Self‐assembly of Gold Nanoparticles into an Adjustable Plasmonic 3D Lattice using Janus‐type Forked Mesogenic Ligands Article Swipe
Yangyang Zhao
,
Yu Cao
,
Giuliano Siligardi
,
Georg H. Mehl
,
Feng Liu
,
Goran Ungar
·
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1002/asia.202200057
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1002/asia.202200057
We report the formation of a 3D body‐centred self‐assembled superlattice of gold nanoparticles whose interparticle gap, and hence its plasmonic properties, are adjustable exclusively in the xy ‐plane. Thus, even though the particles are spherical, their anisotropic packing generates tailorable plasmonic dichroism. The gold nanoparticles are coated with forked ligands containing two mesogens: either two cholesterols (“twin”), one cholesterol and one azobenzene (“Janus”), or a mixture of the two. Beside the body‐centered arrangement of gold nanoparticles, the structure also contains unusual two‐dimensionally x‐y dual undulated (eggbox‐like) smectic‐like layers of mesogens. Moreover, the presence of azobenzene mesogens allows the superlattice to be melted through UV‐induced photo‐isomerization; the process is reversible displaying low fatigue on repeated cycling.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/asia.202200057
- OA Status
- green
- Cited By
- 1
- References
- 41
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4213065296
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4213065296Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/asia.202200057Digital Object Identifier
- Title
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Self‐assembly of Gold Nanoparticles into an Adjustable Plasmonic 3D Lattice using Janus‐type Forked Mesogenic LigandsWork title
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2022Year of publication
- Publication date
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2022-02-22Full publication date if available
- Authors
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Yangyang Zhao, Yu Cao, Giuliano Siligardi, Georg H. Mehl, Feng Liu, Goran UngarList of authors in order
- Landing page
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https://doi.org/10.1002/asia.202200057Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
- OA URL
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https://hull-repository.worktribe.com/output/3949609Direct OA link when available
- Concepts
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Azobenzene, Materials science, Colloidal gold, Plasmon, Superlattice, Nanoparticle, Janus, Crystallography, Self-assembly, Circular dichroism, Nanotechnology, Optoelectronics, Chemistry, Composite material, PolymerTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
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41Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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