Selective Arene Photonitration via Iron-Complex β-Homolysis Article Swipe
Shuyang Liu
,
Ziyu Gan
,
Min Jiang
,
Qian Liao
,
Yusheng Lu
,
Hongyao Wang
,
Zhiyan Xue
,
Ziyang Chen
,
Yongqiang Zhang
,
Xiaobo Yang
,
Chunying Duan
,
Yunhe Jin
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/jacsau.4c00880
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/jacsau.4c00880
Nitroaromatics, as an important member and source of nitrogen-containing aromatics, is bringing enormous economic benefits in fields of pharmaceuticals, dyes, pesticides, functional materials, fertilizers, and explosives. Nonetheless, the notoriously polluting nitration industry, which suffers from excessive discharge of fumes and waste acids, poor functional group tolerance, and tremendous purification difficulty, renders mild, efficient, and environmentally friendly nitration a formidable challenge. Herein, we develop a visible-light-driven biocompatible arene C-H nitration strategy with good efficiency and regioselectivity, marvelous substrate applicability and functional group tolerance, and wide application in scale-up synthesis, total synthesis, and late-stage functionalization. A nitryl radical delivered through unusual β-homolysis of a photoexcited ferric-nitrate complex is proposed to be the key nitrification reagent in this system.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/jacsau.4c00880
- OA Status
- gold
- Cited By
- 16
- References
- 83
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4404575076
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4404575076Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/jacsau.4c00880Digital Object Identifier
- Title
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Selective Arene Photonitration via Iron-Complex β-HomolysisWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-11-21Full publication date if available
- Authors
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Shuyang Liu, Ziyu Gan, Min Jiang, Qian Liao, Yusheng Lu, Hongyao Wang, Zhiyan Xue, Ziyang Chen, Yongqiang Zhang, Xiaobo Yang, Chunying Duan, Yunhe JinList of authors in order
- Landing page
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https://doi.org/10.1021/jacsau.4c00880Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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goldOpen access status per OpenAlex
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https://doi.org/10.1021/jacsau.4c00880Direct OA link when available
- Concepts
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Nitration, Homolysis, Functional group, Chemistry, Regioselectivity, Organic synthesis, Environmentally friendly, Organic chemistry, Combinatorial chemistry, Nitrate, Reagent, Catalysis, Radical, Polymer, Ecology, BiologyTop concepts (fields/topics) attached by OpenAlex
- Cited by
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16Total citation count in OpenAlex
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2025: 16Per-year citation counts (last 5 years)
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83Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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| cited_by_percentile_year.max | 100 |
| cited_by_percentile_year.min | 99 |
| corresponding_author_ids | https://openalex.org/A5089634282 |
| countries_distinct_count | 1 |
| institutions_distinct_count | 12 |
| corresponding_institution_ids | https://openalex.org/I27357992, https://openalex.org/I4210092944 |
| citation_normalized_percentile.value | 0.96651678 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | True |