Structure, nonisothermal decomposition kinetics, thermal safety and mechanisms of improving stability and sensitivity of RDX/expanded graphite embedment composite Article Swipe
X L
,
Zuhua Zhang
,
Fan Jiang
,
Fengqin Shang
,
Xiaolei Ma
,
Xingcheng Du
,
Ye Tao
,
Haoming Zou
,
Xijuan Lv
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1088/1742-6596/2891/3/032013
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1088/1742-6596/2891/3/032013
To understand structure, properties and mechanisms of improving safety of RDX/expanded graphite (EG) embedment composite further and promote the application of EG in energetic materials, embedment stability, formability, detonation velocity, thermal stability, thermal safety and microscopic mechanisms of improving stability and sensitivity of the composite were studied in depth as a supplement to our previous work. Embedment stability was good. Formability (charge density of 1.76 gcm −3 ) and detonation velocity (7577 ms −1 ) were acceptable considering the content of EG was 13 wt%. Thermal stability and safety were proved to be improved by kinetics parameters and self-accelerating decomposition temperature. The former was obtained by forty-one kinds of kinetics model functions and six kinetics equations from nonisothermal thermolysis process of RDX. Molecular dynamics were employed to understand microscopic mechanisms for improving safety. Results showed that after being embedded in EG, strength and number of intermolecular forces in RDX crystal increased by 5.45 % and 14.38 %, and N-NO 2 maximum bond length of RDX molecule was shorted from 1.60 to 1.56 Å indicating a stronger intermolecular interaction and a safer trigger bond. All these results suggested that RDX/EG embedment composite was a more stable and insensitive system with a certain practical value.
Related Topics
Concepts
Embedment
Composite number
Materials science
Thermal decomposition
Graphite
Decomposition
Kinetics
Thermal stability
Sensitivity (control systems)
Stability (learning theory)
Composite material
Chemical engineering
Computer science
Chemistry
Engineering
Organic chemistry
Physics
Machine learning
Quantum mechanics
Electronic engineering
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1088/1742-6596/2891/3/032013
- OA Status
- diamond
- References
- 50
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4405848311
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4405848311Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1088/1742-6596/2891/3/032013Digital Object Identifier
- Title
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Structure, nonisothermal decomposition kinetics, thermal safety and mechanisms of improving stability and sensitivity of RDX/expanded graphite embedment compositeWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-12-01Full publication date if available
- Authors
-
X L, Zuhua Zhang, Fan Jiang, Fengqin Shang, Xiaolei Ma, Xingcheng Du, Ye Tao, Haoming Zou, Xijuan LvList of authors in order
- Landing page
-
https://doi.org/10.1088/1742-6596/2891/3/032013Publisher landing page
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YesWhether a free full text is available
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diamondOpen access status per OpenAlex
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https://doi.org/10.1088/1742-6596/2891/3/032013Direct OA link when available
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Embedment, Composite number, Materials science, Thermal decomposition, Graphite, Decomposition, Kinetics, Thermal stability, Sensitivity (control systems), Stability (learning theory), Composite material, Chemical engineering, Computer science, Chemistry, Engineering, Organic chemistry, Physics, Machine learning, Quantum mechanics, Electronic engineeringTop concepts (fields/topics) attached by OpenAlex
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0Total citation count in OpenAlex
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10Other works algorithmically related by OpenAlex
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| referenced_works | https://openalex.org/W2058860892, https://openalex.org/W2086623463, https://openalex.org/W2160780323, https://openalex.org/W2622213670, https://openalex.org/W2790754671, https://openalex.org/W6654121623, https://openalex.org/W2889335791, https://openalex.org/W1974218876, https://openalex.org/W2361179911, https://openalex.org/W1998266466, https://openalex.org/W2012636747, https://openalex.org/W2324601719, https://openalex.org/W1973340781, https://openalex.org/W2901783858, https://openalex.org/W2005786569, https://openalex.org/W1977616672, https://openalex.org/W2604786969, https://openalex.org/W6650568369, https://openalex.org/W1970859420, https://openalex.org/W2898903652, https://openalex.org/W2884934968, https://openalex.org/W2894088264, https://openalex.org/W2057116581, https://openalex.org/W2013488108, https://openalex.org/W2796353658, https://openalex.org/W2898444264, https://openalex.org/W2779152958, https://openalex.org/W2172784277, https://openalex.org/W2033013763, https://openalex.org/W2895923563, https://openalex.org/W3041773454, https://openalex.org/W2178910408, https://openalex.org/W1985492139, https://openalex.org/W3128085772, https://openalex.org/W2543669294, https://openalex.org/W2905565148, https://openalex.org/W2785648296, https://openalex.org/W2261872783, https://openalex.org/W2051039131, https://openalex.org/W1985391740, https://openalex.org/W2045262110, https://openalex.org/W2061982530, https://openalex.org/W1869896793, https://openalex.org/W2441852798, https://openalex.org/W2091654157, https://openalex.org/W2024955711, https://openalex.org/W2004540732, https://openalex.org/W2972175701, https://openalex.org/W2014325155, https://openalex.org/W2000916593 |
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