bobnar, Barbara Malič, Andreja BenčanList of authors in order
- Landing page
-
https://doi.org/10.3390/ma14237137Publisher landing page
- PDF URL
-
https://www.mdpi.com/1996-1944/14/23/7137/pdf?version=1638442893Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://www.mdpi.com/1996-1944/14/23/7137/pdf?version=1638442893Direct OA link when available
- Concepts
-
Materials science, Sintering, Monoclinic crystal system, Potassium niobate, Tantalum, Perovskite (structure), Composite material, Electron backscatter diffraction, Scanning electron microscope, Microstructure, Electromechanical coupling coefficient, Porosity, Piezoelectric coefficient, Piezoelectricity, Phase (matter), Grain size, Copper, Mineralogy, Chemical engineering, Metallurgy, Ferroelectricity, Crystallography, Crystal structure, Dielectric, Engineering, Optoelectronics, Organic chemistry, ChemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
5Total citation count in OpenAlex
- Citations by year (recent)
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2025: 1, 2024: 1, 2023: 2, 2022: 1Per-year citation counts (last 5 years)
- References (count)
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42Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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| referenced_works | https://openalex.org/W2790871915, https://openalex.org/W2887657302, https://openalex.org/W3158234643, https://openalex.org/W2188843329, https://openalex.org/W1487240792, https://openalex.org/W1975605666, https://openalex.org/W2154791735, https://openalex.org/W2347124297, https://openalex.org/W2732354677, https://openalex.org/W2091756829, https://openalex.org/W2070977443, https://openalex.org/W3041020744, https://openalex.org/W2328128651, https://openalex.org/W3014856952, https://openalex.org/W3015238046, https://openalex.org/W2127728837, https://openalex.org/W2914686950, https://openalex.org/W2099220766, https://openalex.org/W2041275853, https://openalex.org/W2101992711, https://openalex.org/W2035729461, https://openalex.org/W2167688569, https://openalex.org/W6746976777, https://openalex.org/W2158539792, https://openalex.org/W2011734496, https://openalex.org/W2000869499, https://openalex.org/W2950956253, https://openalex.org/W2071172826, https://openalex.org/W2115982866, https://openalex.org/W1982968439, https://openalex.org/W2016388697, https://openalex.org/W2063995209, https://openalex.org/W2993964603, https://openalex.org/W2897112197, https://openalex.org/W2578499738, https://openalex.org/W2572173590, https://openalex.org/W1910296726, https://openalex.org/W2107814476, https://openalex.org/W2057038182, https://openalex.org/W2017003765, https://openalex.org/W2080762952, https://openalex.org/W2775962763 |
| referenced_works_count | 42 |
| abstract_inverted_index.1 | 28 |
| abstract_inverted_index.a | 60, 108, 161 |
| abstract_inverted_index.64 | 166 |
| abstract_inverted_index.PP | 80, 97 |
| abstract_inverted_index.We | 0 |
| abstract_inverted_index.an | 169 |
| abstract_inverted_index.as | 177, 179 |
| abstract_inverted_index.at | 42 |
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| abstract_inverted_index.is | 87, 105 |
| abstract_inverted_index.kt | 174 |
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| abstract_inverted_index.or | 47, 51 |
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| abstract_inverted_index.~2 | 117 |
| abstract_inverted_index.0.1 | 114 |
| abstract_inverted_index.The | 31, 57, 102 |
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| abstract_inverted_index.1100 | 43 |
| abstract_inverted_index.43%, | 176 |
| abstract_inverted_index.CuO. | 30 |
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| abstract_inverted_index.from | 113 |
| abstract_inverted_index.have | 59 |
| abstract_inverted_index.less | 185 |
| abstract_inverted_index.mol% | 25, 29 |
| abstract_inverted_index.pm/V | 167 |
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| abstract_inverted_index.them | 189 |
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| abstract_inverted_index.were | 33 |
| abstract_inverted_index.with | 23, 50, 124 |
| abstract_inverted_index.μm, | 118 |
| abstract_inverted_index.(KNN) | 21 |
| abstract_inverted_index.(PFM) | 130 |
| abstract_inverted_index.(PP). | 56 |
| abstract_inverted_index.0.5%, | 187 |
| abstract_inverted_index.Thick | 155 |
| abstract_inverted_index.Using | 126 |
| abstract_inverted_index.[100] | 71 |
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| abstract_inverted_index.packing | 54 |
| abstract_inverted_index.printed | 35 |
| abstract_inverted_index.without | 52, 95 |
| abstract_inverted_index.[−101] | 73 |
| abstract_inverted_index.analysis | 136 |
| abstract_inverted_index.compared | 123 |
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| abstract_inverted_index.obtaining | 83 |
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| abstract_inverted_index.promising | 190 |
| abstract_inverted_index.sintering | 3, 100 |
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| abstract_inverted_index.candidates | 191 |
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| abstract_inverted_index.substrates | 39 |
| abstract_inverted_index.atmosphere. | 101 |
| abstract_inverted_index.atmospheres | 6 |
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| abstract_inverted_index.coefficient | 164, 173 |
| abstract_inverted_index.contributes | 81 |
| abstract_inverted_index.diffraction | 134 |
| abstract_inverted_index.directions. | 74 |
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| abstract_inverted_index.preferential | 61 |
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| abstract_inverted_index.characterized | 106 |
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| abstract_inverted_index.piezoresponse | 127 |
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| abstract_inverted_index.notwithstanding | 98 |
| abstract_inverted_index.oxygen-sintered | 138 |
| abstract_inverted_index.K5.4Cu1.3Ta10O29 | 26 |
| abstract_inverted_index.crystallographic | 62 |
| abstract_inverted_index.microstructural, | 10 |
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| cited_by_percentile_year.min | 89 |
| corresponding_author_ids | https://openalex.org/A5032347639 |
| countries_distinct_count | 3 |
| institutions_distinct_count | 9 |
| corresponding_institution_ids | https://openalex.org/I3006985408, https://openalex.org/I4210113529 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/7 |
| sustainable_development_goals[0].score | 0.8199999928474426 |
| sustainable_development_goals[0].display_name | Affordable and clean energy |
| citation_normalized_percentile.value | 0.51771089 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |