Structural Interconversions and Guest Binding Properties of Tetrakis(formylpyridine)-Based Pseudo -Cubic and Trigonal-Prismatic Metal–Organic Capsules Article Swipe

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Yuyin Du , Tanya K. Ronson , Yuchong Yang , Jonathan R. Nitschke , Yuyin Du , Tanya K. Ronson , Yuchong Yang , Jonathan R. Nitschke ·

YOU? · · 2025 · Open Access · · DOI: https://doi.org/10.1021/jacs.5c16191

Here, we report a new tetrakis(formylpyridine) subcomponent that was designed to assemble with anilines and Zn^II to afford a set of structurally distinct metal-organic cage structure types. By modulating the metal-to-ligand stoichiometry, we obtained a pseudo-cubic Zn₈L₆ cage and an open Zn₆L₃ trigonal prism, the former featuring a diastereomeric configuration of faces and vertices that had not been previously observed. Addition of a tritopic subcomponent yielded a Zn₆L₃L'₂ heteroleptic capped trigonal prism, which could also be prepared via a combination of the homoleptic cages formed by the two individual ligands. The capped trigonal prism encapsulated the pollutant perfluorobutanesulfonate and the oxidant tetracyanoquinodimethane, both technologically relevant guests.

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Chemistry Homoleptic Diastereomer Trigonal crystal system Cage Crystallography Stereochemistry Supramolecular chemistry Trigonal prismatic molecular geometry Trigonal pyramidal molecular geometry Molecule Prism Combinatorial chemistry Polymer chemistry

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Type: article
Language: en
Landing Page: https://doi.org/10.1021/jacs.5c16191
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References: 55
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DOI: https://doi.org/10.1021/jacs.5c16191

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Title: Structural Interconversions and Guest Binding Properties of Tetrakis(formylpyridine)-Based Pseudo -Cubic and Trigonal-Prismatic Metal–Organic Capsules

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Publication year: 2025

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Authors: Yuyin Du, Tanya K. Ronson, Yuchong Yang, Jonathan R. Nitschke, Yuyin Du, Tanya K. Ronson, Yuchong Yang, Jonathan R. Nitschke

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Concepts: Chemistry, Homoleptic, Diastereomer, Trigonal crystal system, Cage, Crystallography, Stereochemistry, Supramolecular chemistry, Trigonal prismatic molecular geometry, Trigonal pyramidal molecular geometry, Molecule, Prism, Combinatorial chemistry, Polymer chemistry

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