Sintering Behavior of BST Nanoparticles at Low Temperature and Electrical Properties of their Ceramics Article Swipe
YOU?
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· 2020
· Open Access
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· DOI: https://doi.org/10.21203/rs.3.rs-40548/v1
The powders of the Ba 0.75 Sr 0.25 TiO 3 (BST) nanoparticles were directly synthesized by milling of Ba(OH) 2 ·8H 2 O, Sr(OH) 2 ·8H 2 O and Ti(BuO) 4 in ethanol at room temperature. They have homogenous grains of ~15 nm and the high sintering activity. The dense ceramics with the density >90% can be obtained at a sintering temperature of ≤950 o C by them with adding 3 wt% sintering aids of Bi 2 O 3 and Li 2 CO 3 . The sintering behavior of the BST nanoparticles by adding the aids of Bi 2 O 3 and Li 2 CO 3 is studied carefully. Several Bi-related compounds are involved in the sintering procedure at a different temperature. They enhance the mass transfer and promote the sintering densification. These compounds such as Ba 2 BiO 4 and SrBiO 4 appear at 800 o C, LiBa 4 Bi 3 O 11 and Sr 1.2 Bi 0.8 O 3 appear over 830 o C, and Bi 8.11 Ba 0.89 O 13.05 appears at 950 o C. The cation Bi in the ceramics has mixture valences of 3+ and 5+. It makes the ceramics as semiconducting state with the dark gray color and decreases the ceramics resistivities. With the sintering temperature increase, especially at 950 o C, the cation Bi tends back to single valence of +3 in the ceramics. The most of alkaline earth cations in Bi-related compounds will release and resorb into the lattice of BST and drive the densification of the nanoparticles. The BST ceramics can have a peak dielectric constant >6500 at 53 o C, loss <0.025, and resistivity >10 12 W·cm when sintered at a temperature of ≥900 o C with 3 wt% sintering aids. They have a potential application for multiple layer ceramic capacitors (MLCC) with silver inner-electrodes.
Related Topics
- Type
- preprint
- Language
- en
- Landing Page
- https://doi.org/10.21203/rs.3.rs-40548/v1
- https://www.researchsquare.com/article/rs-40548/v1.pdf?c=1594216148000
- OA Status
- green
- References
- 8
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4245681461
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4245681461Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.21203/rs.3.rs-40548/v1Digital Object Identifier
- Title
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Sintering Behavior of BST Nanoparticles at Low Temperature and Electrical Properties of their CeramicsWork title
- Type
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preprintOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2020Year of publication
- Publication date
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2020-07-08Full publication date if available
- Authors
-
Jianquan Qi, Yan Li, Mengyin Li, Jiahui Xie, Tianchi Yu, Qingwen Sun, Yifan Yan, Jian Wang, Xinkai Xiong, Ting‐Hui Wang, Xiumei HanList of authors in order
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https://doi.org/10.21203/rs.3.rs-40548/v1Publisher landing page
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https://www.researchsquare.com/article/rs-40548/v1.pdf?c=1594216148000Direct link to full text PDF
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YesWhether a free full text is available
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greenOpen access status per OpenAlex
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https://www.researchsquare.com/article/rs-40548/v1.pdf?c=1594216148000Direct OA link when available
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Sintering, Materials science, Ceramic, Nanoparticle, Valence (chemistry), Chemical engineering, Mineralogy, Analytical Chemistry (journal), Metallurgy, Nanotechnology, Chemistry, Organic chemistry, EngineeringTop concepts (fields/topics) attached by OpenAlex
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0Total citation count in OpenAlex
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8Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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| primary_location.landing_page_url | https://doi.org/10.21203/rs.3.rs-40548/v1 |
| publication_date | 2020-07-08 |
| publication_year | 2020 |
| referenced_works | https://openalex.org/W2165928548, https://openalex.org/W2787108412, https://openalex.org/W2042797998, https://openalex.org/W2086752618, https://openalex.org/W2052892034, https://openalex.org/W1972917841, https://openalex.org/W1999959092, https://openalex.org/W2190209080 |
| referenced_works_count | 8 |
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