Snapshots of the Stopped Polymerization of a Hindered Isocyanide within the Coordination Sphere of Ni(II) Article Swipe
Clara del Carmen-Rodríguez
,
Lucía Álvarez‐Miguel
,
Celedonio M. Álvarez
,
Raúl García‐Rodríguez
,
Daniel Miguel
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1021/acs.inorgchem.4c05461
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1021/acs.inorgchem.4c05461
The use of cationic Ni(II) complexes containing dialkyldithiophosphate ligands in conjunction with sterically hindered isocyanides suppresses polymerization, allowing the formation of well-defined monomeric cationic Ni(II) complexes 3 that result from the coupling of three isocyanides. These complexes have been characterized, including X-ray structure determination, and represent a snapshot of the first steps of the polymerization of isocyanide. Studies via X-ray, IR, and NMR seem to indicate that the key active species in the Ni(II)-catalyzed isocyanide polymerization and its so-called "merry-go-round" mechanism is not a carbene, as has been proposed, but actually a formamidinyl species. The use of the most sterically congested set of ligands enabled the isolation of the intermediate species 4c, which contains only two coupled isocyanides and can be used in the stepwise and controlled synthesis of a rare mixed Ni(II) complex 5 by using two different isocyanides.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.inorgchem.4c05461
- OA Status
- hybrid
- References
- 47
- Related Works
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- OpenAlex ID
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All OpenAlex metadata
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https://openalex.org/W4408222940Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.inorgchem.4c05461Digital Object Identifier
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Snapshots of the Stopped Polymerization of a Hindered Isocyanide within the Coordination Sphere of Ni(II)Work title
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-03-07Full publication date if available
- Authors
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Clara del Carmen-Rodríguez, Lucía Álvarez‐Miguel, Celedonio M. Álvarez, Raúl García‐Rodríguez, Daniel MiguelList of authors in order
- Landing page
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https://doi.org/10.1021/acs.inorgchem.4c05461Publisher landing page
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://doi.org/10.1021/acs.inorgchem.4c05461Direct OA link when available
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Chemistry, Isocyanide, Polymerization, Coordination sphere, Polymer chemistry, Medicinal chemistry, Crystallography, Organic chemistry, Crystal structure, PolymerTop concepts (fields/topics) attached by OpenAlex
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0Total citation count in OpenAlex
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10Other works algorithmically related by OpenAlex
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| publication_date | 2025-03-07 |
| publication_year | 2025 |
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