Sequential Pore Functionalization in MOFs for Enhanced Carbon Dioxide Capture Article Swipe
Ankit K. Yadav
,
Andrzej Gładysiak
,
Ah‐Young Song
,
Lei Gan
,
Casey R. Simons
,
Nawal M. Alghoraibi
,
Ammar Alahmed
,
Mourad Younes
,
Jeffrey A. Reimer
,
Hongliang Huang
,
José Giner Planas
,
Kyriakos C. Stylianou
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/jacsau.4c00808
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/jacsau.4c00808
The capture of carbon dioxide (CO2) is crucial for reducing greenhouse emissions and achieving net-zero emission goals. Metal-organic frameworks (MOFs) present a promising solution for carbon capture due to their structural adaptability, tunability, porosity, and pore modification. In this research, we explored the use of a copper (Cu(II))-based MOF called m CBMOF-1. After activation, m CBMOF-1 generates one-dimensional channels with square cross sections, featuring sets of four Cu(II) open metal sites spaced by 6.042 Å, allowing strong interactions with coordinating molecules. To investigate this capability, m CBMOF-1 was exposed to ammonia (NH3) gas, resulting in hysteretic NH3 isotherms indicative of strong interactions between Cu(II) and NH3. At 150 mbar and 298 K, the NH3-loaded (∼1 mmol/g) material exhibited a 106% increase in CO2 uptake compared to that of the pristine m CBMOF-1. Carbon-13 solid-state nuclear magnetic resonance spectra and density functional theory calculations confirmed that the sequential loading of NH3 followed by CO2 adsorption generated a copper-carbamic acid complex within the pores of m CBMOF-1. Our study highlights the effectiveness of sequential pore functionalization in MOFs as an attractive strategy for enhancing the interactions of MOFs with small molecules such as CO2.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/jacsau.4c00808
- OA Status
- gold
- Cited By
- 8
- References
- 82
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4404961278
All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W4404961278Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/jacsau.4c00808Digital Object Identifier
- Title
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Sequential Pore Functionalization in MOFs for Enhanced Carbon Dioxide CaptureWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-12-03Full publication date if available
- Authors
-
Ankit K. Yadav, Andrzej Gładysiak, Ah‐Young Song, Lei Gan, Casey R. Simons, Nawal M. Alghoraibi, Ammar Alahmed, Mourad Younes, Jeffrey A. Reimer, Hongliang Huang, José Giner Planas, Kyriakos C. StylianouList of authors in order
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https://doi.org/10.1021/jacsau.4c00808Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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goldOpen access status per OpenAlex
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https://doi.org/10.1021/jacsau.4c00808Direct OA link when available
- Concepts
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Surface modification, Carbon dioxide, Chemical engineering, Materials science, Nanotechnology, Chemistry, Organic chemistry, EngineeringTop concepts (fields/topics) attached by OpenAlex
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8Total citation count in OpenAlex
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2025: 8Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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